scholarly journals Heterogeneous catalysts based on supported Rh–NHC complexes: synthesis of high molecular weight poly(silyl ether)s by catalytic hydrosilylation

2014 ◽  
Vol 4 (1) ◽  
pp. 62-70 ◽  
Author(s):  
Guillermo Lázaro ◽  
Francisco J. Fernández-Alvarez ◽  
Manuel Iglesias ◽  
Cristina Horna ◽  
Eugenio Vispe ◽  
...  
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Heterogeneous Catalysts ◽  
Silyl Ether ◽  
Catalytic Hydrosilylation ◽  
High Molecular Weight Poly

Linear and high-molecular-weight poly-porphyrins for efficient photodynamic therapy

2021 ◽  
Author(s):  
Nan Zheng ◽  
Xiahui Li ◽  
Shangwei Huangfu ◽  
Kangkai Xia ◽  
Ruofei Yue ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Photodynamic Therapy ◽  
Quantum Yield ◽  
Singlet Oxygen ◽  
High Molecular Weight ◽  
Linear Poly ◽  
High Molecular Weight Poly

A linear poly-porphyrin with high Mw and conjugated by PEG and acetazolamide was developed with enhanced singlet oxygen quantum yield, improved photo-toxicity and excellent in vivo photodynamic therapy.

Stereo-chemical contributions to the glass transition and liquid–liquid phase separation in high molecular weight poly(N-vinyl carbazole)

RSC Advances ◽  
2016 ◽  
Vol 6 (35) ◽  
pp. 29326-29333 ◽  
Author(s):  
Abdul G. Al Lafi ◽  
James N. Hay
Keyword(s):  
Molecular Weight ◽  
Glass Transition ◽  
Phase Separation ◽  
Liquid Phase ◽  
High Molecular Weight ◽  
Structural Properties ◽  
Thermal History ◽  
Liquid Phase Separation ◽  
High Molecular Weight Poly ◽  
Liquid Liquid Phase Separation

Thermal history and purification effects on the structural properties of PVK were investigated. Liquid–liquid phase separation is suggested to occur by separation of isotactic rich segments from a matrix which is predominantly atactic.

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