scholarly journals Smoothing the energy transfer pathway in quasi-2D perovskite films using methanesulfonate leads to highly efficient light-emitting devices

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Lingmei Kong ◽  
Xiaoyu Zhang ◽  
Yunguo Li ◽  
Haoran Wang ◽  
Yuanzhi Jiang ◽  
...  

AbstractQuasi-two-dimensional (quasi-2D) Ruddlesden–Popper (RP) perovskites such as BA2Csn–1PbnBr3n+1 (BA = butylammonium, n > 1) are promising emitters, but their electroluminescence performance is limited by a severe non-radiative recombination during the energy transfer process. Here, we make use of methanesulfonate (MeS) that can interact with the spacer BA cations via strong hydrogen bonding interaction to reconstruct the quasi-2D perovskite structure, which increases the energy acceptor-to-donor ratio and enhances the energy transfer in perovskite films, thus improving the light emission efficiency. MeS additives also lower the defect density in RP perovskites, which is due to the elimination of uncoordinated Pb2+ by the electron-rich Lewis base MeS and the weakened adsorbate blocking effect. As a result, green light-emitting diodes fabricated using these quasi-2D RP perovskite films reach current efficiency of 63 cd A−1 and 20.5% external quantum efficiency, which are the best reported performance for devices based on quasi-2D perovskites so far.

RSC Advances ◽  
2017 ◽  
Vol 7 (7) ◽  
pp. 4196-4202 ◽  
Author(s):  
Fengxian Lu ◽  
Rui Hu ◽  
Shuangqing Wang ◽  
Xudong Guo ◽  
Guoqiang Yang

A saturated white-light emission was obtained by dispersing three benzothiazole analogues into a solid PMMA matrix. This skillfully avoids the detrimental energy transfer between doped dyes providing a simple approach for fabrication of white-light emitting devices.


2021 ◽  
Vol 23 (12) ◽  
pp. 7495-7503
Author(s):  
Wanlin Cai ◽  
Kai Ren ◽  
Ancong Zhao ◽  
Xiulan Wu ◽  
Rongxing He ◽  
...  

Compared to the PtOO7-based system, the greater EQE of the PtON7-based system is mainly governed by the stronger energy transfer efficiency (ηEET); thus, it is necessary to evaluate ηEET from hosts to guests for the rational design of OLEDs.


Author(s):  
Hyunsik Im ◽  
Atanu Jana ◽  
Vijaya Gopalan Sree ◽  
QIANKAI BA ◽  
Seong Chan Cho ◽  
...  

Lead-free, non-toxic transition metal-based phosphorescent organic–inorganic hybrid (OIH) compounds are promising for next-generation flat-panel displays and solid-state light-emitting devices. In the present study, we fabricate highly efficient phosphorescent green-light-emitting diodes...


2021 ◽  
Vol 9 (9) ◽  
pp. 3052-3057
Author(s):  
Jerzy J. Langer ◽  
Ewelina Frąckowiak

H+LEDs are light emitting devices based on a protonic p–n junction; now with no organic polymers. The unique are non-linear optical effects: collimated light beams and stimulated Raman scattering (SRS), observed while generating intense light pulses.


2003 ◽  
Vol 789 ◽  
Author(s):  
Michael Cross ◽  
Walter Varhue

ABSTRACT: One of the major shortcomings of silicon (Si) as a semiconductor material is its inability to yield efficient light emission. There has been a continued interest in adding rare earth ion impurities such as erbium (Er) to the Si lattice to act as light emitting centers. The low band gap of Si however has complicated this practice by quenching and absorbing this possible emission. Increasing the band gap of the host has been successfully tried in the case of gallium nitride (GaN) [1] and Si-rich oxide (SRO) [2] alloys. A similar approach has been tried here, where Er oxide (ErOx) nanocrystals have been formed in a yttria stabilized zirconia (YSZ) host deposited on a Si (100) substrate. The YSZ is deposited as a heteroepitaxial, insulating layer on the Si substrate by a reactive sputtering technique. The Er is also incorporated by a sputtering process from a metallic target and its placement in the YSZ host can be easily controlled. The device structure formed is a simple metal contact/insulator/phosphor sandwich. The device has been found to emit visible green light at low bias voltages. The advantage of this material is that it is much more structured than SiO2 which can theoretically lead to higher emission intensity.


2015 ◽  
Vol 17 (48) ◽  
pp. 32297-32303 ◽  
Author(s):  
Xinhua Cao ◽  
Haichuang Lan ◽  
Zhenhua Li ◽  
Yueyuan Mao ◽  
Liming Chen ◽  
...  

A two-component light-harvesting organogel containing a naphthalimide-based gelator as a donor and a phosphorescent Ir(iii) complex as an acceptor was used to produce white-light-emitting organogels.


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