In Situ Coupling Reconstruction of Cobalt–Iron Oxide on a Cobalt Phosphate Nanoarray with Interfacial Electronic Features for Highly Enhanced Water Oxidation Catalysis

2020 ◽  
Vol 8 (12) ◽  
pp. 4773-4780 ◽  
Author(s):  
Peng Guo ◽  
Zhaojie Wang ◽  
Shaohui Ge ◽  
Hongyu Chen ◽  
Jinbao Zhang ◽  
...  
2015 ◽  
Vol 54 (6) ◽  
pp. 2734-2741 ◽  
Author(s):  
Gökhan Elmaci ◽  
Carolin E. Frey ◽  
Philipp Kurz ◽  
Birgül Zümreoğlu-Karan

2016 ◽  
Vol 4 (22) ◽  
pp. 8812-8821 ◽  
Author(s):  
Gökhan Elmacı ◽  
Carolin E. Frey ◽  
Philipp Kurz ◽  
Birgül Zümreoğlu-Karan

A first comparative study on 1D-, 2D- and 3D-manganese oxides supported by iron oxide nanoparticles for use as water oxidation catalysts is presented.


2019 ◽  
Vol 7 (11) ◽  
pp. 6012-6020 ◽  
Author(s):  
Laurent Liardet ◽  
Jordan E. Katz ◽  
Jingshan Luo ◽  
Michael Grätzel ◽  
Xile Hu

An optically transparent cobalt-iron oxide catalyst improves the photoelectrochemical performance of nanostructured hematite photoanodes.


2020 ◽  
Vol 998 ◽  
pp. 123-133
Author(s):  
Li Fei Xi ◽  
Christoph Schwanke ◽  
Kathrin M. Lange ◽  
Marcel Risch

Understanding the process of water oxidation, especially intermediate species, represents an important step toward gaining a mechanistic understanding of new emerging catalysts. The aim of this study is exploring the process of water oxidation and electrolyte orientation under external potential when using an emerging water oxidation catalyst, CoBi, in sodium borate (NaBi) buffer using in situ attenuated–total-reflection Fourier transform infrared spectroscopy (ATR-FTIR) spectroscopy. CoBi is generated via electrodeposition from aqueous solutions containing borate and Co2+. IR spectra were obtained for CoBi films under applied potentials supporting water oxidation catalysis. The spectra of water and CoBi on ZnSe/Cr/Au electrode surfaces change in intensity and their slope depends on the potential, which is rarely reported. The appearance of new bands at certain potentials is interpreted in terms of the potential-dependent re-alignment of water and borate molecules both from the film and electrolyte. A superoxide surface intermediate at 1027 cm-1 was observed in both thin and thick films. It is proposed to be Co (III)OO*H bridging and relates to a fast water oxidation process. The chemical structure of the intermediate species is proposed finally.


2019 ◽  
Vol 7 (1) ◽  
pp. 118-123
Author(s):  
Qiaoqiao Zhang ◽  
Yong Fan ◽  
Wei Wang ◽  
Ning Liu ◽  
Jingqi Guan

2008 ◽  
Vol 43 (10) ◽  
pp. 3539-3552 ◽  
Author(s):  
Christopher F. Blanford ◽  
C. Barry Carter ◽  
Andreas Stein

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