Enhancement in the photocatalytic degradation of low density polyethylene–TiO2 nanocomposite films under solar irradiation

RSC Advances ◽  
2013 ◽  
Vol 3 (33) ◽  
pp. 14080 ◽  
Author(s):  
Reny Thankam Thomas ◽  
N. Sandhyarani
2020 ◽  
Vol 40 (2) ◽  
pp. 181-191 ◽  
Author(s):  
Parisa Kamalian ◽  
Saied Nouri Khorasani ◽  
Amir Abdolmaleki ◽  
Mehdi Karevan ◽  
Shahla Khalili ◽  
...  

AbstractIn this research, the photocatalytic degradation performance in a commercial low-density polyethylene (LDPE) film was investigated in the presence of zinc oxide (ZnO) nanoparticles grafted with two amounts of polyacrylamide. Fourier-transform infrared spectroscopy (FTIR) besides thermogravimetric analysis (TGA) test results reinforced the successful grafting of polyacrylamide to the extent of 10 and 39 wt.% on the ZnO nanoparticles. The photocatalytic degradation of the films under ultraviolet (UV) radiation was evaluated by characterizing the mechanical properties, weight loss, and morphology. The UV absorption and emission for ZnO nanoparticles were increased after grafting with 10% polyacrylamide. The tensile strength of the nanocomposite films increased with the incorporation of nanoparticles. The presence of ZnO nanoparticles in LDPE films increased the rate of degradation after 200 h of irradiation. The polyacrylamide grafting improved the dispersion of ZnO particles in LDPE matrix, whereas the increase of grafting extent from 10 to 39 wt.% reduced the photocatalytic performance of ZnO nanoparticles.


RSC Advances ◽  
2015 ◽  
Vol 5 (98) ◽  
pp. 80739-80748 ◽  
Author(s):  
Hua-Dong Huang ◽  
Sheng-Yang Zhou ◽  
Peng-Gang Ren ◽  
Xu Ji ◽  
Zhong-Ming Li

The successful conversion from hydrophilic GONSs to hydrophobic ODA–GONSs imparts LDPE nanocomposite films with enhanced mechanical and barrier performances for potential packaging materials.


Author(s):  
Saba Sadaqat Ali ◽  
Ishtiaq A. Qazi ◽  
Muhammad Arshad ◽  
Zahiruddin Khan ◽  
Thomas C. Voice ◽  
...  

2013 ◽  
Vol 129 (4) ◽  
pp. 1907-1914 ◽  
Author(s):  
Funda Inceoglu ◽  
Yusuf Ziya Menceloglu

2014 ◽  
Vol 27 ◽  
pp. 53-64 ◽  
Author(s):  
Maryam Jokar ◽  
Russly Abdul Rahman ◽  
Luqman Chuah Abdullah

Colloidal Silver nanoparticles with a size of 5 nm produced by chemical reduction using poly ethylene glycol (PEG 200). Layers of silver nanoparticles and chitosan were deposited onto low density polyethylene (LDPE) substrate by layer by layer (LBL) self-assembly technique. Silver nanocomposite films were built by sequential dipping of LDPE film in either anionic silver nanoparticles or cationic chitosan. Silver nanoparticles and chitosan led to the formation of nanocomposite films possessing antimicrobial properties with the thickness of 2, 4, 8, 12 and 20 layers. Silver nanocomposite films were characterized by atomic force microscopy (AFM). Thermal, mechanical and barrier properties of LBL deposited nanocomposite films were investigated. Results showed that the LBL deposition of silver nanoparticles and chitosan increased the crystallinity of the composites and also improved mechanical and barrier properties of LDPE film significantly (p<0.05). Antimicrobial activity of silver nanocomposites againstEscherichia coliandStaphylococcus aureuswas evaluated. Growth kinetic parameters ofE.coliandS.aureusaffected by silver nanocomposites were calculated by modeling of absorbance data according to Gomperz equation. LDPE-silver nanocomposite affected bacterial growth parameters significantly (p<0.05). The specific growth rate reduced from 0.30 to 0.11 h-1forE. coliand decreased 0.27 to 0.06 h-1forS. aureus.


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