Structure and Morphology Evolution of Hematite (α-Fe2O3) Nanoparticles in Forced Hydrolysis of Ferric Chloride

2008 ◽  
Vol 112 (25) ◽  
pp. 9203-9208 ◽  
Author(s):  
Wei Wang ◽  
Jane Y. Howe ◽  
Baohua Gu
2012 ◽  
Vol 210 ◽  
pp. 357-362 ◽  
Author(s):  
Chao-An Chiu ◽  
Kiril D. Hristovski ◽  
Richard Dockery ◽  
Kyle Doudrick ◽  
Paul Westerhoff

CrystEngComm ◽  
2011 ◽  
Vol 13 (24) ◽  
pp. 7293 ◽  
Author(s):  
Baoliang Lv ◽  
Yao Xu ◽  
Dong Wu ◽  
Yuhan Sun

Author(s):  
Marko Robić ◽  
Mira Ristić ◽  
Stjepko Krehula ◽  
Svetozar Musić

2002 ◽  
Vol 726 ◽  
Author(s):  
Corine Gerardin ◽  
Valérie Buissette ◽  
François Gaudemet ◽  
Olivier Anthony ◽  
Nicolas Sanson ◽  
...  

AbstractDouble hydrophilic block copolymers were used to control the growth of inorganic particles and directly prepare hybrid colloidal suspensions. Colloids of metal hydrous oxides were obtained by forced hydrolysis of metal ions in presence of the copolymers. The block copolymers contain a metal-complexing polyelectrolyte block and a stabilizing neutral block. The role of the first block is to ensure a controlled growth of the inorganic phase, while simultaneously, the second block ensures the colloidal stabilization. Phase diagrams presenting the conditions under which precipitation is inhibited are established. The nanoparticles are then characterized in terms of sizes, morphologies and surface charges. The main parameters controlling the size were identified: the copolymer-to-metal ratio and the metal prehydrolysis ratio. The synthesis steps were characterized. First, a key step of induced micellization of the hydrophilic copolymers leads to hybrid core-shell assemblies. The second step consists in mineralization of the micellar core. The suspension polycondensation leads to hairy particles whose morphologies depend on the nature of the metal and on synthesis parameters.


2017 ◽  
Vol 229 ◽  
pp. 96-103 ◽  
Author(s):  
Hongdan Zhang ◽  
Guangying Ye ◽  
Yutuo Wei ◽  
Xin Li ◽  
Aiping Zhang ◽  
...  

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