Excited-state proton coupled charge transfer modulated by molecular structure and media polarization

2013 ◽  
Vol 42 (3) ◽  
pp. 1379-1408 ◽  
Author(s):  
Alexander P. Demchenko ◽  
Kuo-Chun Tang ◽  
Pi-Tai Chou
Keyword(s):  
Molecular Structure ◽  
Excited State ◽  
Charge Transfer

scholarly journals Theoretical research on excited-state intramolecular proton coupled charge transfer modulated by molecular structure

RSC Advances ◽  
2018 ◽  
Vol 8 (52) ◽  
pp. 29662-29669
Author(s):  
Dapeng Yang ◽  
Guang Yang ◽  
Min Jia ◽  
Xiaoyan Song ◽  
Qiaoli Zhang ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Excited State ◽  
Charge Transfer ◽  
Energy Barrier ◽  
Theoretical Research ◽  
Small Energy

Charge transfer from O1 to O2 of 3HFN results in proton H1 transfer from O1 to O2 in S1 state, while small energy barrier facilitates proton H1 transfer from O1 to N1 in S1 state of diCN-HBO, which results in charge transfer from O1 to di-cyano.

Radiationless Deactivation of an Intramolecular Charge Transfer Excited State through Hydrogen Bonding:  Effect of Molecular Structure and Hard−Soft Anionic Character in the Excited State

2001 ◽  
Vol 105 (45) ◽  
pp. 10488-10496 ◽  
Author(s):  
Akimitsu Morimoito ◽  
Tomoyuki Yatsuhashi ◽  
Tetsuya Shimada ◽  
László Biczók ◽  
Donald A. Tryk ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Hydrogen Bonding ◽  
Excited State ◽  
Charge Transfer ◽  
Intramolecular Charge Transfer ◽  
Bonding Effect ◽  
Hydrogen Bonding Effect

scholarly journals Ingenious modification of molecular structure effectively regulates excited-state intramolecular proton and charge transfer: a theoretical study based on 3-hydroxyflavone

RSC Advances ◽  
2018 ◽  
Vol 8 (52) ◽  
pp. 29589-29597 ◽  
Author(s):  
Jianhui Han ◽  
Xiaochun Liu ◽  
Chaofan Sun ◽  
You Li ◽  
Hang Yin ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Excited State ◽  
Charge Transfer ◽  
Proton Transfer ◽  
Theoretical Study ◽  
Intramolecular Charge Transfer ◽  
Intramolecular Proton Transfer ◽  
Great Promise ◽  
Fluorescence Sensing

Harnessing ingenious modification of molecular structure to regulate excited-state intramolecular proton transfer (ESIPT) and intramolecular charge transfer (ICT) characteristics holds great promise in fluorescence sensing and imaging.

Etude spectroscopique de l'aniline dans les solvants

1975 ◽  
Vol 53 (10) ◽  
pp. 1461-1467 ◽  
Author(s):  
P. Méallier ◽  
A. Berthelon ◽  
B. Pouyet
Keyword(s):  
Molecular Structure ◽  
Dipole Moment ◽  
Excited State ◽  
Charge Transfer ◽  
Ground State ◽  
Aromatic Amines ◽  
Photochemical Oxidation ◽  
Transfer Effects ◽  
Absorption Bands ◽  
Oxidation Processes

The effect of change of solvent on the positions and intensities of absorption bands of some aromatic amines between 200 and 400 nm has been examined. In particular, the behavior of the band at 280 nm has been studied.In hydroxylic solvents, this band is displaced towards shorter wavelengths, and the dipole moment in the excited state of the molecule is smaller than in the ground state. The opposite effects are found when nonhydroxylic solvents are used.The results show how the molecular structure is altered by charge transfer effects and can explain how different solvents affect photochemical oxidation processes.

Spiroconjugated Intramolecular Charge-Transfer Emission in Non-Typical Spiroconjugated Molecules: The Effect of Molecular Structure upon the Excited-State Configuration

ChemPhysChem ◽  
2013 ◽  
Vol 14 (5) ◽  
pp. 982-989 ◽  
Author(s):  
Linna Zhu ◽  
Cheng Zhong ◽  
Cui Liu ◽  
Zhongyin Liu ◽  
Jingui Qin ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Excited State ◽  
Charge Transfer ◽  
Intramolecular Charge Transfer ◽  
State Configuration

Picosecond Infrared Spectra of Isotope-Substituted 4-(Dimethylamino)benzonitriles and Molecular Structure of the Charge-Transfer Singlet Excited State

2001 ◽  
Vol 105 (17) ◽  
pp. 4182-4188 ◽  
Author(s):  
Hiromi Okamoto ◽  
Hironori Inishi ◽  
Yuko Nakamura ◽  
Shigeru Kohtani ◽  
Ryoichi Nakagaki
Keyword(s):  
Molecular Structure ◽  
Excited State ◽  
Charge Transfer ◽  
Infrared Spectra ◽  
Singlet Excited State

Dynamic adjustment of emission from both singlets and triplets: the role of excited state conformation relaxation and charge transfer in phenothiazine derivates

2021 ◽  
Author(s):  
Weidong Qiu ◽  
Xinyi Cai ◽  
Mengke Li ◽  
Liangying Wang ◽  
Yanmei He ◽  
...  
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Intramolecular Charge Transfer ◽  
Dynamic Adjustment ◽  
Twisted Intramolecular Charge Transfer

Dynamic adjustment of emission behaviours by controlling the extent of twisted intramolecular charge transfer character in excited state.

Novel Carbazole-based Multifunctional Materials with Hybridized Local and Charge-Transfer Excited State Acting as Deep Blue Emitters and Phosphorescent Hosts for Highly Efficient Organic Light-Emitting Diodes

2021 ◽  
Author(s):  
Haitao Zhou ◽  
Mengna Yin ◽  
Zhenhong Zhao ◽  
Yanqin Miao ◽  
Xin Jin ◽  
...  
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Light Emitting Diodes ◽  
Organic Light Emitting Diodes ◽  
Multifunctional Materials ◽  
Light Emitting ◽  
Highly Efficient ◽  
Deep Blue ◽  
Organic Light ◽  
Blue Emitters

In this work, two carbazole- and benzo[d]oxazole-based novel multifunctional materials with hybridized local and charge-transfer (HLCT) characteristic, namely OCI and OCT, which could act as deep-blue fluorophors and phosphorescent hosts,...

scholarly journals Anion-enhanced excited state charge separation in a spiro-locked N-heterocycle-fused push-pull zinc porphyrin

2021 ◽  
Author(s):  
Mandeep K. Chahal ◽  
Anuradha Liyanage ◽  
Ajyal Z. Alsaleh ◽  
Paul A. Karr ◽  
Jonathan P. Hill ◽  
...  
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Charge Separation ◽  
Charge Transfer Complex ◽  
Zinc Porphyrin ◽  
New Type ◽  
State Charge

A new type of push–pull charge transfer complex, viz., a spiro-locked N-heterocycle-fused zinc porphyrin, ZnP-SQ, is shown to undergo excited state charge separation, which is enhanced by axial F− binding to the Zn center.

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