scholarly journals Out-of-sequence skeletal growth causing oscillatory zoning in arc olivines

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Pablo Salas ◽  
Philipp Ruprecht ◽  
Laura Hernández ◽  
Osvaldo Rabbia

AbstractPrimitive olivines from the monogenetic cones Los Hornitos, Central-South Andes, preserve dendritic, skeletal, and polyhedral growth textures. Consecutive stages of textural maturation occur along compositional gradients where high Fo–Ni cores of polyhedral olivines (Fo92.5, Ni ~3500 ppm) contrast with the composition of dendritic olivines (Fo < 91.5, Ni < 3000 ppm), indicating sequential nucleation. Here we present a new growth model for oscillatory Fo–Ni olivine zoning that contrasts with the standard interpretation of continuous, sequential core-to-rim growth. Olivine grows rapidly via concentric addition of open-structured crystal frames, leaving behind compositional boundary layers that subsequently fill-in with Fo–Ni-depleted olivine, causing reversals. Elemental diffusion modeling reveals growth of individual crystal frames and eruption at the surface occurred over 3.5–40 days. Those timescales constrain magma ascent rates of 40–500 m/h (0.011 to 0.14 m/s) from the deep crust. Compared to ocean island basalts, where dendritic and skeletal olivines have been often described, magmas erupted at arc settings, experiencing storage and degassing, may lack such textures due to fundamentally different ascent histories.

2005 ◽  
Vol 69 (6) ◽  
pp. 951-971 ◽  
Author(s):  
H. Kawabata ◽  
N. Takafuji

AbstractCalc-alkaline dacites from the Setouchi volcanic belt contain garnet crystals that are classified petrographically and chemically into two types: type I and type M. Type-M garnets are characterized by acicular sillimanite inclusions or dissolution textures, and may be accompanied by xenolith fragments. They exhibit extensive compositional zoning with an increase in MgO/FeO and decrease in MnO content towards the margin. These petrographical and compositional features are identical to those of garnets from metamorphic xenoliths entrained in the Setouchi volcanic rocks, suggesting a xenocrystic origin for the type-M garnets. In contrast, type-I garnets lack sillimanite inclusions and have different rim compositions from the type-M garnets. Transmission electron microscope analysis has revealed the presence of minute glass inclusions in the type-I garnets, which indicate conclusively that these garnets grew in the presence of a melt. Type-I garnets have oscillatory zoning characterized by an antipathetic variation between FeO and MgO. This zoning was probably caused by magma heterogeneity within magma batch. Differences in rim compositions between the two types of garnets, and the presence of reaction rims indicate that the xenocrystic type-M garnets were incorporated into the magma after phenocrystic type-I garnet became unstable due to decompression during magma ascent.


1999 ◽  
Vol 12 (3) ◽  
pp. 335-344
Author(s):  
Ming-Qing Liu ◽  
Zhi-Ping Zhu ◽  
Sheng-Ming Fang ◽  
Ming-Jun Liu ◽  
Jian-Shi Zhang ◽  
...  

2021 ◽  
Vol 176 (11) ◽  
Author(s):  
Charline Lormand ◽  
Georg Florian Zellmer ◽  
Naoya Sakamoto ◽  
Teresa Ubide ◽  
Geoff Kilgour ◽  
...  

AbstractArc magmas typically contain phenocrysts with complex zoning and diverse growth histories. Microlites highlight the same level of intracrystalline variations but require nanoscale resolution which is globally less available. The southern Taupo Volcanic Zone (TVZ), New Zealand, has produced a wide range of explosive eruptions yielding glassy microlite-bearing tephras. Major oxide analyses and textural information reveal that microlite rims are commonly out of equilibrium with the surrounding glass. We mapped microlites and microcrysts at submicron resolution for major and trace element distributions and observed three plagioclase textural patterns: (1) resorption and overgrowth, (2) oscillatory zoning, and (3) normal (sharp) zoning. Pyroxene textures are diverse: (1) resorption and overgrowth, (2) calcium-rich bands, (3) hollow textures, (4) oscillatory zoning, (5) sector zoning, (6) normal zoning and (7) reverse zoning. Microlite chemistry and textures inform processes operating during pre-eruptive magma ascent. They indicate a plumbing system periodically intruded by short-lived sub-aphyric dykes that entrain microantecrysts grown under diverse physico-chemical conditions and stored in rapidly cooled, previously intruded dykes. Changes in temperature gradients between the intrusion and the host rock throughout ascent and repeated magma injections lead to fluctuations in cooling rates and generate local heterogeneities illustrated by the microlite textures and rim compositions. Late-stage degassing occurs at water saturation, forming thin calcic microcryst rims through local partitioning effects. This detailed investigation of textures cryptic to conventional imaging shows that a significant proportion of the micrometre-sized crystal cargo of the TVZ is of antecrystic origin and may not be attributed to late-stage nucleation and growth at the onset of volcanic eruptions, as typically presumed.


Author(s):  
E. L. Hall

Sensitization in stainless steels is caused by the formation of chromium-rich M23C6 carbides at grain boundaries, which depletes the adjacent matrix and boundary region of chromium, and hence leads to rapid intergranular attack. To fully understand the sensitization process, and to test the accuracy of theories proposed to model this process, it is necessary to obtain very accurate measurements of the chromium concentration at grain boundaries in sensitized specimens. Quantitative X-ray spectroscopy in the analytical electron microscope (AEM) enables the chromium concentration profile across these boundaries to be studied directly; however, it has been shown that a strong effect of foil thickness and electron probe size may be present in the analysis of rapidly-changing compositional gradients. The goal of this work is to examine these effects.


Author(s):  
J. Drennan ◽  
R.H.J. Hannink ◽  
D.R. Clarke ◽  
T.M. Shaw

Magnesia partially stabilised zirconia (Mg-PSZ) ceramics are renowned for their excellent nechanical properties. These are effected by processing conditions and purity of starting materials. It has been previously shown that small additions of strontia (SrO) have the effect of removing the major contaminant, silica (SiO2).The mechanism by which this occurs is not fully understood but the strontia appears to form a very mobile liquid phase at the grain boundaries. As the sintering reaches the final stages the liquid phase is expelled to the surface of the ceramic. A series of experiments, to examine the behaviour of the liquid grain boundary phase, were designed to produce compositional gradients across the ceramic bodies. To achieve this, changes in both silica content and furnace atmosphere were implemented. Analytical electron microscope techniques were used to monitor the form and composition of the phases developed. This paper describes the results of our investigation and the presentation will discuss the work with reference to liquid phase sintering of ceramics in general.


AIAA Journal ◽  
1998 ◽  
Vol 36 ◽  
pp. 929-935
Author(s):  
A. G. Straatman ◽  
G. D. Stubley ◽  
G. D. Raithby

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