The origin of high electrolyte–electrode interfacial resistances in lithium cells containing garnet type solid electrolytes

2014 ◽  
Vol 16 (34) ◽  
pp. 18294-18300 ◽  
Author(s):  
Lei Cheng ◽  
Ethan J. Crumlin ◽  
Wei Chen ◽  
Ruimin Qiao ◽  
Huaming Hou ◽  
...  
Keyword(s):  
Solid Electrolytes ◽  
Interfacial Resistance ◽  
Lithium Cells

High interfacial resistance in Li7La3Zr2O12(LLZO)/Li cells is correlated with the presence of Li2CO3on LLZO surfaces.

Novel Structured Electrolyte for All-Solid-State Lithium Ion Batteries

2015 ◽  
Author(s):  
Wei Liu ◽  
Ryan Milcarek ◽  
Kang Wang ◽  
Jeongmin Ahn
Keyword(s):  
Solid State ◽  
Lithium Ion Batteries ◽  
Solid Electrolytes ◽  
Material Selection ◽  
Layer Structure ◽  
Gel Polymer Electrolyte ◽  
Lithium Ion ◽  
Interfacial Resistance ◽  
Solid State Electrolyte ◽  
Ceramic Electrolyte

In this study, a multi-layer structure solid electrolyte (SE) for all-solid-state electrolyte lithium ion batteries (ASSLIBs) was fabricated and characterized. The SE was fabricated by laminating ceramic electrolyte Li1.3Al0.3Ti1.7(PO4)3 (LATP) with polymer (PEO)10-Li(N(CF3SO2)2 electrolyte and gel-polymer electrolyte of PVdF-HFP/ Li(N(CF3SO2)2. It is shown that the interfacial resistance is generated by poor contact at the interface of the solid electrolytes. The lamination protocol, material selection and fabrication method play a key role in the fabrication process of practical multi-layer SEs.

Single- and double-ion type cross-linked polysiloxane solid electrolytes for lithium cells

1993 ◽  
Vol 41 (3) ◽  
pp. 291-298 ◽  
Author(s):  
Hiromori Tsutsumi ◽  
Masahiro Yamamoto ◽  
Masayuki Morita ◽  
Yoshiharu Matsuda ◽  
Takashi Nakamura ◽  
...  
Keyword(s):  
Solid Electrolytes ◽  
Lithium Cells

scholarly journals Evaluation of Ga0.2Li6.4Nd3Zr2O12 garnets: exploiting dopant instability to create a mixed conductive interface to reduce interfacial resistance for all solid state batteries

2021 ◽  
Vol 50 (39) ◽  
pp. 13786-13800
Author(s):  
M. P. Stockham ◽  
B. Dong ◽  
M. S. James ◽  
Y. Li ◽  
Y. Ding ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Interfacial Resistance ◽  
Low Resistance ◽  
Eutectic Mixtures ◽  
Solid State Batteries ◽  
All Solid State Batteries ◽  
Lithium Garnets

Lithium garnets are promising solid electrolytes; however, they suffer from intrinsically high interfacial resistance. In this work we exploit Ga dopant instability to form Li/Ga eutectic mixtures that give very low resistance at the Li interface.

Surface modification of garnet with amorphous SnO2via atomic layer deposition

2020 ◽  
Vol 8 (35) ◽  
pp. 18087-18093
Author(s):  
Bin Tang ◽  
Longxue Gao ◽  
Junqing Liu ◽  
Shou-Hang Bo ◽  
Zhaojun Xie ◽  
...  
Keyword(s):  
Surface Modification ◽  
Atomic Layer Deposition ◽  
Solid Electrolytes ◽  
High Stability ◽  
Atomic Layer ◽  
Interfacial Resistance ◽  
Interface Reactions ◽  
Layer Deposition ◽  
Metallic Lithium

We sputter amorphous SnO2 layer onto the surface of solid electrolytes via atomic layer deposition, which reduces interfacial resistance, prevents interface reactions with metallic lithium and provides high stability for long cycling.

Organic-inorganic hybrid solid electrolytes for solid-state lithium cells operating at room temperature

2016 ◽  
Vol 218 ◽  
pp. 271-277 ◽  
Author(s):  
Yun-Chae Jung ◽  
Myung-Soo Park ◽  
Chil-Hoon Doh ◽  
Dong-Won Kim
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Room Temperature ◽  
Inorganic Hybrid ◽  
Lithium Cells

Development of Solid Electrolytes for All-Solid-State Batteries

2019 ◽  
Vol 92 (11) ◽  
pp. 430-434
Author(s):  
Akitoshi HAYASHI ◽  
Atsushi SAKUDA ◽  
Masahiro TATSUMISAGO
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Solid State Batteries ◽  
All Solid State Batteries

How Certain Are the Reported Ionic Conductivities of Thiophosphate-Based Solid Electrolytes? an Interlaboratory Study

2020 ◽  
Author(s):  
Saneyuki Ohno ◽  
Tim Bernges ◽  
Johannes Buchheim ◽  
Marc Duchardt ◽  
Anna-Katharina Hatz ◽  
...  
Keyword(s):  
Standard Deviation ◽  
Ionic Conductivity ◽  
Relative Standard Deviation ◽  
Solid Electrolytes ◽  
Ionic Conductivities ◽  
Ionic Conductors ◽  
Energy Storage Devices ◽  
Activation Barriers ◽  
Storage Devices ◽  
Relative Standard

<p>Owing to highly conductive solid ionic conductors, all-solid-state batteries attract significant attention as promising next-generation energy storage devices. A lot of research is invested in the search and optimization of solid electrolytes with higher ionic conductivity. However, a systematic study of an <i>interlaboratory reproducibility</i> of measured ionic conductivities and activation energies is missing, making the comparison of absolute values in literature challenging. In this study, we perform an uncertainty evaluation via a Round Robin approach using different Li-argyrodites exhibiting orders of magnitude different ionic conductivities as reference materials. Identical samples are distributed to different research laboratories and the conductivities and activation barriers are measured by impedance spectroscopy. The results show large ranges of up to 4.5 mScm<sup>-1</sup> in the measured total ionic conductivity (1.3 – 5.8 mScm<sup>-1</sup> for the highest conducting sample, relative standard deviation 35 – 50% across all samples) and up to 128 meV for the activation barriers (198 – 326 meV, relative standard deviation 5 – 15%, across all samples), presenting the necessity of a more rigorous methodology including further collaborations within the community and multiplicate measurements.</p>

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