A porous polyethersulfone hollow fiber membrane in a gas humidification process

RSC Advances ◽  
2015 ◽  
Vol 5 (19) ◽  
pp. 14448-14457 ◽  
Author(s):  
Gh. Bakeri ◽  
S. Naeimifard ◽  
T. Matsuura ◽  
A. F. Ismail

Porous PES hollow fiber membrane was fabricated and characterized in terms of pore size, porosity and wettability and used in humidification process. The membrane showed high performance compared to the commercial and in-house made membranes.

Author(s):  
S. A. Mousavi ◽  
Z. Arab Aboosadi ◽  
A. Mansourizadeh ◽  
B. Honarvar

Abstract Wetting and fouling have significantly affected the application of membrane distillation (MD). In this work, a dip-coating method was used for improving surface hydrophobicity of the polyetherimide (PEI) hollow fiber membrane. An air gap membrane distillation (AGMD) process was applied for treatment of the methylene blue (MB) solution. The porous PEI membrane was fabricated by a dry-wet spinning process and the hydrophobic 2-(Perfluoroalkyl) ethanol (Zonyl® BA) was used as the coating material. From FESEM, the modified PEI-Zonyl membrane showed an open structure with large finger-like cavities. The modified membrane displayed a narrow pore size distribution with mean pore size of 0.028 μm. The outer surface contact angle of the PEI-Zonly membrane increased from 81.3° to 100.4° due to the formation of an ultra-thin coated layer. The pure water flux of the PEI-Zonyl membrane was slightly reduced compared to the pristine PEI membrane. The permeate flux of 6.5 kg/m2 h and MB rejection of 98% was found for the PEI-Zonyl membrane during 76 h of the AGMD operation. Adsorption of MB on the membrane surface was confirmed based on the Langmuir isotherm evaluation, AFM and FESM analysis. The modified PEI-Zonyl membrane can be a favorable alternative for AGMD of dyeing wastewaters.


2005 ◽  
Vol 821 (2) ◽  
pp. 153-158 ◽  
Author(s):  
K HAGIWARA ◽  
S YONEDU ◽  
K SAITO ◽  
T SHIRAISHI ◽  
T SUGO ◽  
...  

Membranes ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 843
Author(s):  
Hazirah Syahirah Zakria ◽  
Mohd Hafiz Dzarfan Othman ◽  
Siti Hamimah Sheikh Abdul Kadir ◽  
Roziana Kamaludin ◽  
Asim Jilani ◽  
...  

Existing toxic solvents in the manufacturing of polymeric membranes have been raising concerns due to the risks of exposure to health and the environment. Furthermore, the lower tensile strength of the membrane renders these membranes unable to endure greater pressure during water treatment. To sustain a healthier ecosystem, fabrication of polyvinylidene fluoride (PVDF) hollow fiber membrane using a less toxic solvent, triethyl phosphate (TEP), with a lower molecular weight polyethylene glycol (PEG 400) (0–3 wt.%) additive were experimentally demonstrated via a phase inversion-based spinning technique at various air gap (10, 20 and 30 cm). Membrane with 2 wt.% of PEG 400 exhibited the desired ultrafiltration asymmetric morphology, while 3 wt.% PEG 400 resulting microfiltration. The surface roughness, porosity, and water flux performance increased as the loading of PEG 400 increased. The mechanical properties and contact angle of the fabricated membrane were influenced by the air gap where 20 cm indicate 2.91 MPa and 84.72°, respectively, leading to a stronger tensile and hydrophilicity surface. Lower toxicity TEP as a solvent helped in increasing the tensile properties of the membrane as well as producing an eco-friendly membrane towards creating a sustainable environment. The comprehensive investigation in this study may present a novel composition for the robust structure of polymeric hollow fiber membrane that is suitable in membrane technology.


2018 ◽  
Vol 14 (3) ◽  
pp. 343-347 ◽  
Author(s):  
Sumarni Mansur ◽  
Mohd Hafiz Dzarfan Othman ◽  
Ahmad Fauzi Ismail ◽  
Muhammad Nidzhom Zainol Abidin ◽  
Noresah Said ◽  
...  

Asymmetric, porous ultrafiltration polysulfone (PSf) hollow fiber membranes were fabricated via the dry-wet phase inversion spinning technique specifically for haemodialysis membrane. The objective was to discover the suitable spinning condition for the fabrication of ultrafiltration hollow fiber membrane with desired sponge-like structure. During haemodialysis procedure, uremic toxins such as urea and creatinine range from size 10,000-55,000 Da needs to be excreted out from the blood. While, proteins such as albumin (66,000 Da) need to be retained. The physical structure or morphology of a fabricated membrane is a major concern in determining the efficiency of a dialysis membrane. Different type of membrane morphology will give a different result in term of its permeability and clearance efficiency. The phase inversion spinning technique is suitable in producing ultrafiltation (UF) membrane where the average pore size of the fabricated membrane is in the range of 0.001 – 0.1 µm. However, there is many factors need to be controlled and manipulated in the phase inversion technique. In this study, the effect of the PVP on membrane pore size and performances were analysed. The contact angle measurement was measured to determine the hydrophilicity of the fibers. The hydrophilic polymer is favorable to avoid fouling and increase its biocompatibility. Furthermore, the diameter of the hollow fibers was determined using a scanning electron microscope (SEM). The effects of different morphology of the hollow fibers on the performance of the membranes were evaluated by pure water flux and BSA rejection. Both techniques were tested using permeation flux system. Based on the results obtained, it is found that the finger-like macrovoids in PSf hollow fiber membranes were suppressed by adding 8% PVP (Mw of 360 kDa) into the spinning dope solution as the result of a drastic increase in dope viscosity. On top of that, fiber spun with 8% PVP show more porous structure which contribute to higher permeability of the membrane. The result of this study can benefit to the membrane field of research especially in membrane technology for haemodialysis application.


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