Synthesis of cyclic carbonates from CO2 and epoxides using ionic liquids and related catalysts including choline chloride–metal halide mixtures

2014 ◽  
Vol 4 (6) ◽  
pp. 1513-1528 ◽  
Author(s):  
Qing He ◽  
Jeremy W. O'Brien ◽  
Kayla A. Kitselman ◽  
Lindsay E. Tompkins ◽  
Gregory C. T. Curtis ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Choline Chloride ◽  
Cycloaddition Reactions ◽  
Cyclic Carbonates ◽  
The Past ◽  
Focus On Results ◽  
Primary Focus ◽  
Made In

In this mini-review, progress made in the use of ionic liquid catalysts and related systems for cycloaddition reactions of carbon dioxide with epoxides is described with the primary focus on results from the past eight years.

scholarly journals Synthesis of Cyclic Carbonates from Olefin Oxides and Carbon Dioxide. Part 1. Catalysis by Ionic Liquids

2016 ◽  
Vol 16 (3) ◽  
pp. 6-16
Author(s):  
A. V. Sulimov ◽  
A. V. Ovcharova ◽  
A. A. Ovcharov ◽  
T. A. Ryabova ◽  
G. M. Kravchenko ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Cyclic Carbonates ◽  
Olefin Oxides

Catalytic applications of immobilized ionic liquids for synthesis of cyclic carbonates from carbon dioxide and epoxides

2013 ◽  
Vol 30 (11) ◽  
pp. 1973-1984 ◽  
Author(s):  
Dong-Woo Kim ◽  
Roshith Roshan ◽  
Jose Tharun ◽  
Amal Cherian ◽  
Dae-Won Park
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Cyclic Carbonates ◽  
Catalytic Applications

scholarly journals Highly efficient synthesis of alkylidene cyclic carbonates from low concentration CO2 using hydroxyl and azolate dual functionalized ionic liquids

2021 ◽  
Author(s):  
Guiling Shi ◽  
Ran Zhai ◽  
Haoran Li ◽  
Congmin Wang
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Catalytic System ◽  
Cyclic Carbonates ◽  
Efficient Synthesis ◽  
Excellent Performance ◽  
Functionalized Ionic Liquid ◽  
Low Concentration ◽  
Propargylic Alcohols ◽  
Highly Efficient

A dual functionalized ionic liquid catalytic system was developed for the reaction between CO2 and propargylic alcohols, and exhibited excellent performance and good reusability, even under a low concentration of CO2 in a gram-scale reaction.

Distillable ionic liquids for a new multicomponent reaction

2007 ◽  
Vol 79 (11) ◽  
pp. 1869-1877 ◽  
Author(s):  
Anthony E. Rosamilia ◽  
Christopher R. Strauss ◽  
Janet L. Scott
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Multicomponent Reaction ◽  
Reaction Medium ◽  
Building Blocks ◽  
Substituted Anilines ◽  
Reaction Sequence ◽  
Unsaturated Ketones ◽  
Direct Preparation

Adducts of dimethylamine and carbon dioxide form a "distillable ionic liquid" (DIMCARB) that may used as both a reaction medium and catalyst in the direct, atom-economical synthesis of useful synthetic building blocks, such as mono-condensed α,β-unsaturated ketones. The utilization of such building blocks in the synthesis of two new classes of versatile macrocycles, by a sequence of condensation reactions (H2O by-product), is described. Investigation into the mechanism of action of DIMCARB catalysis and observation of an aniline impurity arising from a competing reaction sequence led to development of a new multicomponent reaction for the direct preparation of 2- or 4-substituted anilines. Some of the macrocycles and anilines are, respectively, supramolecular host compounds and ligands for the preparation of metal complexes.

Ionic Liquid [Bmim]OH Grafted Catalyst for Cycloaddition of Carbon Dioxide

2014 ◽  
Vol 989-994 ◽  
pp. 676-679 ◽  
Author(s):  
Xue Lan Zhang ◽  
Deng Feng Wang
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Silica Gel ◽  
Propylene Carbonate ◽  
Propylene Oxide ◽  
Heterogeneous Catalysts ◽  
Element Analysis ◽  
Mild Conditions ◽  
Adsorption Desorption

An ionic liquid 1-butyl-3-methylimidazolium hydroxide ([Bmim]OH) was grafted on silica gel by post-grafting method. Such grafted ionic liquids (GILs) which were verified by means of FTIR, element analysis N2adsorption-desorption and TG could be used as highly effective heterogeneous catalysts toward propylene carbonate synthesis through cycloaddition of carbon dioxide with propylene oxide under solventless and mild conditions.

Highly efficient synthesis of cyclic carbonates from carbon dioxide and epoxides catalyzed by ionic liquid [Heemim][ZrCl5]

RSC Advances ◽  
2015 ◽  
Vol 5 (83) ◽  
pp. 67886-67891 ◽  
Author(s):  
Yu-Lin Hu ◽  
Ming Lu ◽  
Xue-Lin Yang
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquid ◽  
Cycloaddition Reaction ◽  
Cyclic Carbonates ◽  
Efficient Synthesis ◽  
Highly Efficient

A facile and efficient synthesis of cyclic carbonates by cycloaddition reaction is described.

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