scholarly journals Tailoring Adsorption Induced Switchability of a Pillared Layer MOF by Crystal Size Engineering

2020 ◽  
Author(s):  
Leila Abylgazina ◽  
Irena Senkovska ◽  
Sebastian Ehrling ◽  
Volodymyr Bon ◽  
Petko Petkov ◽  
...  
Keyword(s):  
Particle Size ◽  
Low Frequency ◽  
Polar Molecules ◽  
Adsorption Enthalpy ◽  
Factors Affecting ◽  
University Of Technology ◽  
Order Of Magnitude ◽  
Crystal Structural ◽  
Critical Particle Size ◽  
Characteristic Adsorption

The pillared layer framework DUT-8(Zn) (Zn<sub>2</sub>(2,6-ndc)<sub>2</sub>(dabco), 2,6-ndc = 2,6-naphthalenedicarboxylate, dabco = 1,4-diazabicyclo-[2.2.2]-octane, DUT = Dresden University of Technology) is a prototypical switchable MOF, showing characteristic adsorption and desorption induced open phase (<i>op</i>) to closed phase (<i>cp</i>) transformation associated with huge changes in cell volume. We demonstrate switchability strongly depends on a framework-specific critical particle size (d<i><sub>crit</sub></i>). The solvent removal process (pore desolvation stress contracting the framework) significantly controls the <i>cp</i>/<i>op</i> ratio after desolvation and, subsequently, the adsorption induced switchability characteristics of the system. After desolvation, the dense <i>cp</i> phase of DUT-8(Zn) shows no adsorption-induced reopening and therefore is non-porous for N<sub>2</sub> at 77 K and CO<sub>2</sub> at 195 K. However, polar molecules with a higher adsorption enthalpy, such as the polar molecules such as chloromethane at 249 K and dichloromethane (DCM) at 298 K can reopen the macro-sized crystals upon adsorption. For macro-sized particles, the outer surface energy is negligible and only the type of metal (Zn, Co, Ni) controls the DCM-induced gate opening pressure. The framework stiffness increases from Zn to Ni as confirmed by DFT calculations, X-ray crystal structural analyses, and low frequency Raman spectroscopy. The partial disintegration of the Zn based node hinges produces an overall increased stabilization of<i> cp </i>vs. <i>op</i> phase shifts the critical particle size at which switchability starts to become suppressed to even lower values (d<i><sub>crit</sub></i> < 200 nm) as compared to the Ni-based system (<i>d<sub>crit</sub></i> ≈ 500 nm). Hence, the three factors affecting switchability (energetics of the empty host, (<i>E<sub>op</sub>-E<sub>cp</sub></i>) (I), particle size (II), and desolvation stress (III)) appear to be of the same order of magnitude and should be considered collectively, not individually.

scholarly journals Tailoring Adsorption Induced Switchability of a Pillared Layer MOF by Crystal Size Engineering

2020 ◽  
Author(s):  
Leila Abylgazina ◽  
Irena Senkovska ◽  
Sebastian Ehrling ◽  
Volodymyr Bon ◽  
Petko Petkov ◽  
...  
Keyword(s):  
Particle Size ◽  
Low Frequency ◽  
Polar Molecules ◽  
Adsorption Enthalpy ◽  
Factors Affecting ◽  
University Of Technology ◽  
Order Of Magnitude ◽  
Crystal Structural ◽  
Critical Particle Size ◽  
Characteristic Adsorption

The pillared layer framework DUT-8(Zn) (Zn<sub>2</sub>(2,6-ndc)<sub>2</sub>(dabco), 2,6-ndc = 2,6-naphthalenedicarboxylate, dabco = 1,4-diazabicyclo-[2.2.2]-octane, DUT = Dresden University of Technology) is a prototypical switchable MOF, showing characteristic adsorption and desorption induced open phase (<i>op</i>) to closed phase (<i>cp</i>) transformation associated with huge changes in cell volume. We demonstrate switchability strongly depends on a framework-specific critical particle size (d<i><sub>crit</sub></i>). The solvent removal process (pore desolvation stress contracting the framework) significantly controls the <i>cp</i>/<i>op</i> ratio after desolvation and, subsequently, the adsorption induced switchability characteristics of the system. After desolvation, the dense <i>cp</i> phase of DUT-8(Zn) shows no adsorption-induced reopening and therefore is non-porous for N<sub>2</sub> at 77 K and CO<sub>2</sub> at 195 K. However, polar molecules with a higher adsorption enthalpy, such as the polar molecules such as chloromethane at 249 K and dichloromethane (DCM) at 298 K can reopen the macro-sized crystals upon adsorption. For macro-sized particles, the outer surface energy is negligible and only the type of metal (Zn, Co, Ni) controls the DCM-induced gate opening pressure. The framework stiffness increases from Zn to Ni as confirmed by DFT calculations, X-ray crystal structural analyses, and low frequency Raman spectroscopy. The partial disintegration of the Zn based node hinges produces an overall increased stabilization of<i> cp </i>vs. <i>op</i> phase shifts the critical particle size at which switchability starts to become suppressed to even lower values (d<i><sub>crit</sub></i> < 200 nm) as compared to the Ni-based system (<i>d<sub>crit</sub></i> ≈ 500 nm). Hence, the three factors affecting switchability (energetics of the empty host, (<i>E<sub>op</sub>-E<sub>cp</sub></i>) (I), particle size (II), and desolvation stress (III)) appear to be of the same order of magnitude and should be considered collectively, not individually.

DC and AC Measurements of Magnetite Nanoparticulates and Implications for Nonlinear Response

2008 ◽  
Vol 1138 ◽  
Author(s):  
Silvia Liong ◽  
Ricky Lamar Moore
Keyword(s):  
Particle Size ◽  
Magnetic Properties ◽  
Polymer Composites ◽  
Magnetic Measurements ◽  
Bulk Material ◽  
Low Frequency ◽  
Anisotropy Field ◽  
Coaxial Line ◽  
Magnetic Data ◽  
Order Of Magnitude

AbstractThis paper discusses preparation, characterization and measurement of linear DC and AC magnetic properties of magnetite (Fe3O4) nanoparticles (size ranges of 7-50 nm and 5 microns) and polymer composites of those particulates. Selected data and analysis are taken from the PhD thesis of Liong [1]. The goal of this research is to obtain magnetic data, specifically magnetization, anisotropy and coercivity as functions of particle size. These will be used as inputs to non linear magnetic simulations and in planning for future nonlinear magnetic measurements. Magnetite nanoparticles were synthesized by chemical coprecipitation, a method that allowed for the production of samples in gram quantities. Vibrating sample magnetometry was used to measure the room-temperature DC magnetization and coercivity of the particulates. Coaxial line impedance measurements were used to measure low frequency and dispersive AC permeability of Fe3O4–polymer composites from 1 Megahertz to 10 Gigahertz. AC data are applied to infer particulate magnetic susceptibility and anisotropy field change with particle size. Particle size was calculated from XTD data and supported by TEM images.Measured DC saturation magnetization and coercivity decreased with particle dimension while anisotropy was calculated to increase. Magnetization data are consistent with models that calculate nanoparticle magnetization as a volumetric average of a spherical bulk material core and a passive outer shell. The shell thickness was calculated at 0.84 nm, very near one lattice constant of bulk Fe3O4, 0.8394 nm. Composites containing particulate volume fractions less than 20% were fabricated. Effective media theory was applied to measured AC composite permeability to extract particle magnetic properties and thereby anisotropy field, which increased by an order of magnitude from the bulk. Permeability decreased with particulate size.

scholarly journals Tailoring adsorption induced switchability of a pillared layer MOF by crystal size engineering

CrystEngComm ◽  
2021 ◽  
Author(s):  
Leila Abylgazina ◽  
Irena Senkovska ◽  
Sebastian Ehrling ◽  
Volodymyr Bon ◽  
Petko St. Petkov ◽  
...  
Keyword(s):  
Particle Size ◽  
Crystal Size ◽  
Factors Affecting ◽  
Order Of Magnitude ◽  
Main Factors

The main factors affecting switchability are identified for DUT-8(Zn): energetics of the host, particle size, and desolvation stress. They influence the flexible behaviour to the same order of magnitude and should be always considered collectively.

scholarly journals Reduction Mechanism of Fine Hematite Ore Particles in Suspension

2021 ◽  
Author(s):  
Zhiyuan Chen ◽  
Christiaan Zeilstra ◽  
Jan van der Stel ◽  
Jilt Sietsma ◽  
Yongxiang Yang
Keyword(s):  
Particle Size ◽  
Temperature Drop ◽  
Reduction Rate ◽  
Reduction Process ◽  
Reciprocal Relationship ◽  
Drop Tube ◽  
Surface Nucleation ◽  
Order Of Magnitude ◽  
Relationship Of ◽  
Kinetics Of

AbstractIn order to understand the pre-reduction behaviour of fine hematite particles in the HIsarna process, change of morphology, phase and crystallography during the reduction were investigated in the high temperature drop tube furnace. Polycrystalline magnetite shell formed within 200 ms during the reduction. The grain size of the magnetite is in the order of magnitude of 10 µm. Lath magnetite was observed in the partly reduced samples. The grain boundary of magnetite was reduced to molten FeO firstly, and then the particle turned to be a droplet. The Johnson-Mehl-Avrami-Kolmogorov model is proposed to describe the kinetics of the reduction process. Both bulk and surface nucleation occurred during the reduction, which leads to the effect of size on the reduction rate in the nucleation and growth process. As a result, the reduction rate constant of hematite particles increases with the increasing particle size until 85 µm. It then decreases with a reciprocal relationship of the particle size above 85 µm.

scholarly journals A Numerical Study of the Effect of Particle Size on Particle Deposition on Turbine Vanes and Blades

2021 ◽  
Vol 13 (5) ◽  
pp. 168781402110178
Author(s):  
Zhengang Liu ◽  
Weinan Diao ◽  
Zhenxia Liu ◽  
Fei Zhang
Keyword(s):  
Particle Size ◽  
Particle Deposition ◽  
Numerical Study ◽  
Stokes Number ◽  
Capture Efficiency ◽  
Particle Capture ◽  
Factors Affecting ◽  
Pressure Surface ◽  
Deposition Area ◽  
Turbine Vanes

Particle deposition could decrease the aerodynamic performance and cooling efficiency of turbine vanes and blades. The particle motion in the flow and its temperature are two important factors affecting its deposition. The size of the particle influences both its motion and temperature. In this study, the motion of particles with the sizes from 1 to 20 μm in the first stage of a turbine are firstly numerically simulated with the steady method, then the particle deposition on the vanes and blades are numerically simulated with the unsteady method based on the critical viscosity model. It is discovered that the particle deposition on vanes mainly formed near the leading and trailing edge on the pressure surface, and the deposition area expands slowly to the whole pressure surface with the particle size increasing. For the particle deposition on blades, the deposition area moves from the entire pressure surface toward the tip with the particle size increasing due to the effect of rotation. For vanes, the particle capture efficiency increases with the particle size increasing since Stokes number and temperature of the particle both increase with its size. For blades, the particle capture efficiency increases firstly and then decreases with the particle size increasing.

scholarly journals Facilitating Successful Smart Campus Transitions: A Systems Thinking-SWOT Analysis Approach

2021 ◽  
Vol 11 (5) ◽  
pp. 2044
Author(s):  
Bankole Awuzie ◽  
Alfred Beati Ngowi ◽  
Temitope Omotayo ◽  
Lovelin Obi ◽  
Julius Akotia
Keyword(s):  
Systems Thinking ◽  
Swot Analysis ◽  
Qualitative Content Analysis ◽  
Holistic Approach ◽  
Education Institution ◽  
Factors Affecting ◽  
Smart Campus ◽  
University Of Technology ◽  
Management Approaches ◽  
Gap Data

An identification of strengths, weakness, opportunities, and threats (SWOT) factors remains imperative for enabling a successful Smart Campus transition. The absence of a structured approach for analyzing the relationships between these SWOT factors and the influence thereof on Smart Campus transitions negate effective implementation. This study leverages a systems thinking approach to bridge this gap. Data were collected through a stakeholder workshop within a University of Technology case study and analyzed using qualitative content analysis (QCA). This resulted in the establishment of SWOT factors affecting Smart Campus transitions. Systems thinking was utilized to analyze the relationships between these SWOT factors resulting in a causal loop diagram (CLD) highlighting extant interrelationships. A panel of experts drawn from the United Kingdom, New Zealand, and South Africa validated the relationships between the SWOT factors as elucidated in the CLD. Subsequently, a Smart Campus transition framework predicated on the CLD archetypes was developed. The framework provided a holistic approach to understanding the interrelationships between various SWOT factors influencing Smart Campus transitions. This framework remains a valuable tool for facilitating optimal strategic planning and management approaches by policy makers, academics, and implementers within the global Higher Education Institution (HEI) landscape for managing successful Smart Campus transition at the South African University of Technology (SAUoT) and beyond.

scholarly journals Physicochemical factors affecting the wettability of copper mine blasting dust

2021 ◽  
Author(s):  
Longzhe Jin ◽  
Jianguo Liu ◽  
Jingzhong Guo ◽  
Jiaying Wang ◽  
Tianyang Wang
Keyword(s):  
Particle Size ◽  
Physicochemical Properties ◽  
Pore Structure ◽  
Total Pore Volume ◽  
Open Pit ◽  
X Rays ◽  
Factors Affecting ◽  
Copper Mine ◽  
Mineral Components ◽  
Hydrophobic Component

AbstractTo investigate the factors affecting the wettability of copper mine blasting dust, the primary blasting dust was collected from an open-pit copper mine and separated into hydrophilic blasting dust (HLBD) and hydrophobic blasting dust (HBBD) using water flotation method. The physicochemical properties of HLBD and HBBD were measured and compared with each other. The properties included particle size distributions (PSDs), micromorphologies, pore structures, mineral components and surface organic carbon functional groups. The results show that particle size and pore structure of the blasting dust are the main factors affecting its wettability. Specifically, particle size of HBBD is smaller than that of HLBD, and their respiratory dust (less than 10 µm) accounts for 61.74 vol% and 53.00 vol%, respectively. The pore structure of HBBD is more developed, and the total pore volume of HBBD is 1.66 times larger than that of HLBD. The identical mineral compositions were detected in HLBD and HBBD by X-rays diffraction (XRD); however, the surface organic hydrophobic component of HBBD is slightly larger than that of HLBD, this may be the reason for the poor wettability of HBBD. This study is significant to understand the effects of physicochemical properties of copper mine blasting dust on its wettability.

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