Entry Probe Radio Science for Measurements of Ice Giant Atmospheric Dynamics and Composition

<p>Planetary atmospheric winds, waves, tides, and turbulence represent a tie-point between planetary structure and processes, including atmospheric thermal and energy structure, cloud location and properties, and atmospheric composition and compositional gradients. The only direct means by which dynamics of an ice giant atmosphere can be measured along the probe descent path is via radiometric tracking of an ice giant entry probe. Additionally, measurements on an orbiter of the strength of a probe telecom signal can be used to provide the abundance of microwave absorbing molecules along the probe relay signal raypath, expected to be primarily ammonia (NH<sub>3</sub>) or hydrogen sulfide (H<sub>2</sub>S).</p> <p> </p> <p>Doppler tracking of a descent probe has been demonstrated with the Galileo probe at Jupiter and the Huygens probe at Titan. By including an ultrastable oscillator on both the transmit and receive sides of the probe telemetry relay signal, the time variation of the measured relay signal frequency provides a measure of wind speeds (via the Doppler effect). and the signatures of atmospheric waves, convection, and turbulence. In addition, other probe dynamical effects such as pendulum motion under the parachute, probe spin, and aerodynamic buffeting can be retrieved from careful analysis of the probe telecom signal Doppler residuals. Measurements made on board the orbiter of the time-varying received signal strength would provide a profile of microwave absorbing molecules along the probe radio signal raypath, complementing composition measurements made the probe mass spectrometer.</p> <p> </p> <p>The scientific objectives, measurement requirements, and expected measurement accuracies of the profile of zonal winds and atmospheric absorption will be discussed in this presentation, with a preliminary attempt to quantify the effect of uncertainties in the reconstruction of the probe descent and carrier overflight trajectories.</p>

Out-of-sequence skeletal growth causing oscillatory zoning in arc olivines

Primitive olivines from the monogenetic cones Los Hornitos, Central-South Andes, preserve dendritic, skeletal, and polyhedral growth textures. Consecutive stages of textural maturation occur along compositional gradients where high Fo–Ni cores of polyhedral olivines (Fo92.5, Ni ~3500 ppm) contrast with the composition of dendritic olivines (Fo < 91.5, Ni < 3000 ppm), indicating sequential nucleation. Here we present a new growth model for oscillatory Fo–Ni olivine zoning that contrasts with the standard interpretation of continuous, sequential core-to-rim growth. Olivine grows rapidly via concentric addition of open-structured crystal frames, leaving behind compositional boundary layers that subsequently fill-in with Fo–Ni-depleted olivine, causing reversals. Elemental diffusion modeling reveals growth of individual crystal frames and eruption at the surface occurred over 3.5–40 days. Those timescales constrain magma ascent rates of 40–500 m/h (0.011 to 0.14 m/s) from the deep crust. Compared to ocean island basalts, where dendritic and skeletal olivines have been often described, magmas erupted at arc settings, experiencing storage and degassing, may lack such textures due to fundamentally different ascent histories.

Analysis of Compositional Gradients in Cu(In,Ga)(S,Se)2 Solar Cell Absorbers Using Energy Dispersive X-ray Analysis with Different Acceleration Energies

The efficiency of Cu(In,Ga)(S,Se)2 (CIGSSe) solar cell absorbers can be increased by the optimization of the Ga/In and S/Se gradients throughout the absorber. Analyzing such gradients is therefore an important method in tracking the effectiveness of process variations. To measure compositional gradients in CIGSSe, energy dispersive X-ray analysis (EDX) with different acceleration energies performed at both the front surface and the backside of delaminated absorbers was used. This procedure allows for the determination of compositional gradients at locations that are millimeters apart and distributed over the entire sample. The method is therefore representative for a large area and yields information about the lateral homogeneity in the millimeter range. The procedure is helpful if methods such as secondary ion-mass (SIMS), time-of-flight SIMS, or glow-discharge optical emission spectrometry (GDOES) are not available. Results of such EDX measurements are compared with GDOES, and they show good agreement. The procedure can also be used in a targeted manner to detect local changes of the gradients in inhomogeneities or points of interest in the µm range. As an example, a comparison between the compositional gradients in the regular absorber and above the laser cut separating the Mo back contact is shown.

The Role of Crystal Accumulation and Cumulate Remobilization in the Formation of Large Zoned Ignimbrites: Insights From the Aso-4 Caldera-forming Eruption, Kyushu, Japan

The Aso-4 caldera-forming event (86.4 ± 1.1 ka, VEI-8) is the second largest volcanic eruption Earth experienced in the past 100 ka. The ignimbrite sheets produced during this event are some of the first ever described compositionally zoned pyroclastic flow deposits exhibiting clear compositional, mineralogical and thermal gradients with stratigraphic position. Large quantities of the deposits are composed of crystal-poor, highly evolved juvenile pumices, while late-erupted pyroclastic flows are in many cases dominated by crystal-rich and less silicic scoria. These petrological gradients in the Aso-4 deposits have been linked to extensive magma mixing of two compositionally distinct magmas in a complex upper crustal reservoir. However, new studies on several other zoned ignimbrites suggest that magma mixing alone is not sufficient to fully explain such strong compositional gradients in the deposits. These gradients are expected to be dominantly caused by the recharge-induced reactivation of extracted melt caps and their complementary cumulate in the upper crust. Here, we investigate bulk rock and matrix glass data with detailed analyses of mineral chemistry in order to re-evaluate the Aso-4 deposits in light of these latest developments. Reverse chemical zoning in phenocrysts, Sr enrichment in euhedral rims of plagioclase and the presence of mafic minerals (clinopyroxene, olivine) indicate recharge of hot, mafic magmas shortly prior to eruption, inducing a mixing signature. However, the marked enrichment in some elements in bulk-rock analyses and the presence of highly evolved minerals (some in the form of glomerocrysts) in the late-erupted, crystal-rich units, provide clear evidence for crystal accumulation in these scoria. Mass balance modeling of P2O5, Sr and SiO2 supports the extraction of melt-rich lenses within an upper crustal mush zone, leaving a partly cumulative evolved crystal residue. We therefore propose an origin of the compositionally zoned Aso-4 ignimbrite largely by erupting a heterogeneous upper crustal reservoir, consisting of crystal-poor rhyodacitic melt caps within its associated cumulate mush. This complex reservoir was reactivated by mafic recharge shortly prior to eruption, imparting an additional mixing signature to the deposits.

Evolution and demise of passive margins through grain mixing and damage

How subduction—the sinking of cold lithospheric plates into the mantle—is initiated is one of the key mysteries in understanding why Earth has plate tectonics. One of the favored locations for subduction triggering is at passive margins, where sea floor abuts continental margins. Such passive margin collapse is problematic because the strength of the old, cold ocean lithosphere should prohibit it from bending under its own weight and sinking into the mantle. Some means of mechanical weakening of the passive margin are therefore necessary. Spontaneous and accumulated grain damage can allow for considerable lithospheric weakening and facilitate passive margin collapse. Grain damage is enhanced where mixing between mineral phases in lithospheric rocks occurs. Such mixing is driven both by compositional gradients associated with petrological heterogeneity and by the state of stress in the lithosphere. With lateral compressive stress imposed by ridge push in an opening ocean basin, bands of mixing and weakening can develop, become vertically oriented, and occupy a large portion of lithosphere after about 100 million y. These bands lead to anisotropic viscosity in the lithosphere that is strong to lateral forcing but weak to bending and sinking, thereby greatly facilitating passive margin collapse.

Functionally Graded AISI 316L and AISI H13 Manufactured by L-DED for Die and Mould Applications

Tooling in the die and mould industry is subjected to high-wear and high-temperature environments, which often leads to the premature failure of this high-added-value tooling. When severe damage occurs, an alternative to replacing the whole component consists of the repair by laser-directed energy deposition (L-DED). For that end, intermediate layers are commonly employed as buffer material, where introducing a functionally graded material (FGM) might be beneficial to avoid material incompatibilities and improve the overall performance of the tooling. In the present work, an FGM composed of gradient AISI 316L to AISI H13 has been manufactured, and its microstructure and hardness analysed. Firstly, cracking owing to the formation of brittle intermediate phases has been detected. Secondly, an increase of the hardness and a decrease of the corrosion resistance has been observed when transitioning from AISI 316L to AISI H13. Thirdly, despite the FGM composition evolving linearly, nonlinear material properties such as hardness and corrosion have been observed, which are conditioned by the microstructure formed during the L‑DED process and the nonlinear influence of the composition of steel on such properties. Consequently, nonlinear compositional gradients are recommended if linear mechanical properties are to be obtained in the case of steel FGMs.

Lack of congruence between terrestrial and epiphytic lichen strata in boreal forests

Lichens occupy diverse substrates across tremendous ranges of environmental variation. In boreal forests, lichen communities co-occur in ‘strata’ defined by terrestrial or arboreal substrates, but these strata may or may not be interchangeable as bioindicators. Do co-occurring lichen strata have similar community structures and environmental responses? Could one stratum serve as a proxy for the other? We assessed variation in species richness and community compositions between ground-layer versus epiphyte-layer lichen strata in boreal forests and peatlands of interior Alaska. Species richness was lower and more spatially structured in the ground layer than the epiphyte layer. Richness of strata was not correlated. The most compositionally unique ground-layer communities were species-poor but contained regionally rare species not common in other plots. Variation in community compositions (ordination scores) were not congruent between strata (Procrustes congruence < 0.16 on 0–1 scale); the largest departures from congruence occurred where ground layers were species-poor. The best predictors of ground-layer community compositions were hydrological and topographic, whereas epiphytes were most associated with macroclimate and tree abundances. We conclude that lichens on different substrates ‘move in different circles’: compositional gradients did not agree and the environmental gradients most important to each lichen stratum were not the same. The conditions which strongly influence one vegetation stratum may have little bearing upon another. As global changes modify habitats, an incremental change in environment may lead community trajectories to diverge among lichen strata.

3D printed gradient index glass optics

We demonstrate an additive manufacturing approach to produce gradient refractive index glass optics. Using direct ink writing with an active inline micromixer, we three-dimensionally print multimaterial green bodies with compositional gradients, consisting primarily of silica nanoparticles and varying concentrations of titania as the index-modifying dopant. The green bodies are then consolidated into glass and polished, resulting in optics with tailored spatial profiles of the refractive index. We show that this approach can be used to achieve a variety of conventional and unconventional optical functions in a flat glass component with no surface curvature.

Mixing of Condensable Constituents with H/He During Formation of the Jupiter

&lt;p&gt;We present results of simulations of the growth of giant planets that incorporate the mixing of light gases with denser material that enters the planet as solids. We find that heavy compounds and gas begin to intimately mix when the planet is quite small, and substantial mixing occurs when the planet becomes roughly as massive as Earth, because even incoming silicates can then fully vaporize if they arrive in the form of planetesimals or smaller bodies. Nonetheless, most of the icy and rocky material accreted by a giant planet settles to a region in which vaporized ice and rock are well-mixed until the growing planet is several times as massive as Earth. Subsequently, planetesimals break up in a region that is too cool for all the silicates to vaporize, so the silicates continue to sink, but the water remains at higher altitudes. As the planet continues to grow, silicates vaporize farther out. Because the mean molecular weight decreases rapidly outward at many radii, some of the radially inhomogeneities in composition produced during the accretion era are able to survive for billions of years. After 4.57 Gyr, our model Jupiter retains compositional gradients; from the inside outwards one finds: (i) an inner core, dominantly composed of heavy elements; (ii) a density-gradient region, containing the majority of the planet's heavy elements, where H and He increase in abundance with height, reaching ~90% mass fraction at 30% of Jupiter's radius, with rocky materials enhanced relative to ices in the lower part of this gradient region and the composition transitioning to ices enhanced relative to rock at higher altitudes; (iv) a large, uniform-composition region (we do not account for He immiscibility), enriched relative to protosolar in heavy elements, especially ices, that contains the bulk of the planet's mass; and (v) an outer region where condensation of many constituents occurs. This radial compositional profile has heavy elements more broadly distributed within the planet than predicted by classical Jupiter-formation models. NASA&amp;#8217;s Juno spacecraft's measurements of Jupiter's gravity field also implies less concentration of heavy elements near the center of the planet than classical theoretical models. However, the preferred dilution of the core found in Juno-constrained gravity models is substantially larger than what is suggested by our accretion models, requiring some modification in the heavy element distribution. The compositional gradients in the region containing the bulk of the planet&amp;#8217;s heavy elements prevent convection, both in our models and the models that fit current gravity, probably resulting in a hot deep interior where much of the energy from the early stages of the planet's accretion remains trapped.&lt;/p&gt;