scholarly journals Carbene iridium complexes for efficient water oxidation: scope and mechanistic insights

2014 ◽  
Vol 7 (7) ◽  
pp. 2316-2328 ◽  
Author(s):  
James A. Woods ◽  
Ralte Lalrempuia ◽  
Ana Petronilho ◽  
Neal D. McDaniel ◽  
Helge Müller-Bunz ◽  
...  
Keyword(s):  
Factor Analysis ◽  
Dft Calculations ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Spectroscopic Studies ◽  
Iridium Complexes ◽  
Carbene Complexes ◽  
In Operando ◽  
Insight Into

Combined kinetic & in operando spectroscopic studies, factor analysis, and DFT calculations provide insight into the water oxidation reaction catalyzed by operationally homogeneous iridium mesoionic carbene complexes.

scholarly journals In operando studies on the electrochemical oxidation of water mediated by molecular catalysts

2017 ◽  
Vol 53 (77) ◽  
pp. 10622-10631 ◽  
Author(s):  
Dennis G. H. Hetterscheid
Keyword(s):  
Electrochemical Oxidation ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Feature Article ◽  
On Line ◽  
In Operando ◽  
Molecular Catalysts ◽  
Operando Studies

This feature article describes on-line studies regarding the water oxidation reaction mediated by molecular catalysts.

Impact Of Synthesis Route on the Water Oxidation Kinetics of Hematite Photoanodes

2020 ◽  
Author(s):  
Camilo A. Mesa ◽  
Ludmilla Steier ◽  
Benjamin Moss ◽  
Laia Francàs ◽  
James E. Thorne ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Reaction Kinetics ◽  
Water Oxidation ◽  
Oxidation Kinetics ◽  
Oxidation Reaction ◽  
Charge Accumulation ◽  
Optical Signals ◽  
Current Voltage ◽  
Voltage Performance ◽  
Kinetics Of

<p><i>Operando</i> spectroelectrochemical analysis is used to determine the water oxidation reaction kinetics for hematite photoanodes prepared using four different synthetic procedures. Whilst these photoanodes exhibit very different current / voltage performance, their underlying water oxidation kinetics are found to be almost invariant. Lower photoanode performance was found to correlate with the observation of optical signals indicative of charge accumulation in mid-gap oxygen vacancy states, indicating these states do not contribute directly to water oxidation.</p>

Insight into the formation of H-bonds propagating the monomeric zinc complexes of a tridentate reduced Schiff base to form an infinite chain

CrystEngComm ◽  
2021 ◽  
Author(s):  
Mainak Karmakar ◽  
Antonio Frontera ◽  
Shouvik Chattopadhyay
Keyword(s):  
Schiff Base ◽  
Solid State ◽  
Dft Calculations ◽  
Zinc Complexes ◽  
Infinite Chain ◽  
State Structure ◽  
Computational Tools ◽  
Solid State Structure ◽  
Reduced Schiff Base ◽  
Insight Into

The formation of an infinite 1D assembly is governed by the H-bonding interactions in the solid state structure of the two zinc complexes. It has been analyzed energetically using DFT calculations and several computational tools.

scholarly journals R Coronae Borealis Stars: Long-Term Photometric & Spectroscopic Studies

1998 ◽  
Vol 11 (1) ◽  
pp. 379-379
Author(s):  
P.L. Cottrell ◽  
L. Skuljan ◽  
P.M. Kilmartin ◽  
C. Gilmore ◽  
W.A. Lawson
Keyword(s):  
Radial Velocity ◽  
Spectroscopic Studies ◽  
Photometric Data ◽  
Decline Phase ◽  
Dust Clouds ◽  
Medium Resolution ◽  
Formation And Evolution ◽  
R Coronae Borealis Stars ◽  
Insight Into

For more than a decade we have been able to acquire and analyse a significant amount of photometric data of the highly variable R Coronae Borealis (RCB) stars. This has made been possible by a photometric service observing programme instigated at the Observatory. These photometric data have been combined with less extensive spectroscopic coverage, particularly of the decline phase of these stars. These have been supplemented by observations obtained at Mount Stromlo and Siding Spring Observatories for a radial velocity study. Significantly more spectroscopic observations are now being acquired with the development of a new medium resolution spectrograph at Mount John University Observatory. In this poster we will present recent photometric and spectroscopic results for a number of the RCB stars in our sample. This observational and analysis work can be used to provide further insight into the nature of these stars, their likely progeny and progenitors and the processes that are involved in the formation and evolution of the obscuring dust clouds which cause the decline phase.

Nano-sized Mn oxide: A true catalyst in the water-oxidation reaction

2015 ◽  
Vol 152 ◽  
pp. 127-132 ◽  
Author(s):  
Mohammad Mahdi Najafpour ◽  
Suleyman I. Allakhverdiev
Keyword(s):  
Water Oxidation ◽  
Oxidation Reaction ◽  
Mn Oxide
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