Lead sulfate nano- and microparticles in the acid plant blow-down generated at the sulfuric acid plant of the El Teniente mine, Chile

2014 ◽  
Vol 16 (12) ◽  
pp. 2734-2741 ◽  
Author(s):  
Giancarlo M. Barassi ◽  
Martin Klimsa ◽  
Thomas Borrmann ◽  
Mathew J. Cairns ◽  
Joachim Kinkel ◽  
...  

Suspended solids in weak acid waste from a copper smelter have been identified to be anglesite, lead sulphate, nano- and microparticles. The particles bypass filters and could pose a serious environmental threat.

2020 ◽  
Vol 20 (4) ◽  
Author(s):  
Bartosz Mikoda ◽  
Anna Potysz ◽  
Harry Kucha ◽  
Ewa Kmiecik

Abstract Spent catalysts being considered hazardous wastes exhibit a high metal content in mobile forms. In addition, growing demand for circular economy policy applications requires proper utilization of these wastes. This study aimed at the assessment of vanadium leaching from spent desulfurization catalyst derived from sulfuric acid plant dump located nearby a copper smelter. Chemical and phase composition of the catalyst has been characterized. The extraction has been performed using chemical (0.1-M and 1-M citric acid) and biological (biotic solution with Acidithiobacillus thiooxidans) methods, using different experimental parameters (pulp density, particle size, leaching time) to observe V leaching behavior and kinetics. The results revealed that both citric acid and bacteria carried out the extraction process well. The optimal parameters for acid leaching were < 0.2-mm particle size and 2% pulp density, which allowed to leach out 95% of V from spent catalyst within 48 h. The bacterially mediated extraction resulted in 93% V leached out within 21 days with 2% pulp density. The experiments showed that V present in the catalyst is susceptible to bioleaching and organic acid leaching with the latter being a quicker process.


Author(s):  
BA Chowdhury ◽  
MS Islam ◽  
F Begum ◽  
AM Parvez

Journal of Chemical Engineering Vol.ChE 23 1995-2005


2011 ◽  
Vol 474-476 ◽  
pp. 172-177 ◽  
Author(s):  
Jing Yong Liu ◽  
Xun An Ning

The soil samples in a profile were collected around the pyrite slag pile site near a sulfuric acid plant in Guangdong province and the contents of lead were investigated detail. At the same time, the mechanism of lead pollution was principium analyzed. The research found that the lead pollutants were mainly concentrated in soils surface layer about 0-10cm and shown characteristics of contents rapidly decreasing along the uprights. the main factors that affected the transference of lead from the slag to the soil were the filtering by acid rain and itself acidification of the slag. Iron oxide colloid and organic matter may have been responsible for the lead retention in soil.<b></b>


2019 ◽  
Vol 222 ◽  
pp. 369-380 ◽  
Author(s):  
Beatriz Gasparini Reis ◽  
Ana Lívia B. Araújo ◽  
Camila C. Vieira ◽  
Miriam Cristina Santos Amaral ◽  
Helen Conceição Ferraz

2010 ◽  
Vol 158 (2) ◽  
pp. 241-249 ◽  
Author(s):  
Anton A. Kiss ◽  
Costin S. Bildea ◽  
Johan Grievink

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