Catalytic olefin epoxidation over cobalt(ii)-containing mesoporous silica by molecular oxygen in dimethylformamide medium

2014 ◽  
Vol 4 (6) ◽  
pp. 1820-1828 ◽  
Author(s):  
Susmita Bhunia ◽  
Sreyashi Jana ◽  
Debraj Saha ◽  
Buddhadeb Dutta ◽  
Subratanath Koner
Keyword(s):  
Schiff Base ◽  
Mesoporous Silica ◽  
Molecular Oxygen ◽  
Atmospheric Pressure ◽  
Allyl Alcohol ◽  
Schiff Base Complex ◽  
Olefin Epoxidation ◽  
Base Complex ◽  
Mcm 41

A cobalt(ii) Schiff base complex has been anchored onto the surface of Si–MCM-41 to prepare a new catalyst. The catalyst is capable of catalyzing epoxidation reactions of olefinic compounds, including styrene and allyl alcohol, with molecular oxygen at atmospheric pressure in DMF medium.

scholarly journals A phosphine-free, atom-efficient cross-coupling reaction of triorganoindiums with acyl chlorides catalyzed by immobilization of palladium(0) in MCM-41

RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42570-42578 ◽  
Author(s):  
Jiankang Miao ◽  
Bin Huang ◽  
Haiyi Liu ◽  
Mingzhong Cai
Keyword(s):  
Schiff Base ◽  
Schiff Base Complex ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Free Atom ◽  
Acyl Chlorides ◽  
Base Complex ◽  
Cross Coupling Reaction ◽  
Mcm 41

The phosphine-free, atom-efficient cross-coupling of triorganoindiums with acyl chlorides has been achieved using a recyclable MCM-41-immobilized palladium(0)–Schiff base complex.

Synthesis and X-ray crystal structure of a Molybdenum(VI) Schiff base complex: Design of a new catalytic system for sustainable olefin epoxidation

2020 ◽  
Vol 511 ◽  
pp. 119775
Author(s):  
Hamed Mahmoudi ◽  
Mojtaba Bagherzadeh ◽  
Saeed Ataie ◽  
Reza Kia ◽  
Seyed Heydar Moravej ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Catalytic System ◽  
Schiff Base Complex ◽  
Olefin Epoxidation ◽  
Base Complex ◽  
X Ray ◽  
Complex Design
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