Synthesis of N-[(3'-Hydroxy-2',3'-dicarboxy)- ethyl]chitosan:A New, Water-Soluble Chitosan Derivative

1995 ◽  
Vol 28 (26) ◽  
pp. 8865-8867 ◽  
Author(s):  
James V. Gruber ◽  
Venceslav Rutar ◽  
Jagdeesh Bandekar ◽  
Peter N. Konish

2020 ◽  
Vol 38 (3-4) ◽  
pp. 113-126
Author(s):  
Qiaoling Xie ◽  
Gaojie Liang ◽  
Tao Lin ◽  
Fuming Chen ◽  
Dandan Wang ◽  
...  

A study on selective chelating precipitation of palladium metal from real electroplating wastewater using chitosan and its water-soluble derivative was conducted. The pH parameter, the concentrations of chitosan and its water-soluble derivative and the chelating precipitation time were experimentally investigated, and the optimum conditions were determined. The results revealed that both chitosan and its water-soluble derivative acted as chelating precipitation agents. Rapid chelating precipitation occurred when chitosan was added to real electroplating wastewater containing the chitosan derivative, thereby improving removal efficiency of palladium in different forms up to 95% under the optimum condition of 0.2 g/L chitosan and 0.16 mg/L derivative at pH 2.5. Then, dissolution experiments showed that chelating precipitation products could be dissolved in aqua regia. Additionally, selective chelating precipitation of palladium by chitosan and its derivative was characterized using X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. Thus, it can be concluded that the combined utilization of chitosan and its water-soluble derivative is a promising approach method for the removal of different forms of palladium from real electroplating wastewater.



2014 ◽  
Vol 16 (7) ◽  
Author(s):  
Fábio P. Ramanery ◽  
Alexandra A. P. Mansur ◽  
Fernanda G. L. M. Borsagli ◽  
Herman S. Mansur




2010 ◽  
Vol 47 (5) ◽  
pp. 696-699 ◽  
Author(s):  
Mingyan Jiang ◽  
Kemin Wang ◽  
John F. Kennedy ◽  
Jun Nie ◽  
Qiang Yu ◽  
...  


2013 ◽  
Vol 11 (3) ◽  
pp. 410-418 ◽  
Author(s):  
Gurpreet Kaur Khaira ◽  
Rashmi Kumariya ◽  
Manmohan Chibber ◽  
Moushumi Ghosh

The antibacterial activity of a water-soluble chitosan derivative prepared by chemical modification to quaternary ammonium compound N,N,N-trimethylchitosan (TC) was investigated against four selected waterborne pathogens: Aeromonas hydrophila ATCC 35654, Yersinia enterocolitica ATCC 9610, Listeria monocytogenes ATCC 19111 and Escherichia coli O157:H7 ATCC 32150. An inactivation of 4 log CFU/ml of all waterborne pathogens was noted for the quaternized chitosan as compared with chitosan over a short contact time (30 min) and low dosage (4.5 ppm) at ambient temperature. A marked increase in glucose level, protein content and lactate dehydrogenase (LDH) activity was observed concurrently in the cell supernatant to be a major bactericidal mechanism. The results suggest that the TC derivative may be a promising commercial substitute for acid-soluble chitosan for rapid and effective disinfection of water.



2018 ◽  
Vol 26 (4(130)) ◽  
pp. 116-121 ◽  
Author(s):  
Wei Zhang ◽  
Xinlan Dai ◽  
Jinjie Zhou

In this study, a novel fibre-reactive nanoparticle was synthesised in three steps. First a water-soluble chitosan derivative, N-[(2-hydroxy-3-trimethylammonium)propyl] chitosan chloride (short for HTCC), was prepared by reacting chitosan with 2,3-epoxypropyltrimethylammonium chloride. Second the HTCC was further modified by reacting it with N-(hydroxymethyl)- acrylamide to prepare a fibre-reactive chitosan derivative, O-methyl acrylamide quaternary ammonium salt of chitosan (short for NMA-HTCC), which can form covalent bonds with cellulose fibre under alkaline conditions. Thirdly NMA-HTCC nanoparticles were prepared by the ionotropic gelation reaction method. The particle size and TEM researches indicated that the globular NMA-HTCC nanoparticle with a size distribution of 15 - 50 nm was successfully prepared and presented good dispersity and stability. Then the NMA-HTCC nanoparticle was used for the textile finishing of cotton fabric. The modified cotton fabric demonstrated excellent durable wrinkle-resistance and antibacterial activity against Staphylococcus aureus and Escherichia coli, even after 50 repeated launderings. Moreover the shrinkage-resistance of the modified cotton fabric was distinctly improved, and the contact angle was slightly larger, while the whiteness and mechanical properties had not changed in an obvious way.





RSC Advances ◽  
2022 ◽  
Vol 12 (2) ◽  
pp. 1095-1104
Author(s):  
Mahmoud H. Abu Elella ◽  
Ahmed Esmail Shalan ◽  
Magdy W. Sabaa ◽  
Riham R. Mohamed

This study aimed to show the efficacy of the one-pot green biosynthesis of nanocomposites as effective antimicrobial agents based on a water-soluble biodegradable polysaccharide and silver nitrate (AgNO3).



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