A cuprous oxide–reduced graphene oxide (Cu2O–rGO) composite photocatalyst for hydrogen generation: employing rGO as an electron acceptor to enhance the photocatalytic activity and stability of Cu2O

Nanoscale ◽  
2012 ◽  
Vol 4 (13) ◽  
pp. 3875 ◽  
Author(s):  
Phong D. Tran ◽  
Sudip K. Batabyal ◽  
Stevin S. Pramana ◽  
James Barber ◽  
Lydia H. Wong ◽  
...  
2014 ◽  
Vol 07 (02) ◽  
pp. 1450013 ◽  
Author(s):  
Jie Zhu ◽  
Wanhong He ◽  
Lu Zhang ◽  
Xu Xiang ◽  
Zhiwei Li

A new protocol was developed to obtain a composite photocatalyst by incorporating indium to ZnO and subsequently assembling it with reduced graphene oxide (RGO) sheets. The incorporation of indium led to lattice distortion of ZnO and introduction of defect levels. The hybridization with RGO could improve the electron transport and extend the lifetime of photo-generated carriers, leading to enhanced activity for dye degradation driven by visible light. The photocatalytic activity appeared to be dependent on the relative quantity of RGO. The optimized quantity resulted in the highest activity due to the dual role of electron shuttle and "shielding effect" of RGO. In addition, the composite photocatalyst exhibited excellent repeatable use performance, suggestive of its high stability. This study proposed a promising strategy to construct photocatalysts by rational bandgap engineering and tunable composite technology.


2021 ◽  
pp. 138897
Author(s):  
Suresh Sagadevan ◽  
J. Anita Lett ◽  
Getu Kassegn Weldegebrieal ◽  
Md Rokon ud Dowla Biswas ◽  
Won Chun Oh ◽  
...  

NANO ◽  
2017 ◽  
Vol 12 (03) ◽  
pp. 1750032 ◽  
Author(s):  
H.-Y. He

Reduced graphene oxide-SnSe (rGO-SnSe) nanohybrids were synthesized with a solution chemical reaction at room temperature. The nanohybrids were characterized by various techniques for their microstructural and photocatalytic activities in photodegradation of alkaline dye malachite green in the water. The effects of rGO/SnSe ratio, initial solution pH, and H2O2 concentration on the photodegradation efficiency were studied. The SnSe nanocrystallines with nanoscale size and narrow bandgap were formed and uniformly adhered on the rGO surface. Raman analysis confirmed the reduction of GO. The experimental results indicated that the nanohybrids showed excellent sunlight-excited photocatalytic activity in degrading malachite green in the water. Significantly, the nanohybrids showed remarkable photo-Fenton-like catalytic activity. The photodegradation rates of the hybrids were greater than that of SnSe nanoparticles, increased with increasing rGO/SnSe ratio, and related to operation parameters. High photocatalytic activities were ascribed to the efficiency interface effect that was confirmed by the calculations of band energy level and photoconductivity. The TOC measurement further verified the photodegradation results. The nanoparticles and nanohybrids also showed excellent reusability.


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