Scale-up issues for in situ anaerobic tetrachloroethene bioremediation

1997 ◽  
Vol 18 (2-3) ◽  
pp. 106-115 ◽  
Author(s):  
M D Lee ◽  
G E Quinton ◽  
R E Beeman ◽  
A A Biehle ◽  
R L Liddle ◽  
...  
Keyword(s):  
2016 ◽  
Vol 14 (13) ◽  
pp. 3423-3431 ◽  
Author(s):  
Benjamin J. Deadman ◽  
Rosella M. O'Mahony ◽  
Denis Lynch ◽  
Daniel C. Crowley ◽  
Stuart G. Collins ◽  
...  

In situ generation and use of tosyl azide in flow enables enhanced safety and ready scale-up in diazo transfer processes.


2008 ◽  
Vol 61 (6) ◽  
pp. 419 ◽  
Author(s):  
Matthew J. Spafford ◽  
James E. Christensen ◽  
Matthew G. Huddle ◽  
Joshua R. Lacey ◽  
Ram S. Mohan

A bismuth trifluoromethanesulfonate (triflate)-catalyzed (2.0 mol-%) multicomponent reaction involving the allylation of dioxolanes followed by in situ derivatization with anhydrides to generate highly functionalized esters has been developed under solvent-free conditions. Most reagents used to date for allylation of dioxolanes are highly corrosive and are often required in stoichiometric amounts. In contrast, the use of a relatively non-toxic and non-corrosive bismuth(iii)-based catalyst makes this methodology especially attractive for scale-up.


2020 ◽  
Author(s):  
Ahmed I. Osman ◽  
Charlie Farrell ◽  
Ala'a H. Al-Muhtaseb ◽  
Ahmed S. Al-Fatesh ◽  
John Harrison ◽  
...  

Abstract Background: Recycling the ever-increasing plastic waste has become an urgent global concern. One of the most convenient methods for plastic recycling is pyrolysis, owing to its environmentally friendly nature and its intrinsic properties. Understanding the pyrolysis process and the degradation mechanism is crucial for scale-up and reactor design. Therefore, we studied kinetic modelling of the pyrolysis process for one of the most common plastics, polyethylene terephthalate (PET). The focus was to better understand and predict PET pyrolysis when transitioning to a low carbon economy and adhering to environmental and governmental legislation. This work aims at presenting for the first time, the kinetic triplet (activation energy, pre-exponential constant and reaction rate) for the PET pyrolysis using the differential iso-conversional method. This is coupled with the in-situ online tracking of the gaseous emissions using mass spectrometry.Results: The differential iso-conversional method showed activation energy (Ea) values of 165-195 kJ.mol-1, R2 = 0.99659. While the ASTM-E698 showed 165.6 kJ.mol-1 and integral methods such as Flynn-Wall and Ozawa (FWO) (166-180 kJ.mol-1). The in-situ Mass Spectrometry results showed the pyrolysis gaseous emissions which are C1-hydrocarbon and H-O-C=O along with C2 hydrocarbons, C5- C6 hydrocarbons, acetaldehyde, the fragment of O-CH=CH2, hydrogen and water. Conclusions: From the obtained results herein, thermal predictions (isothermal, non-isothermal and step-based heating) were determined based on the kinetic parameters and can be used at numerous scales with a high level of accuracy compared with the literature.


2020 ◽  
Vol 20 (20) ◽  
pp. 12063-12091
Author(s):  
Guillaume Monteil ◽  
Grégoire Broquet ◽  
Marko Scholze ◽  
Matthew Lang ◽  
Ute Karstens ◽  
...  

Abstract. Atmospheric inversions have been used for the past two decades to derive large-scale constraints on the sources and sinks of CO2 into the atmosphere. The development of dense in situ surface observation networks, such as ICOS in Europe, enables in theory inversions at a resolution close to the country scale in Europe. This has led to the development of many regional inversion systems capable of assimilating these high-resolution data, in Europe and elsewhere. The EUROCOM (European atmospheric transport inversion comparison) project is a collaboration between seven European research institutes, which aims at producing a collective assessment of the net carbon flux between the terrestrial ecosystems and the atmosphere in Europe for the period 2006–2015. It aims in particular at investigating the capacity of the inversions to deliver consistent flux estimates from the country scale up to the continental scale. The project participants were provided with a common database of in situ-observed CO2 concentrations (including the observation sites that are now part of the ICOS network) and were tasked with providing their best estimate of the net terrestrial carbon flux for that period, and for a large domain covering the entire European Union. The inversion systems differ by the transport model, the inversion approach, and the choice of observation and prior constraints, enabling us to widely explore the space of uncertainties. This paper describes the intercomparison protocol and the participating systems, and it presents the first results from a reference set of inversions, at the continental scale and in four large regions. At the continental scale, the regional inversions support the assumption that European ecosystems are a relatively small sink (-0.21±0.2 Pg C yr−1). We find that the convergence of the regional inversions at this scale is not better than that obtained in state-of-the-art global inversions. However, more robust results are obtained for sub-regions within Europe, and in these areas with dense observational coverage, the objective of delivering robust country-scale flux estimates appears achievable in the near future.


2020 ◽  
Vol 8 (4) ◽  
Author(s):  
Sarah J. Wolff ◽  
Benjamin Gould ◽  
Niranjan Parab ◽  
Cang Zhao ◽  
Aaron Greco ◽  
...  

Abstract In laser melting processes of metallic parts, including welding and additive manufacturing, there are challenges in porosity formation and developing predictive multiphysics of the process. Surrounding a melt pool with an external magnetic field has promise in changing the Marangoni flow and reducing porosity formation. In-situ X-ray imaging enables the observation of melt pool behavior and porosity formation in real-time. This preliminary study shows that an external magnetic field can achieve both, with potential to scale up in industrial processes and to validate multiphysics models.


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