Brønsted Acidic Ionic Liquid Modified Magnetic Nanoparticle: An Efficient and Green Catalyst for Biodiesel Production

2014 ◽  
Vol 53 (8) ◽  
pp. 3040-3046 ◽  
Author(s):  
Zuowang Wu ◽  
Zhong Li ◽  
Gaoming Wu ◽  
Lele Wang ◽  
Shenqin Lu ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Magnetic Nanoparticle ◽  
Biodiesel Production ◽  
Green Catalyst ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid

The synthesis of biodiesel from coconut oil using novel Brønsted acidic ionic liquid as green catalyst

2016 ◽  
Vol 296 ◽  
pp. 71-78 ◽  
Author(s):  
Ting Qiu ◽  
Xiaoting Guo ◽  
Jinbei Yang ◽  
Lihua Zhou ◽  
Ling Li ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Coconut Oil ◽  
Green Catalyst ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid

Brønsted acidic ionic liquid 1-methylimidazolium tetrafluoroborate: a green catalyst and recyclable medium for esterification

2003 ◽  
Vol 5 (1) ◽  
pp. 38 ◽  
Author(s):  
Hua-Ping Zhu ◽  
Fan Yang ◽  
Jie Tang ◽  
Ming-Yuan He
Keyword(s):  
Ionic Liquid ◽  
Green Catalyst ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid

Surfactant-like Brønsted acidic ionic liquid as an efficient catalyst for selective Mannich reaction and biodiesel production in water

2016 ◽  
Vol 14 (4) ◽  
pp. 907-914 ◽  
Author(s):  
Majid Vafaeezadeh ◽  
Mina Karbalaie-Reza ◽  
Mohammad Mahmoodi Hashemi ◽  
Kasra Qasempour Soleimany
Keyword(s):  
Ionic Liquid ◽  
Mannich Reaction ◽  
Biodiesel Production ◽  
Efficient Catalyst ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid

Biodiesel Production by Esterification of Oleic Acid over Brønsted Acidic Ionic Liquid Supported onto Fe-Incorporated SBA-15

2012 ◽  
Vol 51 (51) ◽  
pp. 16590-16596 ◽  
Author(s):  
Lin Zhang ◽  
Yadong Cui ◽  
Chunping Zhang ◽  
Lei Wang ◽  
Hui Wan ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Oleic Acid ◽  
Biodiesel Production ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid

1, 1’-Sulfinyldiethylammonium Bis (Hydrogen Sulfate) as a Recyclable Dicationic Ionic Liquid Catalyst for the Efficient Solvent-free Synthesis of 3, 4-Dihydropyrimidin-2(1H)-ones via Biginelli Reaction

2020 ◽  
Vol 23 (2) ◽  
pp. 157-167
Author(s):  
Zainab Ehsani-Nasab ◽  
Ali Ezabadi
Keyword(s):  
Ionic Liquid ◽  
Biginelli Reaction ◽  
Aromatic Aldehydes ◽  
Solvent Free ◽  
Hydrogen Sulfate ◽  
One Pot ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid ◽  
Solvent Free Conditions ◽  
Dicationic Ionic Liquid

Objective: A facile and efficient method for synthesis of 3, 4-dihydropyrimidin-2(1H)-ones via Biginelli reaction catalyzed by a novel dicationic Brönsted acidic ionic liquid, [(EtNH2)2SO][HSO4]2, has been successfully developed. Material and Method:: 3, 4-Dihydropyrimidin-2(1H)-ones were synthesized through one-pot condensation of aromatic aldehydes, ethyl acetoacetate, and urea under solvent-free conditions using [(EtNH2)2SO][HSO4]2 as a novel catalyst. The progress of the reaction was monitored by thin-layer chromatography (ethyl acetate / n-hexane = 1 / 5). The products have been characterized by IR, 1H NMR, 13C NMR, and also by their melting points. Results: In this research, a library of dihydropyrimidinone derivatives was synthesized via Biginelli reaction under solvent-free conditions at 120oC using [(EtNH2)2SO][HSO4]2 as a catalyst. Various aromatic aldehydes, as well as heteroaromatic aldehydes, were employed, affording good to high yields of the corresponding products and illustrating the substrate generality of the present method. In addition, the prepared dicationic Brönsted acidic ionic liquid can be easily recovered and reused. Conclusion: 1, 1’-Sulfinyldiethylammonium bis (hydrogen sulfate), as a novel dicationic ionic liquid, can act as a highly efficient catalyst for the synthesis of 3, 4-dihydropyrimidin-2(1H)-ones under solvent-free conditions.

Synthesis and Characterization of a Novel Ionic Liquid Based on N,N,N,N-tetramethylethylenediamine and its Application in the Synthesis of 1,8-dioxo-octahydro Xanthenes

2018 ◽  
Vol 21 (7) ◽  
pp. 526-532 ◽  
Author(s):  
Zahra Abdi Piralghar ◽  
Mohammad Mahmoodi Hashemi ◽  
Ali Ezabadi
Keyword(s):  
Ionic Liquid ◽  
Chlorosulfonic Acid ◽  
Solvent Free ◽  
Aryl Aldehydes ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid ◽  
Solvent Free Conditions ◽  
Aryl Aldehyde ◽  
High Yields

Aim and Objective: In this work, we synthesized and characterized a novel Brönsted acidic ionic liquid from the reaction of N, N, N’, N’-tetramethylethylenediamine with chlorosulfonic acid and explored its catalytic activity in 1, 8-dioxo-octahydroxanthenes synthesis. Materials and Methods: Dimedone, aryl aldehydes, and the ionic liquid as the catalyst were reacted under solvent-free conditions. The progressive of the reaction was monitored by a thin layer of chromatography (ethyl acetate/n-hexane = 1/5). All products were characterized as the basis of their spectra data and melting point by comparison with those reported in the literature. Results: The prepared ionic liquid was successfully applied in the synthesis of 1, 8-dioxooctahydroxanthenes in good to high yields on the reaction of aryl aldehyde and dimedone at 120oC under solvent-free conditions. Conclusion: This research demonstrates that the catalyst is impressive for 1, 8-dioxo-octahydroxanthenes synthesis under solvent-free conditions.

Biodiesel production from waste cooking oil by acidic ionic liquid as a catalyst

2015 ◽  
Vol 77 ◽  
pp. 521-526 ◽  
Author(s):  
Zahoor Ullah ◽  
Mohamad Azmi Bustam ◽  
Zakaria Man
Keyword(s):  
Ionic Liquid ◽  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Cooking Oil ◽  
Acidic Ionic Liquid
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