Liquid crystalline and charge transport properties of double-decker cerium phthalocyanine complexes

2007 ◽  
Vol 17 (25) ◽  
pp. 2607 ◽  
Author(s):  
Fabien Nekelson ◽  
Hirosato Monobe ◽  
Motoo Shiro ◽  
Yo Shimizu
Soft Matter ◽  
2018 ◽  
Vol 14 (11) ◽  
pp. 2104-2111 ◽  
Author(s):  
J. Szydłowska ◽  
A. Sitkiewicz ◽  
E. Nazaruk ◽  
D. Pociecha ◽  
P. Krzyczkowska ◽  
...  

Mesogenic dibenzophenazine derivatives have been synthesized and their liquid crystalline, fluorescent and electrochemical properties have been studied.


2010 ◽  
Vol 114 (10) ◽  
pp. 4617-4627 ◽  
Author(s):  
Vincent Lemaur ◽  
Saïd Bouzakraoui ◽  
Yoann Olivier ◽  
Patrick Brocorens ◽  
Cédric Burhin ◽  
...  

Author(s):  
Beatriz Feringán ◽  
Roberto Termine ◽  
Attilio Golemme ◽  
Jose M. Granadino-Roldan ◽  
Amparo Navarro ◽  
...  

Despite the fact that triphenylamine derivatives have been widely explored as hole-transporting materials, studies on charge transport properties in the liquid crystal phase have been overlooked. Here, it is reported...


2019 ◽  
Vol 7 (42) ◽  
pp. 13192-13202 ◽  
Author(s):  
Ming-Cong Yang ◽  
Jun-ichi Hanna ◽  
Hiroaki Iino

Mobility shows Poole–Frenkel like behaviour in the low order mesophase of liquid crystalline organic semiconductors based on an electron-deficient dibenzo[c,h][2,6]naphthyridine (DBN) derivative.


2012 ◽  
Vol 48 (26) ◽  
pp. 3209 ◽  
Author(s):  
Frédéric Lincker ◽  
André-Jean Attias ◽  
Fabrice Mathevet ◽  
Benoît Heinrich ◽  
Bertrand Donnio ◽  
...  

2015 ◽  
Vol 3 (8) ◽  
pp. 1757-1765 ◽  
Author(s):  
Lydia Sosa-Vargas ◽  
Fabien Nekelson ◽  
Daiju Okuda ◽  
Minokazu Takahashi ◽  
Yukimasa Matsuda ◽  
...  

Enhancement of the Col mesophase thermal stability, high carrier mobility in ambipolar nature and strong tendency towards homeotropic alignment.


2019 ◽  
Vol 7 (19) ◽  
pp. 5724-5738 ◽  
Author(s):  
Indu Bala ◽  
Wan-Yun Yang ◽  
Santosh Prasad Gupta ◽  
Joydip De ◽  
Rohit Ashok Kumar Yadav ◽  
...  

Room temperature discotic dyads as emitters in blue OLEDs and their TNF complexes with ambipolar charge transport properties.


2019 ◽  
Vol 23 (11n12) ◽  
pp. 1603-1615
Author(s):  
Chandana Pal ◽  
Isabelle Chambrier ◽  
Andrew N. Cammidge ◽  
A. K. Sharma ◽  
Asim K. Ray

In-plane electrical characteristics of non-peripherally octyl(C[Formula: see text]H[Formula: see text]- and hexyl(C[Formula: see text]H[Formula: see text]-substituted liquid crystalline (LC) double decker lanthanide bisphthalocyanine (LnPc[Formula: see text] complexes with central metal ions lutetium (Lu), and gadolinium (Gd) have been measured in thin film formulations on interdigitated gold (Au) electrodes for the applied voltage ([Formula: see text] range of [Formula: see text]. The conduction mechanism is found to be Ohmic within the bias of [Formula: see text] while the bulk limited Poole–Frenkel mechanism is responsible for the higher bias. The compounds show individual characteristics depending on the central metal ions, substituent chain lengths and their mesophases. Values of 67.55 [Formula: see text]cm[Formula: see text] and 42.31 [Formula: see text]cm[Formula: see text] have been obtained for room temperature in-plane Ohmic conductivity of as-deposited octyl lutetium (C[Formula: see text]LuPc[Formula: see text] and hexyl gadolinium (C[Formula: see text]GdPc[Formula: see text] films, respectively while C[Formula: see text]GdPc[Formula: see text] films exhibit nearly two orders of magnitude smaller conductivity. On annealing at 80[Formula: see text]C, Ohmic conductivities of C[Formula: see text]LuPc[Formula: see text] and C[Formula: see text]GdPc[Formula: see text] are found to have increased but the conductivity of C[Formula: see text]GdPc[Formula: see text] decreased by more than one order of magnitude to 1.5 [Formula: see text]cm[Formula: see text]. For physical interpretation of the charge transport behavior of these three molecules, their UV-vis optical absorption spectra in the solution and in as-deposited and annealed solid phases and atomic force microscopy study have been performed. It is believed that both orientation and positional reorganizations are responsible, depending upon the size of the central ion and side chain length.


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