Metastable Electrons, High-Mobility Solvent Anions, and Charge Transfer Reactions in Supercritical Carbon Dioxide

2001 ◽  
Vol 105 (19) ◽  
pp. 4520-4530 ◽  
Author(s):  
I. A. Shkrob ◽  
M. C. Sauer
Keyword(s):  
Carbon Dioxide ◽  
Charge Transfer ◽  
Supercritical Carbon Dioxide ◽  
High Mobility ◽  
Transfer Reactions ◽  
Charge Transfer Reactions ◽  
Supercritical Carbon

scholarly journals Charge transfer reactions between gas-phase hydrated electrons, molecular oxygen and carbon dioxide at temperatures of 80–300 K

2016 ◽  
Vol 18 (34) ◽  
pp. 23528-23537 ◽  
Author(s):  
Amou Akhgarnusch ◽  
Wai Kit Tang ◽  
Han Zhang ◽  
Chi-Kit Siu ◽  
Martin K. Beyer
Keyword(s):  
Mass Spectrometry ◽  
Carbon Dioxide ◽  
Charge Transfer ◽  
Quantum Chemistry ◽  
Gas Phase ◽  
Molecular Oxygen ◽  
Transfer Reactions ◽  
Hydrated Electrons ◽  
Charge Transfer Reactions

With a combination of mass spectrometry and quantum chemistry, we derive hydration enthalpies for CO2˙− and O2˙− and show that the charge transfer from CO2˙− to O2 proceeds via a CO4˙− intermediate.

Sign in / Sign up

Export Citation Format

Share Document