In Situ Consolidation of Thermoplastic Prepreg by Generating Harmonic Oscillations on the Consolidation Roller

Automation technologies such as Automated Fiber Placement (AFP) or Automated Tape Laying (ATL) are widely used in the aerospace industry today. However, these processes can still be further improved for higher productivity. Fiber-reinforced plastics allow the production of components with extremely high specific strength and stiffness. Regarding the automated manufacturing processes, the thermoplastic tape placement offers efficiency improvements compared to the nowadays more commonly used thermoset tape placement, especially through the substitution of the expensive and time-consuming autoclave process. The consolidation of thermoplastic Prepregs is achieved with an elastic or rigid roller according to the current state of the art. The Prepregs must be consolidated precisely on the substrate or on top of each other. The most important process parameters for high-quality laminate structure with low porosity are the control of heat source, consolidation force, consolidation roll speed, and tape tension. The efficiency of the AFP process can generally be improved by increasing the speed of the consolidation roller. By increasing the speed of the consolidation roller, porosity is increased and mechanical properties of the laminate are reduced significantly due to the short contact time between consolidation roller and Prepregs. This study investigates a process that can reduce these challenges by increasing the contact time and force duration of the consolidation roller on the Prepregs. The consolidation roller in this study is additionally to be driven by the harmonic oscillations. The new method allows the consolidation roller to oscillate forward and backward during the fiber placement process. This creates another force vector in addition to the compressive force of the consolidation roller and increases the bonding strength between the layers.

Improvised centrifugal spinning for the production of polystyrene microfibers from waste expanded polystyrene foam and its potential application for oil adsorption

A straightforward approach to recycle waste expanded polystyrene (EPS) foam to produce polystyrene (PS) microfibers using the improvised centrifugal spinning technique is demonstrated in this work. A typical benchtop centrifuge was improvised and used as a centrifugal spinning device. The obtained PS microfibers were characterized for their potential application for oil adsorption. Fourier transform infrared spectroscopy results revealed similarity on the transmission bands of EPS foam and PS microfibers suggesting the preservation of the EPS foam’s chemical composition after the centrifugal spinning process. Scanning electron microscopy displayed well-defined fibers with an average diameter of 3.14 ± 0.59 μm. At the same time, energy dispersive X-ray spectroscopy revealed the presence of carbon and oxygen as the primary components of the fibers. Contact angle (θCA) measurements showed the more enhanced hydrophobicity of the PS microfiber (θCA = 100.2 ± 1.3°) compared to the untreated EPS foam (θCA = 92.9 ± 3.5°). The PS microfiber also displayed better oleophilicity compared to EPS foam. Finally, the fabricated PS microfibers demonstrated promising potential for oil removal in water with a calculated sorption capacity value of about 15.5 g/g even at a very short contact time. The fabricated PS fiber from the waste EPS foam may provide valuable insights into the valorization of polymeric waste materials for environmental and other related applications.

Authentication and Billing for Dynamic Wireless EV Charging in an Internet of Electric Vehicles

Dynamic wireless charging (DWC) is a promising technology to charge Electric Vehicles (EV) using on-road charging segments (CS), also known as DWC pads. In order to ensure effective utilization of this on-the-road charging service, communication and coordination need to be established between the EVs and the different network entities, thereby forming an Internet of Electric Vehicles (IoEV). In an IoEV, EVs can utilize different V2X communication modes to enable charging scheduling, load management, and reliable authentication and billing services. Yet, designing an authentication scheme for dynamic EV charging presents significant challenges given the mobility of the EVs and the short contact time between the EVs and the charging segments. Accordingly, this work proposes a fast, secure and lightweight authentication scheme that allows only authentic EVs with valid credentials to charge their batteries while ensuring secure and fair payments. The presented scheme starts with a key pre-distribution phase between the charging service company (CSC) and the charging pad owner (PO), followed by a hash chain and digital signature-based registration and authentication phase between the EV and the CSC, before the EV reaches the beginning of the charging lane. These preliminary authentication phases allow the authentication between the EVs and the charging segments to be performed using simple hash key verification operations prior to charging activation, which reduces the computational cost of the EVs and the CS. Symmetric and asymmetric key cryptography are utilized to secure the communication between the different network entities. Analysis of the computational and transmission time requirements of the proposed authentication scheme shows that, for an EV traveling at 60 km/h to start charging at the beginning of the charging lane, the authentication process must be initiated at least 1.35 m ahead of the starting point of the lane as it requires ≃81 ms to be completed.

Nghiên cứu chế tạo xúc tác zeolite Y đa mao quản ứng dụng cho quá trình cracking xúc tác tầng sôi nhằm nâng cao hiệu quả chế biến nguyên liệu cặn dầu nặng

Bài báo trình bày kết quả nghiên cứu và đánh giá xúc tác zeolite Y đa mao quản cho quá trình cracking nguyên liệu cặn dầu nặng của Nhà máy Lọc dầu Dung Quất. Kết quả nghiên cứu cho thấy, sau khi xử lý acid, kiềm ở điều kiện tối ưu (EDTA 0,1 M và NaOH 0,1 M) và bền hóa bằng trao đổi với ion lanthanum và ammonium, xúc tác zeolite Y đa mao quản thu được có diện tích bề mặt mao quản trung bình đạt 140 m2/g, phân bố mao quản trung bình tập trung khoảng 14 nm, tính chất acid được cải thiện (2474 μmol NH3/g). Hoạt tính của zeolite Y đa mao quản được đánh giá trên hệ thiết bị SCT-MAT (Short-Contact-Time Microactivity Test) của Grace. Mẫu xúc tác DMQ-Yên Thế chế tạo trên cơ sở zeolite Y đa mao quản sau khi giảm hoạt tính cho độ chuyển hóa đạt khoảng 74% khối lượng, hiệu suất sản phẩm có lợi như xăng và propylene đạt lần lượt là 48% khối lượng và 7% khối lượng. So với hệ xúc tác thương mại cùng loại (GRX-3, Grace), hệ xúc tác DMQ-Y cho hiệu suất propylene cao hơn khoảng 2% khối lượng. Kết quả này cho thấy mao quản trung bình trong xúc tác zeolite Y đa mao quản đã tăng khả năng cracking phần nặng thành các sản phẩm có lợi, đồng thời hạn chế sự chuyển hóa thứ cấp không mong muốn, giúp nâng cao hiệu suất propylene.

Emulsion-Based Multicompartment Vaginal Drug Carriers: From Nanoemulsions to Nanoemulgels

In order to overcome the limitations associated with vaginal administration of drugs, e.g., the short contact time of the drug form with the mucosa or continuous carrier wash-out, the development of new carriers for gynecological use is necessary. Furthermore, high individual anatomical and physiological variability resulting in unsatisfactory therapeutic efficacy of lipophilic active substances requires application of multicompartment drug delivery systems. This manuscript provides an up-to-date comprehensive review of the literature on emulsion-based vaginal dosage forms (EVDF) including macroemulsions, microemulsions, nanoemulsions, multiple emulsions and self-emulsifying drug delivery systems. The first part of the paper discusses (i) the influence of anatomical-physiological conditions on therapeutic efficacy of drug forms after local and systemic administration, (ii) characterization of EVDF components and the manufacturing techniques of these dosage forms and (iii) methods used to evaluate the physicochemical and pharmaceutical properties of emulsion-based vaginal dosage forms. The second part of the paper presents (iv) the results of biological and in vivo studies as well as (v) clinical evaluation of EVDF safety and therapeutic efficacy across different indications.

Oscillatory Behaviour of Ni Supported on ZrO2 in the Catalytic Partial Oxidation of Methane as Determined by Activation Procedure

Ni/ZrO2 catalysts, active and selective for the catalytic partial oxidation of methane to syngas (CH4-CPO), were prepared by the dry impregnation of zirconium oxyhydroxide (Zhy) or monoclinic ZrO2 (Zm), calcination at 1173 K and activation by different procedures: oxidation-reduction (ox-red) or direct reduction (red). The characterization included XRD, FESEM, in situ FTIR and Raman spectroscopies, TPR, and specific surface area measurements. Catalytic activity experiments were carried out in a flow apparatus with a mixture of CH4:O2 = 2:1 in a short contact time. Compared to Zm, Zhy favoured the formation of smaller NiO particles, implying a higher number of Ni sites strongly interacting with the support. In all the activated Ni/ZrO2 catalysts, the Ni–ZrO2 interaction was strong enough to limit Ni aggregation during the catalytic runs. The catalytic activity depended on the activation procedures; the ox-red treatment yielded very active and stable catalysts, whereas the red treatment yielded catalysts with oscillating activity, ascribed to the formation of Niδ+ carbide-like species. The results suggested that Ni dispersion was not the main factor affecting the activity, and that active sites for CH4-CPO could be Ni species at the boundary of the metal particles in a specific configuration and nuclearity.

Heat transfer, physiological responses, and subjective perceptions during short contact time with wood or other materials

This study investigates the physiological responses and subjective perceptions of touching wood. In particular, it focuses on their respective relationships with the amount of heat transfer across the hand–material interface during contact. The study participants included 55 university students (20 females and 35 males) who gave written informed consent. The participants’ blood pressure, pulse rate, and cerebral blood hemoglobin concentrations were measured continuously for 90 s while they gently held vertical bar-shaped specimens of Japanese cypress (Chamaecyparis obtusa), Japanese oak (Quercus crispula), polyethylene, and aluminum. The specimens also included wood with a surface coating. We measured subjective warmth and comfort as well as the heat flux between the palm and the surface of the material. The wooden materials were rated as significantly warmer compared to aluminum and polyethylene, regardless of the wood species (cypress or oak) or its coating; this result corresponds with smaller heat transfers in the wooden materials. Additionally, the wooden materials were more comfortable to hold as compared to the aluminum bar. Based on the changes in blood pressure, touching Japanese cypress and uncoated Japanese oak were interpreted to induce less physiological stress. Therefore, we can conclude that wood, with lower thermal conductivity, feels warm, and it causes relatively smaller physiological changes compared to other materials with higher thermal conductivity. Thus, they may present less physiological burdens when touched.

Non-Premixed Reactive Volatilization Reactor for Catalytic Partial Oxidation of Low Volatility Fuels at a Short Contact Time

This work presents a novel non-premixed opposed-flow reactive volatilization reactor that simultaneously vaporizes and partially oxidizes low volatility liquid hydrocarbons at a short contact time (<12 ms). In the reactor,...