Enhanced Li Storage Capacity in 3 nm Diameter SnO2 Nanocrystals Firmly Anchored on Multiwalled Carbon Nanotubes

2011 ◽  
Vol 115 (44) ◽  
pp. 22062-22067 ◽  
Author(s):  
Yun-Ho Jin ◽  
Kyung-Mi Min ◽  
Seung-Deok Seo ◽  
Hyun-Woo Shim ◽  
Dong-Wan Kim
2002 ◽  
Vol 106 (5) ◽  
pp. 963-966 ◽  
Author(s):  
Peng-xiang Hou ◽  
Quan-hong Yang ◽  
Shuo Bai ◽  
Shi-tao Xu ◽  
Min Liu ◽  
...  

2012 ◽  
Vol 2012 ◽  
pp. 1-12 ◽  
Author(s):  
Kuen-Song Lin ◽  
Yao-Jen Mai ◽  
Shin-Rung Li ◽  
Chia-Wei Shu ◽  
Chieh-Hung Wang

The synthesis, identification, and H2storage of multiwalled carbon nanotubes (MWCNTs) have been investigated in the present work. MWCNTs were produced from the catalytic-assembly solvent (benzene)-thermal (solvothermal) route. Reduction of C6Cl6with metallic potassium was carried out in the presence of Co/Ni catalyst precursors at 503–623 K for 12 h. XRD patterns indicated that the abstraction of Cl from hexachlorobenzene and the formation of KCl precipitates were involved in the early stage of the synthesis process of MWCNTs. This result offers further explanation for the formation of MWCNT structure and yield using the solvothermal route depending on the Co/Ni catalyst precursors. The diameter of MWCNTs ranged between 30 and 100 nm and the H2storage capacity of MWCNTs improved when 2.7–3.8 wt% Pd or NaAlH4were doped. The XANES/EXAFS spectra revealed that the Co/Ni catalyst precursors of the MWCNT synthesis were in metallic form and Pd atoms possessed a Pd–Pd bond distance of 2.78 Å with a coordination number of 9.08. Ti-NaAlH4or Pd nanoparticles were dispersed on MWCNTs and facilitated to improve the H2storage capacity significantly with the surface modification process.


2012 ◽  
Vol 2 (6) ◽  
pp. 166-168 ◽  
Author(s):  
Dr.T.Ch.Madhavi Dr.T.Ch.Madhavi ◽  
◽  
Pavithra.P Pavithra.P ◽  
Sushmita Baban Singh Sushmita Baban Singh ◽  
S.B.Vamsi Raj S.B.Vamsi Raj ◽  
...  

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