scholarly journals Transient birefringence of liquids induced by terahertz electric-field torque on permanent molecular dipoles

2017 ◽  
Vol 8 (1) ◽  
Author(s):  
Mohsen Sajadi ◽  
Martin Wolf ◽  
Tobias Kampfrath

Abstract Collective low-frequency molecular motions have large impact on chemical reactions and structural relaxation in liquids. So far, these modes have mostly been accessed indirectly by off-resonant optical pulses. Here, we provide evidence that intense terahertz (THz) pulses can resonantly excite reorientational-librational modes of aprotic and strongly polar liquids through coupling to the permanent molecular dipole moments. We observe a significantly enhanced response because the transient optical birefringence is up to an order of magnitude higher than obtained with optical excitation. Frequency-dependent measurements and a simple analytical model indicate that the enhancement arises from resonantly driven librations and their coupling to reorientational motion, assisted by the pump field and/or a cage translational mode. Our results open up the path to applications such as efficient molecular alignment, enhanced transient Kerr signals and systematic resonant nonlinear THz spectroscopy of the coupling between intermolecular modes in liquids.

2021 ◽  
Author(s):  
Shilin Chen ◽  
Chris Propes ◽  
Curtis Lanning ◽  
Brad Dunbar

Abstract In this paper we present a new type of vibration related to PDC bits in drilling and its mitigation: a vibration coupled in axial, lateral and torsional directions at a high common frequency (3D coupled vibration). The coupled frequency is as high as 400Hz. 3D coupled vibration is a new dysfunction in drilling operation. This type of vibration occurred more often than stick-slip vibration. Evidences reveal that the coupled frequency is an excitation frequency coming from the bottom hole pattern formed in bit/rock interaction. This excitation frequency and its higher order harmonics may excite axial resonance and/or torsional resonance of a BHA. The nature of 3D coupled vibration is more harmful than low frequency stick-slip vibration and high frequency torsional oscillation (HFTO). The correlation between the occurrence of 3D coupled vibration and bit design characteristics is studied. Being different from prior publications, we found the excitation frequency is dependent on bit design and the occurrence of 3D coupled vibration is correlated with bit design characteristics. New design guidlines have been proposed to reduce or to mitigate 3D coupled vibration.


2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
Olivier Pottiez ◽  
Rodrigo Paez-Aguirre ◽  
Hector Santiago-Hernandez ◽  
Manuel Duran-Sanchez ◽  
Baldemar Ibarra-Escamilla ◽  
...  

We propose in this work a technique for determining the amplitude distribution of a wave packet containing a large number of short optical pulses with different amplitudes. The technique takes advantage of the fast response of the optical Kerr effect in a fiber nonlinear optical loop mirror (NOLM). Under some assumptions, the statistics of the pulses can be determined from the energy transfer characteristic of the packet through the NOLM, which can be measured with a low-frequency detection setup. The statistical distribution is retrieved numerically by approximating the solution of a system of nonlinear algebraic equations using the least squares method. The technique is demonstrated numerically in the case of a packet of solitons.


2020 ◽  
Author(s):  
Leila Abylgazina ◽  
Irena Senkovska ◽  
Sebastian Ehrling ◽  
Volodymyr Bon ◽  
Petko Petkov ◽  
...  

The pillared layer framework DUT-8(Zn) (Zn<sub>2</sub>(2,6-ndc)<sub>2</sub>(dabco), 2,6-ndc = 2,6-naphthalenedicarboxylate, dabco = 1,4-diazabicyclo-[2.2.2]-octane, DUT = Dresden University of Technology) is a prototypical switchable MOF, showing characteristic adsorption and desorption induced open phase (<i>op</i>) to closed phase (<i>cp</i>) transformation associated with huge changes in cell volume. We demonstrate switchability strongly depends on a framework-specific critical particle size (d<i><sub>crit</sub></i>). The solvent removal process (pore desolvation stress contracting the framework) significantly controls the <i>cp</i>/<i>op</i> ratio after desolvation and, subsequently, the adsorption induced switchability characteristics of the system. After desolvation, the dense <i>cp</i> phase of DUT-8(Zn) shows no adsorption-induced reopening and therefore is non-porous for N<sub>2</sub> at 77 K and CO<sub>2</sub> at 195 K. However, polar molecules with a higher adsorption enthalpy, such as the polar molecules such as chloromethane at 249 K and dichloromethane (DCM) at 298 K can reopen the macro-sized crystals upon adsorption. For macro-sized particles, the outer surface energy is negligible and only the type of metal (Zn, Co, Ni) controls the DCM-induced gate opening pressure. The framework stiffness increases from Zn to Ni as confirmed by DFT calculations, X-ray crystal structural analyses, and low frequency Raman spectroscopy. The partial disintegration of the Zn based node hinges produces an overall increased stabilization of<i> cp </i>vs. <i>op</i> phase shifts the critical particle size at which switchability starts to become suppressed to even lower values (d<i><sub>crit</sub></i> < 200 nm) as compared to the Ni-based system (<i>d<sub>crit</sub></i> ≈ 500 nm). Hence, the three factors affecting switchability (energetics of the empty host, (<i>E<sub>op</sub>-E<sub>cp</sub></i>) (I), particle size (II), and desolvation stress (III)) appear to be of the same order of magnitude and should be considered collectively, not individually.


2020 ◽  
Vol 09 (04) ◽  
pp. 2050019
Author(s):  
H. C. Chiang ◽  
T. Dyson ◽  
E. Egan ◽  
S. Eyono ◽  
N. Ghazi ◽  
...  

Measurements of redshifted 21[Formula: see text]cm emission of neutral hydrogen at [Formula: see text][Formula: see text]MHz have the potential to probe the cosmic “dark ages,” a period of the universe’s history that remains unobserved to date. Observations at these frequencies are exceptionally challenging because of bright Galactic foregrounds, ionospheric contamination, and terrestrial radio-frequency interference. Very few sky maps exist at [Formula: see text][Formula: see text]MHz, and most have modest resolution. We introduce the Array of Long Baseline Antennas for Taking Radio Observations from the Sub-Antarctic (ALBATROS), a new experiment that aims to image low-frequency Galactic emission with an order-of-magnitude improvement in resolution over existing data. The ALBATROS array will consist of antenna stations that operate autonomously, each recording baseband data that will be interferometrically combined offline. The array will be installed on Marion Island and will ultimately comprise 10 stations, with an operating frequency range of 1.2–125[Formula: see text]MHz and maximum baseline lengths of [Formula: see text][Formula: see text]km. We present the ALBATROS instrument design and discuss pathfinder observations that were taken from Marion Island during 2018–2019.


2013 ◽  
Vol 641-642 ◽  
pp. 371-376 ◽  
Author(s):  
Shi Sha Zhu ◽  
Xue Peng Qian ◽  
Hao He ◽  
Quan Fu Zhang

When the Electrorheological elastomer (ERE) is embedded into intelligence structure system, the structure damping and stiffness of the system can be changed quickly and reversibly under an external electric field. Thus, the application of the Electrorheological elastomer in the active and passive hybrid control of structural vibration has already attracted people's wide attention. In this paper, three types of ER elastomer were prepared based on barium titanate, starch, then the microstructure of ER elastomer was observed and the mechanical properties were analyzed; a shear mode ERE shock absorber was designed, the vibration response performance of which was experimentally evaluated under various excitation frequency with or without the applied field. The experimental results showed that the damping and stiffness of the shock absorber could be modified with a changing external electric field, whose macro-features was that the damping coefficient increased with the increase of the electric field, and the damping effect in the high frequency was better than in the low frequency.


Author(s):  
Kyoyul Oh ◽  
Ali H. Nayfeh

Abstract We experimentally investigated nonlinear combination resonances in a graphite-epoxy cantilever plate having the configuration (–75/75/75/ – 75/75/ – 75)s. As a first step, we compared the natural frequencies and mode shapes obtained from the finite-element and experimental modal analyses. The largest difference in the obtained frequencies was 2.6%. Then, we transversely excited the plate and obtained force-response and frequency-response curves, which were used to characterize the plate dynamics. We acquired time-domain data for specific input conditions using an A/D card and used them to generate time traces, power spectra, pseudo-state portraits, and Poincaré maps. The data were obtained with an accelerometer monitoring the excitation and a laser vibrometer monitoring the plate response. We observed the external combination resonance Ω≈12(ω2+ω5) and the internal combination resonance Ω≈ω8≈12(ω2+ω13), where the ωi are the natural frequencies of the plate and Ω is the excitation frequency. The results show that a low-amplitude high-frequency excitation can produce a high-amplitude low-frequency motion.


2021 ◽  
Author(s):  
Felix Jungmann ◽  
Jens Teiser ◽  
Maximilian Kruss ◽  
Tobias Steinpilz ◽  
Kolja Joeris ◽  
...  

&lt;p&gt;In early phases of planet formation, bouncing and fragmentation barriers still represent major obstacles. Beginning at micrometer, dust can readily grow to sub-millimeter size in collisions due to cohesion before bouncing prevails. Later, streaming instabilities trigger further growth which might finally results into planetesimal formation by gravitational collapse. However, for streaming instabilities sub-millimeter grains might be too small, therefore there is gap of at least 1 order of magnitude in size which needs to be bridged.&lt;/p&gt; &lt;p&gt;Here, we present our ongoing work how to bridge this gap by charge moderated aggregation [1]. When two (dielectric) grains collide they charge. This tribocharging or collisional charging is omnipresent in nature. We designed drop tower experiments in which we generated charges on glass and basalt grains by collisions in a shaker. In microgravity, the particle trajectories and collisions were observed, and charges were measured by applying an electric field.&lt;/p&gt; &lt;p&gt;In early work, we analyzed millimeter-sized glass grain collisions with a copper plate. The coefficient of restitution increased with the charge on a single grain due to mirror charge forces. That means highly charged grains tend to stick more easily to surfaces than uncharged grains. The velocity where sticking is possible was increased by a factor of 100 up to several dm/s [2].&lt;br /&gt;&amp;#160;&lt;br /&gt;More recently, we used half millimeter basalt spheres and observed sticking events at several cm/s among grains themselves [3]. This is also way higher than predicted by adhesion. In a number of cases, we could observe the sequential formation of aggregates of up to ten single grains. During approach the grains are accelerated due to net charge Coulomb forces but likely also due to higher order charges on the surfaces in agreement to earlier measurements of strong permanent dipole moments [4]. Attraction increases collision cross-sections and the growth is sped up. Growth only stopped by the end of microgravity [3].&amp;#160;&lt;/p&gt; &lt;p&gt;To observe the formation of still larger aggregates we developed a new setup, in which a dense cloud of 150 &amp;#181;m diameter basalt grains was continuously agitated slightly under microgravity and in vacuum. Here, the growth of a giant aggregate of centimeter size was observed collecting nearly all material in one cluster [5].&lt;/p&gt; &lt;p&gt;To conclude, in experiments under various conditions, we see strong evidence that electrostatic charges on grains are able to conquer the bouncing barrier. We observed the bottom-up growth tracking individual particles, stable clusters emerging from dense regions and the formation of giant clusters during agitation. These are all bricks in the wall giving evidence that collisional charging might play a crucial role in planet formation.&lt;/p&gt; &lt;p&gt;&lt;strong&gt;References:&lt;/strong&gt;&lt;/p&gt; &lt;p&gt;[1] Steinpilz, T.; Joeris, K.; Jungmann, F.; Wolf, D.; Brendel, L.; Teiser, J.; Shinbrot, T.; Wurm, G. Nature Physics 2020a, 16, 225-229.&lt;/p&gt; &lt;p&gt;[2] Jungmann, F.; Steinpilz, T.; Teiser, J.; Wurm, G. Journal of Physics Communications 2018, 2 095009, 095009.&lt;/p&gt; &lt;p&gt;[3] Jungmann, F.;Wurm, G. Astronomy and Astrophysics 2021, DOI: https://doi.org/10.1051/0004-6361/202039430.&lt;/p&gt; &lt;p&gt;[4] Steinpilz, T.; Jungmann, F.; Joeris, K.; Teiser, J.; Wurm, G. New Journal of Physics 2020b, 22, 093025.&lt;/p&gt; &lt;p&gt;[5] Teiser, J.; Kruss, M.; Jungmann, F.; Wurm, G. The Astrophysical Journal Letters 2021, 908, L22.&lt;/p&gt;


2020 ◽  
Vol 50 (2) ◽  
pp. 323-342 ◽  
Author(s):  
D. A. Cherian ◽  
E. L. Shroyer ◽  
H. W. Wijesekera ◽  
J. N. Moum

AbstractWe describe the seasonal cycle of mixing in the top 30–100 m of the Bay of Bengal as observed by moored mixing meters (χpods) deployed along 8°N between 85.5° and 88.5°E in 2014 and 2015. All χpod observations were combined to form seasonal-mean vertical profiles of turbulence diffusivity KT in the top 100 m. The strongest turbulence is observed during the southwest and postmonsoon seasons, that is, between July and November. The northeast monsoon (December–February) is a period of similarly high mean KT but an order of magnitude lower median KT, a sign of energetic episodic mixing events forced by near-inertial shear events. The months of March and April, a period of weak wind forcing and low near-inertial shear amplitude, are characterized by near-molecular values of KT in the thermocline for weeks at a time. Strong mixing events coincide with the passage of surface-forced downward-propagating near-inertial waves and with the presence of enhanced low-frequency shear associated with the Summer Monsoon Current and other mesoscale features between July and October. This seasonal cycle of mixing is consequential. We find that monthly averaged turbulent transport of salt out of the salty Arabian Sea water between August and January is significant relative to local E − P. The magnitude of this salt flux is approximately that required to close model-based salt budgets for the upper Bay of Bengal.


2020 ◽  
Vol 90 (2) ◽  
pp. 250-267 ◽  
Author(s):  
Sergio A. Marenssi ◽  
Carlos O. Limarino ◽  
Laura J. Schencman ◽  
Patricia L. Ciccioli

ABSTRACT Two episodes of lacustrine sedimentation, separated by an erosional surface and fluvial sedimentation, took place in the southern part of the broken foreland Vinchina basin (NW Argentina) between 11 and 5 Ma. The lacustrine deposits, 768 and 740 meters thick, are recorded in the upper part of the Vinchina Formation (“Vinchina lake”) and the lower part of the Toro Formation (“Toro Negro lake”) respectively. According to sedimentological features, four sedimentary facies associations (FAs) are recognized in the lacustrine deposits: 1) thinly laminated mudstones facies association (FA 1), 2) coarsening- and thickening-upward muddy to sandy cycles (FA 2), 3) medium- to coarse-grained sandstones (FA 3), and 4) mudstones, sandstones, and oolitic limestones (FA 4). Altogether, these facies correspond to ephemeral, shallow, lacustrine systems including saline mudflats. The total thickness of each lacustrine interval, the thickness of the individual cycles and their lithology, and the overall aggradational facies arrangement suggest that both lakes developed during underfilled stages of the basin. The coarsening-upward cycles can be regarded as lacustrine parasequences representing cyclic episodes of expansion and contraction of the lake, but unlike marine parasequences these cycles do not correlate to water depth. The development of lacustrine conditions and continuous base-level rise, together with the coeval southward-directed paleoflow indicators, suggest axial drainages and that the basin was externally closed (endorheic) at that time. The large thicknesses of each lacustrine interval also points to high accommodation in the southern part of the Vinchina basin during these times. Lake filling cycles are one order of magnitude thicker than lake depth, so we postulate that subsidence (tectonic) and rise of the spill point (geomorphology) increased accommodation but not water depth. Thus, unlike marine parasequences, the analyzed coarsening-upward cycles do not correlate to water depth, but rather they are controlled by more complex basinal accommodation processes. We hypothesize that the coeval uplift of the Umango and Espinal basement block to the south, coupled with the initial doming of the Sierra de Los Colorados to the east, may have generated the damming of the southward-directed drainage and a zone of maximum accommodation, then controlling the location of the two lakes and the preservation of their thick sedimentary records. Therefore, localized accommodation was enhanced by a combination of tectonic subsidence and topographic growth. The two lacustrine intervals and the intervening fluvial deposits record changing contributions from axial to transverse drainages and different cycles of closed and open conditions in the basin. A low-frequency, closed to open and back to closed (axial to transverse and return to axial drainage) basin evolution, is envisaged by the development of the two lakes (closed stages) and the erosional surface followed by the interval of fluvial sedimentation that separates them (open stage). In addition, several high-frequency lake fluctuations (expansion–contraction) are represented by the coarsening-upward cycles within each lacustrine interval. The thick lacustrine intervals and their intermediate incision surfaces record cyclic filling and re-excavation stages and localized episodes of increased subsidence in the Vinchina basin, which seem to be a common feature of tectonically active broken foreland basins.


Sensors ◽  
2019 ◽  
Vol 19 (3) ◽  
pp. 614 ◽  
Author(s):  
Ilya Kubasov ◽  
Aleksandr Kislyuk ◽  
Andrei Turutin ◽  
Alexander Bykov ◽  
Dmitry Kiselev ◽  
...  

We present a low-frequency sensor for the detection of vibrations, with a sub-nm amplitude, based on a cantilever made of a single-crystalline lithium niobate (LiNbO3) plate, with a bidomain ferroelectric structure. The sensitivity of the sensor-to-sinusoidal vibrational excitations was measured in terms of displacement as well as of acceleration amplitude. We show a linear behavior of the response, with the vibrational displacement amplitude in the entire studied frequency range up to 150 Hz. The sensitivity of the developed sensor varies from minimum values of 20 μV/nm and 7 V/g (where g = 9.81 m/s2 is the gravitational acceleration), at a frequency of 23 Hz, to peak values of 92.5 mV/nm and 2443 V/g, at the mechanical resonance of the cantilever at 97.25 Hz. The smallest detectable vibration depended on the excitation frequency and varied from 100 nm, at 7 Hz, to 0.1 nm, at frequencies above 38 Hz. Sensors using bidomain lithium niobate single crystals, as sensitive elements, are promising for the detection of ultra-weak low-frequency vibrations in a wide temperature range and in harsh environments.


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