Non-Linear Dynamic Viscoelasticity of Xanthan Gum Solutions

Author(s):  
J. A. Carmona ◽  
P. Ramírez ◽  
N. Calero ◽  
M. C. García ◽  
J. Muñoz
Gels ◽  
2021 ◽  
Vol 7 (2) ◽  
pp. 71
Author(s):  
Takuro Taniguchi ◽  
Kenji Urayama

We investigated the linear dynamic viscoelasticity of dual cross-link (DC) poly(vinyl alcohol) (PVA) (DC-PVA) hydrogels with permanent and transient cross-links. The concentrations of incorporated borate ions to form transient cross-links in the DC-PVA hydrogels (CBIN) were determined by the azomethine-H method. The dynamic viscoelasticity of the DC-PVA hydrogel cannot be described by a simple sum of the dynamic viscoelasticity of the PVA gel with the same permanent cross-link concentration and the PVA aqueous solution with the same borate ion concentration (CB = CBIN) as in the DC-PVA gel. The DC-PVA hydrogel exhibited a considerably higher relaxation strength, indicating that the introduction of permanent cross-links into temporary networks increases the number of viscoelastic chains with finite relaxation times. In contrast, the relaxation frequency (ωc) (given by the frequency at the maximum of loss modulus) for the DC-PVA hydrogel was slightly lower but comparable to that for a dilute PVA solution with the same CB. This signifies that the relaxation dynamics of the DC-PVA hydrogels is essentially governed by the lifetime of an interchain transient cross-link (di-diol complex of boron). The effect of permanent cross-linking on the relaxation dynamics was observed in the finite broadening of the relaxation-time distribution in the long time region.


2020 ◽  
Author(s):  
Gabriel Stockdale ◽  
Vasilis Sarhosis ◽  
Gabriele Milani

2021 ◽  
Vol 11 (11) ◽  
pp. 4898
Author(s):  
Jin-Seon Kim ◽  
Ju-Seong Jung ◽  
Dong-Keun Jung ◽  
Eui-Yong Kim ◽  
Kang-Seok Lee

The present study proposes a new seismic retrofitting method using a concrete-filled tube modular frame (CFT-MF) system, a novel technique to overcome and improve the limitations of existing seismic strengthening methods. This CFT-MF seismic retrofitting method makes the most of the advantages of both concrete and steel pipes, thereby significantly improving constructability and increasing integration between the existing structure and the reinforcement joints. This method falls into the category of typical seismic retrofitting methods that focus on increasing strength, in which the required amount of seismic reinforcement can be easily estimated. Therefore, the method provides an easy solution to improving the strength of existing reinforced concrete (RC) structures with non-seismic details that are prone to shear failure. In the present study, a full-size two-story test frame modeled from existing domestic RC structures with non-seismic details was subjected to pseudo-dynamic testing. As a result, the effect of the CFT-MF system, when applied to existing RC structures, was examined and verified, especially as to its seismic retrofitting performance, i.e., restoring force characteristics, stiffness reinforcement, and seismic response control. In addition, based on the pseudo-dynamic testing results, a restoring force characteristics model was proposed to implement non-linear dynamic analysis of a structure retrofitted with the CFT-MF system (i.e., the test frame). Finally, based on the proposed restoring force characteristics, non-linear dynamic analysis was conducted, and the results were compared with those obtained by the pseudo-dynamic tests. The results showed that the RC frame (building) with no retrofitting measures applied underwent shear failure at a seismic intensity of 200 cm/s2, the threshold applied in seismic design in Korea. In contrast, in the frame (building) retrofitted with the CFT-MF system, only minor earthquake damage was observed, and even when the maximum seismic intensity (300 cm/s2) that may occur in Korean was applied, small-scale damage was observed. These results confirmed the validity of the seismic retrofitting method based on the CFT-MF system developed in the present study. The non-linear dynamic analysis and the pseudo-dynamic test showed similar results, with an average deviation of 10% or less in seismic response load and displacement.


2004 ◽  
Vol 35 (6-8) ◽  
pp. 673-683 ◽  
Author(s):  
Liviu Librescu ◽  
Sang-Yong Oh ◽  
Joerg Hohe

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