Segregation of chain ends to polymer melt surfaces and interfaces

1993 ◽  
Vol 26 (3) ◽  
pp. 561-562 ◽  
Author(s):  
W. Zhao ◽  
X. Zhao ◽  
M. H. Rafailovich ◽  
J. Sokolov ◽  
R. J. Composto ◽  
...  
Keyword(s):  
Polymer Melt ◽  
Surfaces And Interfaces

Molecular-Dynamics Simulations of Polymer Surfaces and Interfaces

MRS Bulletin ◽  
1997 ◽  
Vol 22 (1) ◽  
pp. 27-31 ◽  
Author(s):  
Gary S. Grest ◽  
Martin-D. Lacasse ◽  
Michael Murat
Keyword(s):  
Computer Simulations ◽  
Critical Role ◽  
Lattice Models ◽  
Polymer Melt ◽  
Theoretical Models ◽  
Single Chain ◽  
Surfaces And Interfaces ◽  
Lattice Polymer ◽  
Polymer Models ◽  
Dynamics Simulations

From a single chain in a dilute solution to an entangled polymer melt, from bulk systems to more complex interfacial problems, computer simulations have played a critical role not only in testing the basic assumptions of various theoretical models but also in interpreting experimental results. Early computer simulations of polymers were mostly carried out on a lattice using Monte Carlo methods. This approach has led to significant progress in recent years and will continue to do so in many areas. In some cases however, for example in the study of shear, lattice models have serious limitations. For this reason and also due to the availability of more powerful computers, continuum, off-lattice polymer models have recently become popular. In this article, we review some of the recent progress in studying polymers at surfaces and interfaces using continuum models.

Polymer Morphology Revealed by Staining Techniques

1981 ◽  
Vol 39 ◽  
pp. 340-341
Author(s):  
A. C. Reimschuessel ◽  
V. Kramer
Keyword(s):  
Polymer Melt ◽  
Nylon 6 ◽  
Morphological Features ◽  
Negative Staining ◽  
Polymer Morphology ◽  
Crystallizable Polymer ◽  
Staining Techniques ◽  
Long Chain

Staining techniques can be used for either the identification of different polymers or for the differentiation of specific morphological domains within a given polymer. To reveal morphological features in nylon 6, we choose a technique based upon diffusion of the staining agent into accessible regions of the polymer.When a crystallizable polymer - such as nylon 6 - is cooled from the melt, lamellae form by chainfolding of the crystallizing long chain macromolecules. The regions between adjacent lamellae represent the less ordered amorphous domains into which stain can diffuse. In this process the lamellae will be “outlined” by the dense stain, giving rise to contrast comparable to that obtained by “negative” staining techniques.If the cooling of the polymer melt proceeds relatively slowly - as in molding operations - the lamellae are usually arranged in a radial manner. This morphology is referred to as spherulitic.

Inelastic scattering at surfaces and interfaces

1986 ◽  
Vol 44 ◽  
pp. 392-393
Author(s):  
R. H. Ritchie ◽  
A. Howie
Keyword(s):  
Inelastic Scattering ◽  
Surface Properties ◽  
Correlation Energy ◽  
Condensed Matter ◽  
Charged Particles ◽  
Condensed Matter Physics ◽  
Optical Phonons ◽  
Exchange Correlation ◽  
Surfaces And Interfaces ◽  
Inelastic Interactions

An important part of condensed matter physics in recent years has involved detailed study of inelastic interactions between swift electrons and condensed matter surfaces. Here we will review some aspects of such interactions.Surface excitations have long been recognized as dominant in determining the exchange-correlation energy of charged particles outside the surface. Properties of surface and bulk polaritons, plasmons and optical phonons in plane-bounded and spherical systems will be discussed from the viewpoint of semiclassical and quantal dielectric theory. Plasmons at interfaces between dissimilar dielectrics and in superlattice configurations will also be considered.

Ultramicrotomy as a Technique for Materials Specimen Preparation

1990 ◽  
Vol 48 (2) ◽  
pp. 428-429
Author(s):  
S.R. Glanvill
Keyword(s):  
Materials Science ◽  
Structural Information ◽  
Specimen Preparation ◽  
Preparation Technique ◽  
Cross Sectional ◽  
Surfaces And Interfaces ◽  
Beam Analysis ◽  
Flat Embedding ◽  
20 Nm ◽  
Sectional Analysis

This paper summarizes the application of ultramicrotomy as a specimen preparation technique for some of the Materials Science applications encountered over the past two years. Specimens 20 nm thick by hundreds of μm lateral dimension are readily prepared for electron beam analysis. Materials examined include metals, plastics, ceramics, superconductors, glassy carbons and semiconductors. We have obtain chemical and structural information from these materials using HRTEM, CBED, EDX and EELS analysis. This technique has enabled cross-sectional analysis of surfaces and interfaces of engineering materials and solid state electronic devices, as well as interdiffusion studies across adjacent layers.Samples are embedded in flat embedding moulds with Epon 812 epoxy resin / Methyl Nadic Anhydride mixture, using DY064 accelerator to promote the reaction. The embedded material is vacuum processed to remove trapped air bubbles, thereby improving the strength and sectioning qualities of the cured block. The resin mixture is cured at 60 °C for a period of 80 hr and left to equilibrate at room temperature.

ANTISYMMETRY OF SURFACES AND INTERFACES IN POLAR MATERIALS

1982 ◽  
Vol 43 (C1) ◽  
pp. C1-57-C1-62 ◽  
Author(s):  
R. C. Pond ◽  
D. B. Holt
Keyword(s):  
Surfaces And Interfaces ◽  
Polar Materials

A Study on Polymer Particle Flow in a Disk Zone of a Screw-Disk Extruder

2014 ◽  
Vol 35 (1) ◽  
pp. 121-135 ◽  
Author(s):  
Tomasz Rydzkowski ◽  
Iwona Michalska-Pożoga
Keyword(s):  
Mechanical Properties ◽  
Computer Simulations ◽  
Particle Motion ◽  
Polymer Melt ◽  
Experimental Tests ◽  
Polymer Particle ◽  
Particle Flow ◽  
Material Particle ◽  
Motion Trajectories ◽  
Stretching Effect

Abstract The paper presents the summary of research on polymer melt particle motion trajectories in a disc zone of a screw-disk extruder. We analysed two models of its structure, different in levels of taken simplifications. The analysis includes computer simulations of material particle flow and results of experimental tests to determine the properties of the resultant extrudate. Analysis of the results shows that the motion of melt in the disk zone of a screw-disk extruder is a superposition of pressure and dragged streams. The observed trajectories of polymer particles and relations of mechanical properties and elongation of the molecular chain proved the presence of a stretching effect on polymer molecular chains.

POLYMER MELT FLOW IN ASYMMETRIC SUDDEN EXPANSIONS: A NUMERICAL STUDY

2016 ◽  
Author(s):  
Felipe Oliveira Basso ◽  
Paulo Zdanski ◽  
Diego Beppler ◽  
Miguel Vaz Jr.
Keyword(s):  
Numerical Study ◽  
Polymer Melt ◽  
Melt Flow
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