Control of Crystalline Proton-Conducting Pathways by Water-Induced Transformations of Hydrogen-Bonding Networks in a Metal–Organic Framework

2014 ◽  
Vol 136 (21) ◽  
pp. 7701-7707 ◽  
Author(s):  
Masaaki Sadakiyo ◽  
Teppei Yamada ◽  
Kyohei Honda ◽  
Hiroshi Matsui ◽  
Hiroshi Kitagawa
Keyword(s):  
Hydrogen Bonding ◽  
Metal Organic Framework ◽  
Proton Conducting ◽  
Metal Organic ◽  
Hydrogen Bonding Networks ◽  
Organic Framework

scholarly journals Theoretical hydrogen bonding calculations and proton conduction for Eu(iii)-based metal–organic framework

RSC Advances ◽  
2021 ◽  
Vol 11 (19) ◽  
pp. 11495-11499
Author(s):  
Lu Feng ◽  
Tian-Yu Zeng ◽  
Hao-Bo Hou ◽  
Hong Zhou ◽  
Jian Tian
Keyword(s):  
Hydrogen Bonding ◽  
Theoretical Calculation ◽  
Proton Transport ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
Transport Channel ◽  
Proton Conducting ◽  
Metal Organic ◽  
Organic Framework

A water-mediated proton-conducting Eu(iii)-MOF has been synthesized, which provides a stable proton transport channel that was confirmed by theoretical calculation.

A Stable Polyoxometalate-Pillared Metal-Organic Framework for Proton-Conducting and Colorimetric Biosensing

2015 ◽  
Vol 21 (33) ◽  
pp. 11894-11898 ◽  
Author(s):  
En-Long Zhou ◽  
Chao Qin ◽  
Peng Huang ◽  
Xin-Long Wang ◽  
Wei-Chao Chen ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Proton Conducting ◽  
Metal Organic ◽  
Colorimetric Biosensing ◽  
Organic Framework

Preferential adsorption of ethane over ethylene on a Zr-based metal-organic framework: impacts of C-H···N hydrogen bonding

2021 ◽  
Author(s):  
Yaping Zhang ◽  
Daofei Lv ◽  
Jiayu Chen ◽  
Zewei Liu ◽  
Chongxiong Duan ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Surface Area ◽  
Energy Efficient ◽  
Metal Organic Framework ◽  
Bet Surface Area ◽  
Preferential Adsorption ◽  
Metal Organic ◽  
Organic Framework

The separation of ethylene/ethane mixture using energy-efficient technologies is important but challenging. Here, we prepared a Zr-based metal-organic framework (MOF-545) possessing high Brunauer-Emmett-Teller (BET) surface area of 2265.4 m2/g, and...

scholarly journals Correction to “Proton-Conducting Phenolate-Based Zr Metal–Organic Framework: A Joint Experimental–Modeling Investigation”

2016 ◽  
Vol 120 (49) ◽  
pp. 28374-28374 ◽  
Author(s):  
P. G. M. Mileo ◽  
S. Devautour-Vinot ◽  
G. Mouchaham ◽  
F. Faucher ◽  
A. Vimont ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Experimental Modeling ◽  
Proton Conducting ◽  
Metal Organic ◽  
Organic Framework

High Proton Conduction at above 100 °C Mediated by Hydrogen Bonding in a Lanthanide Metal–Organic Framework

2014 ◽  
Vol 136 (35) ◽  
pp. 12444-12449 ◽  
Author(s):  
Qun Tang ◽  
Yiwei Liu ◽  
Shuxia Liu ◽  
Danfeng He ◽  
Jun Miao ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Proton ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Organic Framework

One-step introduction of terminal sulfonic groups into a proton-conducting metal–organic framework by concerted deprotonation–metalation–hydrolysis reaction

2020 ◽  
Vol 49 (29) ◽  
pp. 9953-9956
Author(s):  
Monika Szufla ◽  
Kornel Roztocki ◽  
Anna Krawczuk ◽  
Dariusz Matoga
Keyword(s):  
Metal Organic Framework ◽  
Hydrolysis Reaction ◽  
Proton Conducting ◽  
Metal Organic ◽  
One Step ◽  
Organic Framework

A one-step strategy for introducing terminal sulfonic groups from a hydrolysable precursor is demonstrated for a proton-conducting metal–organic framework.

scholarly journals Hydrogen-Bonding Linkers Yield a Large-Pore, Non-Catenated, Metal-Organic Framework with pcu Topology

Molecules ◽  
2020 ◽  
Vol 25 (3) ◽  
pp. 697 ◽  
Author(s):  
Mohammad S. Yazdanparast ◽  
Victor W. Day ◽  
Tendai Gadzikwa
Keyword(s):  
Hydrogen Bonding ◽  
Pore Volume ◽  
Reliable Method ◽  
Metal Organic Framework ◽  
Low Density ◽  
Paddle Wheel ◽  
Accessible Volume ◽  
New Material ◽  
Metal Organic ◽  
Organic Framework

Pillared paddle-wheel-based metal-organic framework (MOF) materials are an attractive target as they offer a reliable method for constructing well-defined, multifunctional materials. A drawback of these materials, which has limited their application, is their tendency to form catenated frameworks with little accessible volume. To eliminate this disadvantage, it is necessary to investigate strategies for constructing non-catenated pillared paddle-wheel MOFs. Hydrogen-bonding substituents on linkers have been postulated to prevent catenation in certain frameworks and, in this work, we present a new MOF to further bolster this theory. Using 2,2′-diamino-[1,1′-biphenyl]-4,4′-dicarboxylic acid, BPDC-(NH2)2, linkers and dipyridyl glycol, DPG, pillars, we assembled a MOF with pcu topology. The new material is non-catenated, exhibiting large accessible pores and low density. To the best of our knowledge, this material constitutes the pcu framework with the largest pore volume and lowest density. We attribute the lack of catenation to the presence of H-bonding substituents on both linkers.

Ground to conduct: mechanochemical synthesis of a metal–organic framework with high proton conductivity

2015 ◽  
Vol 51 (36) ◽  
pp. 7637-7640 ◽  
Author(s):  
Dariusz Matoga ◽  
Marcin Oszajca ◽  
Marcin Molenda
Keyword(s):  
Proton Conductivity ◽  
Mechanochemical Synthesis ◽  
Metal Organic Framework ◽  
Environmentally Friendly ◽  
High Proton Conductivity ◽  
Proton Conducting ◽  
High Proton ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

A high proton-conducting metal–organic framework (PCMOF) is prepared for the first time by economical and environmentally-friendly mechanochemistry.

pH-Dependent Proton Conducting Behavior in a Metal-Organic Framework Material

2014 ◽  
Vol 53 (32) ◽  
pp. 8383-8387 ◽  
Author(s):  
Won Ju Phang ◽  
Woo Ram Lee ◽  
Kicheon Yoo ◽  
Dae Won Ryu ◽  
BongSoo Kim ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Proton Conducting ◽  
Metal Organic ◽  
Ph Dependent ◽  
Organic Framework
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