Synthesis of chlorinated and anhydride-modified low density polyethylene by solid-phase chlorination and grafting—improving the adhesion of a film-forming polymer

RSC Advances ◽  
2014 ◽  
Vol 4 (24) ◽  
pp. 12490-12496 ◽  
Author(s):  
Yuan Wang ◽  
Lijuan Liu ◽  
Zhao Jing ◽  
Jiruo Zhao ◽  
Ying Feng

Maleic anhydride was grafted onto high chlorinated polyethylene made of low density polyethylene (LHCPE) prepared from low density polyethylene by in situ chlorinating graft copolymerization, to improve the adhesion.

2020 ◽  
Vol 20 (5) ◽  
pp. 1110
Author(s):  
Iman Rahayu ◽  
Achmad Zainuddin ◽  
Sunit Hendrana

A common graft copolymerization method usually results in a low degree of grafting due to its poor inter-component interactions. A monomer microencapsulation method should be useful to enhance the current graft copolymerization technique. The maleic anhydride (MAH) grafted with linear low-density polyethylene (LLDPE) was successfully synthesized by monomer microencapsulation without using a direct method in order to find a high degree of grafting. The results showed that the degree of grafting of the LLDPE synthesized by microencapsulation (5.9%) was higher than that achieved with the direct method (5.0%).


2016 ◽  
Vol 81 (5) ◽  
pp. 589-605 ◽  
Author(s):  
Nenad Djordjevic ◽  
Aleksandar Marinkovic ◽  
Jasmina Nikolic ◽  
Sasa Drmanic ◽  
Milica Rancic ◽  
...  

The morphological, thermal and barrier properties of low-density polyethylene/polycaprolactone-modified nanocellulose hybrid materials were investigated in this paper. Nanonocelulose/magnetite (NC-Fe3O4) nanocomposite and maleic acid functionalized NC/magnetite (NCMA-Fe3O4) nanocomposite were prepared and used as filler at various concentrations (5, 10 and 15 wt. %) in polycaprolactone (PCL) layer. PE was coated with PCL/NC/magnetite layer. The addition of the filler did not unfavorably affect the inherent properties of the polymer, especially its barrier properties. Oxygen permeation measurements show that the oxygen barrier properties of magnetite enriched PCL film were improved due to chemical activity of added material. The highest level of barrier capacity was observed for PE samples coated with PCL based composite with NCMA-Fe3O4 micro/-nanofiller, which implies the significant contribution of nanocellulose surface modification with maleic anhydride residue to improved barrier properties.


2018 ◽  
Vol 191 (1) ◽  
pp. 20-29
Author(s):  
Lijuan He ◽  
Huiqin Niu ◽  
Yue Ma ◽  
Dawei Li ◽  
Lei Zhao ◽  
...  

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