Interweaving spins with their environment: novel inorganic nanohybrids with controllable magnetic properties

2014 ◽  
Vol 43 (11) ◽  
pp. 4220-4232 ◽  
Author(s):  
Christian Cervetti ◽  
Eric Heintze ◽  
Lapo Bogani
Keyword(s):  
Magnetic Properties ◽  
Nanostructured Materials ◽  
Molecular Magnets ◽  
Synthesis And Characterization ◽  
Magnetic Nanohybrids

We discuss the developments in the synthesis and characterization of magnetic nanohybrids made of molecular magnets and nanostructured materials.

scholarly journals Synthesis and characterization of nanostructured ceramics powders for biomedical applications

2007 ◽  
Vol 12 (4) ◽  
pp. 574-582 ◽  
Author(s):  
Nelson Heriberto de Almeida Camargo ◽  
O. J. Bellini ◽  
Enori Gemelli ◽  
M. Tomiyama
Keyword(s):  
Calcium Phosphate ◽  
Nanostructured Materials ◽  
Biomedical Applications ◽  
Calcium Phosphates ◽  
Morphological Characterization ◽  
Synthesis And Characterization ◽  
Powder Synthesis ◽  
Mineralogical Characteristics ◽  
Nanostructured Ceramics

Nanostructured materials have been largely studied in the last few years because they have a great potential to applications in different fields like physics, chemistry, biology, mechanic and medicine. Synthesis and characterization of nanostructured materials is a subject of great interest involving science, market, politicians, government and society. The nanostructured materials are in demand in biomedical area, mainly the bioceramics composed of calcium phosphates (Ca/P), which have an excellent biocompatibility and mineralogical characteristics similar to those of bones. The aim of this work was to optimize the method of powder synthesis of nanostructured calcium phosphate and of nanocomposites composed of calcium phosphate//SiO2n, containing 5, 10 and 15% (in volume) of nanometric silica (SiO2n). The results are expressed according to the method of synthesis, mineralogical and morphological characterization, and thermal behavior for the different compositions of the nanostructured powder synthesized.

Synthesis and Characterization of Particle-reinforced Ni/Al2O3 Nanocomposites

2002 ◽  
Vol 17 (6) ◽  
pp. 1412-1418 ◽  
Author(s):  
I. Shao ◽  
P. M. Vereecken ◽  
C. L. Chien ◽  
P. C. Searson ◽  
R. C. Cammarata
Keyword(s):  
Magnetic Properties ◽  
Rotation Rate ◽  
Particle Concentration ◽  
Volume Fraction ◽  
Particle Dispersion ◽  
Nanocomposite Films ◽  
Synthesis And Characterization ◽  
Electrode Rotation ◽  
Deposition Current Density

Nanocomposite Ni/Al2O3 films were electrodeposited from a suspension of Al2O3 nanoparticles in aqueous nickel sulfamate solution. The volume fraction of particles incorporated increased with electrode rotation rate and decreased with deposition current density. The composition, microstructure, hardness, and magnetic properties of these nanocomposite films were characterized. The mechanical strengthening due to particle dispersion in the films was interpreted by considering an Orowan dislocation bowing mechanism. The coercivity of the films increased with increasing particle concentration in the film. The saturation magnetization showed a weak dependence on particle concentration.

Synthesis and Characterization of Zwitterionic SBA-15 Nanostructured Materials

2010 ◽  
Vol 22 (23) ◽  
pp. 6459-6466 ◽  
Author(s):  
Montserrat Colilla ◽  
Isabel Izquierdo-Barba ◽  
Sandra Sánchez-Salcedo ◽  
José L. G. Fierro ◽  
José L. Hueso ◽  
...  
Keyword(s):  
Nanostructured Materials ◽  
Synthesis And Characterization

Preparation and properties of thienyl and 2,2′-bithienyl substituted cobalt-bis(semiquinone) valence tautomers

2009 ◽  
Vol 87 (4) ◽  
pp. 533-538 ◽  
Author(s):  
Thomas J. O’Sullivan ◽  
Brandon Djukic ◽  
Paul A. Dube ◽  
Martin T. Lemaire
Keyword(s):  
Magnetic Properties ◽  
Synthesis And Characterization ◽  
Electronic And Magnetic Properties ◽  
Valence Tautomers

The synthesis and characterization of two new 2,2′-bipyridine ligands containing 3-ethynylthiophene and 3,3′-diethynyl-2,2′-bithiophene substituents is presented, along with the preparation, electronic, and magnetic properties of mono- and bimetallic cobalt-semiquinone valence tautomers containing these ligands.

Synthesis and Characterization of the First 1:2 Ordered Perovskite Ruthenate

2002 ◽  
Vol 718 ◽  
Author(s):  
Job Rijssenbeek ◽  
Sylvie Malo ◽  
Takashi Saito ◽  
Vincent Caignaert ◽  
Masaki Azuma ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Neutron Diffraction ◽  
Structure Type ◽  
Synthesis And Characterization ◽  
Neutron Diffraction Data ◽  
X Ray ◽  
Relationship Of ◽  
The Relationship ◽  
Perovskite Lattice

AbstractPerovskite-like mixed metal ruthenates are of interest owing to their varied electronic and magnetic properties, which are heavily dependent on the ordering of the transition metals. We report the synthesis and structural characterization of the first 1:2 ordered perovskite ruthenate, Sr3CaRu2O9. The structure was determined from a combination of powder X-ray, electron and neutron diffraction data and is characterized by a 1:2 ordering of Ca2+ and Ru5+ over the sixcoordinate B-sites of the perovskite lattice. Sr3CaRu2O9 is the first example of this structure-type to include a majority metal with d electrons (Ru(V), d3). The relationship of this material to the K2NiF4-type Sr1.5Ca0.5RuO4 (i.e., Sr3CaRu2O8) highlights the dramatic effects of the ruthenium valence on the resultant structure. Remarkably, these two structures can be quantitatively interconverted by the appropriate choice of reaction temperature and atmosphere.

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