Sulfidation of Ceria Surfaces from Sulfur and Sulfur Diffusion

2012 ◽  
Vol 116 (15) ◽  
pp. 8417-8425 ◽  
Author(s):  
Zhansheng Lu ◽  
Jolla Kullgren ◽  
Zongxian Yang ◽  
Kersti Hermansson
Keyword(s):  

2018 ◽  
Vol 226 ◽  
pp. 50-68 ◽  
Author(s):  
Matthias Bernhard Lierenfeld ◽  
Zoltán Zajacz ◽  
Olivier Bachmann ◽  
Peter Ulmer


Author(s):  
Maya Radune ◽  
D. Ophir ◽  
A. Lugovskoy ◽  
M. Zinigrad ◽  
Dan Eliezer


2019 ◽  
Vol 321 ◽  
pp. 134713 ◽  
Author(s):  
D.-W. Choi ◽  
M. Ohashi ◽  
C.A. Lozano ◽  
J.W. Vanzee ◽  
P. Aungkavattana ◽  
...  


1977 ◽  
Vol 31 (3) ◽  
pp. 210-213 ◽  
Author(s):  
W. E. Swartz ◽  
D. M. Holloway

Auger electron spectroscopy has been employed to study the diffusion of sulfur and carbon in α-iron. In the temperature range 25 to 500°C carbon preferentially segregates to the surface. From 400 to 700°C sulfur segregates to the surface while carbon is thermally desorbed. An Arrhenius analysis of the sulfur diffusion data yields an activation energy of 14.5 kcal/mol, which is consistent with a grain boundary diffusion process. The kinetics of carbon migration is complicated by the thermal desorption which makes Arrhenius analysis impossible.



1998 ◽  
Vol 83 (11-12 Part 1) ◽  
pp. 1141-1151 ◽  
Author(s):  
K. Tobias Winther ◽  
E. Bruce Watson ◽  
Gerald M. Korenowski


1971 ◽  
Vol 45 (1) ◽  
pp. K81-K84
Author(s):  
P. Brätter ◽  
H. Gobrecht
Keyword(s):  


1999 ◽  
Vol 06 (05) ◽  
pp. 935-940
Author(s):  
R. REIBEL ◽  
S. SCHNEIDER ◽  
H. CRUGUEL ◽  
J. LAPEYRE ◽  
R. J. SMITH

Recent studies using Auger Electron Spectroscopy (AES) on polycrystalline titanium surfaces led to the discovery of a temperature-dependent phenomenon for the removal of sulfur using oxygen exposures. It was seen that at temperatures greater than 200°C and pressures lower than 10-7 Torr O 2 the rate of sulfur removal from the surface was decreased significantly. The decrease in this rate of sulfur removal can be linked to several factors, including the temperature-enhanced diffusion of sulfur to the surface and the temperature-enhanced diffusion of oxygen into the bulk. By varying the pressure of oxygen and the temperature of the substrate and by monitoring the surface with AES we were able to identify the significant factors. A kinetic model for the two surface species is discussed and fit to the experimental results. This kinetic model includes physical parameters for such things as the activation energy for the sulfur diffusion to the surface as well as sticking coefficients for oxygen on the surface. Through this model the relevant factors for the decrease in the rate of sulfur removal are examined.



2018 ◽  
Vol 45 (6) ◽  
pp. 0602005 ◽  
Author(s):  
陈茹 Chen Ru ◽  
虞钢 Yu Gang ◽  
何秀丽 He Xiuli ◽  
甘政涛 Gan Zhengtao ◽  
李少霞 Li Shaoxia




1999 ◽  
Vol 69-70 ◽  
pp. 443-448 ◽  
Author(s):  
N. Engler ◽  
H.S. Leipner ◽  
R.F. Scholz ◽  
P. Werner ◽  
F. Syrowatka ◽  
...  


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