Self-Assembly of Pentaphenol Adducts:  Formation of 3D Network and Ladder-type Supramolecular Structures in the Solid State

2006 ◽  
Vol 6 (3) ◽  
pp. 636-642 ◽  
Author(s):  
Akhila Jayaraman ◽  
Venkataramanan Balasubramaniam ◽  
Suresh Valiyaveettil
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Supramolecular Structures ◽  
3D Network

scholarly journals Exploring the Self-Assembled Tacticity in Aurophilic Polymeric Arrangements of Diphosphanegold(I) Fluorothiolates

Molecules ◽  
2019 ◽  
Vol 24 (23) ◽  
pp. 4422 ◽  
Author(s):  
Moreno-Alcántar ◽  
Salazar ◽  
Romo-Islas ◽  
Flores-Álamo ◽  
Torrens
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Structural Diversity ◽  
Supramolecular Structures ◽  
X Ray Diffraction ◽  
Ligand Effects ◽  
Rational Control ◽  
Solid State Structures ◽  
Further Development ◽  
Aurophilic Interactions

Despite the recurrence of aurophilic interactions in the solid-state structures of gold(I) compounds, its rational control, modulation, and application in the generation of functional supramolecular structures is an area that requires further development. The ligand effects over the aurophilic-based supramolecular structures need to be better understood. This paper presents the supramolecular structural diversity of a series of new 1,3-bis(diphenylphosphane)propane (dppp) gold(I) fluorinated thiolates with the general formula [Au2(SRF)2(μ-dppp)] (SRF = SC6F5 (1); SC6HF4-4 (2); SC6H3(CF3)2-3,5 (3); SC6H4CF3-2 (4); SC6H4CF3-4 (5); SC6H3F2-3,4 (6); SC6H3F2-3,5 (7); SC6H4F-2 (8); SC6H4F-3 (9); SC6H4F-4 (10)). These compounds were synthesized and characterized, and six of their solid-state crystalline structures were determined using single-crystal X-ray diffraction. In the crystalline arrangement, they form aurophilic-bridged polymers. In these systems, the changes in the fluorination patterns of the thiolate ligands tune the aurophilic-induced self-assembly of the compounds causing tacticity and chiral differentiation of the monomers. This is an example of the use of ligand effects on the tune of the supramolecular association of gold complexes.

Formation of Interesting Organic Supramolecular Structures in the Solid-State Self-Assembly of Triphenol Adducts

2006 ◽  
Vol 6 (1) ◽  
pp. 150-160 ◽  
Author(s):  
Akhila Jayaraman ◽  
Venkataramanan Balasubramaniam ◽  
Suresh Valiyaveettil
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Supramolecular Structures

Azoimidazole gold(III) complexes: Synthesis, structural characterization and self-assembly in the solid state

2021 ◽  
Vol 522 ◽  
pp. 120373
Author(s):  
Alexander G. Tskhovrebov ◽  
Alexander S. Novikov ◽  
Boris S. Tupertsev ◽  
Alexey A. Nazarov ◽  
Anastasia A. Antonets ◽  
...  
Keyword(s):  
Solid State ◽  
Structural Characterization ◽  
Self Assembly

scholarly journals Self-assembly of arene ruthenium acylpyrazolone fragments to tetranuclear metallacycles. Molecular structures and solid-state 15N CPMAS NMR correlations

2016 ◽  
Vol 45 (9) ◽  
pp. 3974-3982 ◽  
Author(s):  
Riccardo Pettinari ◽  
Fabio Marchetti ◽  
Claudio Pettinari ◽  
Francesca Condello ◽  
Brian W. Skelton ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Self Assembly ◽  
Solid State Nmr ◽  
Molecular Structures ◽  
Sandwich Complexes ◽  
Solid State Nmr Spectroscopy ◽  
Half Sandwich

Mono- and tetranuclear Ru(ii) half-sandwich complexes containing acylpyrazolone ligands. 13C and 15N solid state NMR spectroscopy.

scholarly journals Mechanochemical and solvent-free assembly of zirconium-based metal–organic frameworks

2016 ◽  
Vol 52 (10) ◽  
pp. 2133-2136 ◽  
Author(s):  
Krunoslav Užarević ◽  
Timothy C. Wang ◽  
Su-Young Moon ◽  
Athena M. Fidelli ◽  
Joseph T. Hupp ◽  
...  
Keyword(s):  
Solid State ◽  
High Temperatures ◽  
Self Assembly ◽  
Metal Organic Frameworks ◽  
Accelerated Aging ◽  
Solvent Free ◽  
Catalytically Active ◽  
Metal Organic ◽  
Strong Acids ◽  
Zirconium Metal

Mechanochemistry and accelerated aging are new routes to zirconium metal–organic frameworks, yielding UiO-66 and catalytically active UiO-66-NH2 accessible on the gram scale through mild solid-state self-assembly, without strong acids, high temperatures or excess reactants.

Pentafluorophenyl Copper–Pyridine Complexes: Synthesis, Supramolecular Structures via Cuprophilic and π-Stacking Interactions, and Solid-State Luminescence

2011 ◽  
Vol 31 (4) ◽  
pp. 1546-1558 ◽  
Author(s):  
Ami Doshi ◽  
Anand Sundararaman ◽  
Krishnan Venkatasubbaiah ◽  
Lev N. Zakharov ◽  
Arnold L. Rheingold ◽  
...  
Keyword(s):  
Solid State ◽  
Supramolecular Structures ◽  
Stacking Interactions ◽  
Pyridine Complexes ◽  
Π Stacking ◽  
State Luminescence

Supramolecular Self-Assembly of V-Shaped Water Trimers and Diethylenetriamine Molecules in a New Solid State Ferrous Molybdenum(V) Phosphate

2013 ◽  
Vol 24 (1) ◽  
pp. 243-257 ◽  
Author(s):  
Yunshan Zhou ◽  
Sadaf ul Hassan ◽  
Lijuan Zhang ◽  
Xianqi Li ◽  
Waqar Ahmad
Keyword(s):  
Solid State ◽  
Self Assembly

Correlation of the solid-state reactivities of racemic 2,4(6)-di-O-benzoyl-myo-inositol 1,3,5-orthoformate and its 4,4′-bipyridine cocrystal with their crystal structures

2014 ◽  
Vol 70 (11) ◽  
pp. 1040-1045 ◽  
Author(s):  
Majid I. Tamboli ◽  
Vir Bahadur ◽  
Rajesh G. Gonnade ◽  
Mysore S. Shashidhar
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Transfer Reaction ◽  
Acyl Transfer ◽  
Transfer Reactions ◽  
Group Transfer ◽  
Hydrogen Bonding Interactions ◽  
Benzoyl Group ◽  
The Stability ◽  
Group Migration

Racemic 2,4(6)-di-O-benzoyl-myo-inositol 1,3,5-orthoformate, C21H18O8,(1), shows a very efficient intermolecular benzoyl-group migration reaction in its crystals. However, the presence of 4,4′-bipyridine molecules in its cocrystal, C21H18O8·C10H8N2,(1)·BP, inhibits the intermolecular benzoyl-group transfer reaction. In(1), molecules are assembled around the crystallographic twofold screw axis (baxis) to form a helical self-assembly through conventional O—H...O hydrogen-bonding interactions. This helical association places the reactive C6-O-benzoyl group (electrophile, El) and the C4-hydroxy group (nucleophile, Nu) in proximity, with a preorganized El...Nu geometry favourable for the acyl transfer reaction. In the cocrystal(1)·BP, the dibenzoate and bipyridine molecules are arranged alternately through O—H...N interactions. The presence of the bipyridine molecules perturbs the regular helical assembly of the dibenzoate molecules and thus restricts the solid-state reactivity. Hence, unlike the parent dibenzoate crystals, the cocrystals do not exhibit benzoyl-transfer reactions. This approach is useful for increasing the stability of small molecules in the crystalline state and could find application in the design of functional solids.

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