New Base Pairing Motifs. The Synthesis and Thermal Stability of Oligodeoxynucleotides Containing Imidazopyridopyrimidine Nucleosides with the Ability to Form Four Hydrogen Bonds

2003 ◽  
Vol 125 (33) ◽  
pp. 9970-9982 ◽  
Author(s):  
Noriaki Minakawa ◽  
Naoshi Kojima ◽  
Sadao Hikishima ◽  
Takashi Sasaki ◽  
Arihiro Kiyosue ◽  
...  
2016 ◽  
Vol 4 (1) ◽  
pp. 51-64 ◽  
Author(s):  
Léa Chancelier ◽  
Olivier Boyron ◽  
Thibaut Gutel ◽  
Catherine Santini

This work highlights the factors tuning the thermal stability of imidazolium-based ionic liquids (IL) associated to bis(trifluoromethanesulfonyl)imide anion [NTf2]. The decomposition temperatures (Td) were evaluated by thermogravimetric analyses (TGA) with optimized parameters to obtain reproducible Td. The impact of the alkyl chain length and of the presence of functional groups and unsaturations on Td were evaluated. The thermal behaviour was governed by Van der Waals interactions between alkyl chains, and by inter and intra coulombic interactions such as hydrogen bonds.


1996 ◽  
Vol 61 (9) ◽  
pp. 1295-1306 ◽  
Author(s):  
Zdeněk Mička ◽  
Lucie Prokopová ◽  
Ivana Císařová ◽  
David Havlíček

Magnesium selenates double salts K2Mg(SeO4)2.6H2O, Rb2Mg(SeO4)2.6H2O, Cs2Mg(SeO4)2.6H2O, and (NH4)2Mg(SeO4)2.6H2O have been studied by means of X-ray diffraction methods, thermoanalytical methods, and infrared spectroscopy. The basic building units of these compounds are slightly deformed tetrahedra of selenate anions and octahedra of hexaaquamagnesium(II) cations interconnected by a system of hydrogen bonds. The investigation of IR spectra has been used in the discussion of X-ray diffraction results in the field of description of the hydrogen bond system and deformation of the basic polyhedra of selenate anion and hexaaquamagnesium cation. The thermoanalytical studies are used in evaluating the effects of hydrogen bonds and polarization influence of M+ cations on thermal stability of the compounds studied.


2013 ◽  
Vol 06 (01) ◽  
pp. 19-24 ◽  
Author(s):  
Hiroshi Nakashima ◽  
Ai Fukuoka ◽  
Yuka Saitou

2011 ◽  
Vol 514 (1-2) ◽  
pp. 32-36 ◽  
Author(s):  
Wojciech Przybylski ◽  
Ryszard Gryboś ◽  
Dorota Majda ◽  
Janusz T. Szklarzewicz

Sign in / Sign up

Export Citation Format

Share Document