Enhanced production from an Air Gap Membrane Distillation Desalination system by varying the feed entry angle

The membrane distillation (MD) process is an evaporative metho driven by the partial pressure difference between two different temperature solutions, namely the hot feed and the coolant. The hot feed evaporates, and the vapour gets condensed to the cooler side. A hydrophobic membrane maintains the evaporating surface. Air Gap Membrane Distillation(AGMD) separates the hot feed from the coolant by a narrow air gap and a coolant plate. The condensate forms on the coolant plate, and the air gap works as an insulation for the heat loss through the membrane. The salient parameters like feed temperature, coolant temperature, and air gap thickness have already been identified through research in previous years. In this study, an innovative technique has been tested to minimize the polarization and increase the production from an AGMD lab-scale unit. The effect of the feed flow entry angle has been investigated. Also, the combined effect of inclined flow entry and a finned coolant surface has been studied. It has been found from the experiments that with a feed flow entry angle of 60°, the system shows an average of 10% to 14% boost in performance. When 60° inlet flow angle and finned coolant plate work in combination, an average of 69% to 78% increase of distillate flux was observed with the same energy input.

Surfaces with Adjustable Features—Effective and Durable Materials for Water Desalination

Materials based on PVDF with desirable and controllable features were successfully developed. The chemistry and roughness were adjusted to produce membranes with improved transport and separation properties. Membranes were activated using the novel piranha approach to generate OH-rich surfaces, and finally furnished with epoxy and long-alkyl moieties via stable covalent attachment. The comprehensive materials characterization provided a broad spectrum of data, including morphology, textural, thermal properties, and wettability features. The defined materials were tested in the air-gap membrane distillation process for desalination, and improvement compared with pristine PVDF was observed. An outstanding behavior was found for the PVDF sample equipped with long-alkyl chains. The generated membrane showed an enhancement in the transport of 58–62% compared to pristine. A relatively high contact angle of 148° was achieved with a 560 nm roughness, producing a highly hydrophobic material. On the other hand, it was possible to tone the hydrophobicity and significantly reduce adhesion work. All materials were highly stable during the long-lasting separation process and were characterized by excellent effectiveness in water desalination.

Experimental Study of a Heat Pump for Simultaneous Cooling and Desalination by Membrane Distillation

Heat pump systems can simultaneously produce cooling energy for space cooling in hotels, office and residential buildings and heat for desalination using membrane distillation (MD). The MD technique uses a heat input at a temperature compatible with the levels of heat pump condensers (<60 °C). A heat pump prototype coupled with an air-gap membrane distillation unit was constructed and tested. This paper presents the experimental study on a lab-scale prototype and details the two operating modes “continuous” and “controlled” simulating an air conditioning system and a food storage, respectively. The experimental results enable to analyze the performance of the prototype and the physical phenomena involved. Finally, the study shows that this system could be a promising solution to help supplying freshwater to people in hot regions of the world.

Modification of porous polyetherimide hollow fiber membrane by dip-coating of Zonyl® BA for membrane distillation of dyeing wastewater

Wetting and fouling have significantly affected the application of membrane distillation (MD). In this work, a dip-coating method was used for improving surface hydrophobicity of the polyetherimide (PEI) hollow fiber membrane. An air gap membrane distillation (AGMD) process was applied for treatment of the methylene blue (MB) solution. The porous PEI membrane was fabricated by a dry-wet spinning process and the hydrophobic 2-(Perfluoroalkyl) ethanol (Zonyl® BA) was used as the coating material. From FESEM, the modified PEI-Zonyl membrane showed an open structure with large finger-like cavities. The modified membrane displayed a narrow pore size distribution with mean pore size of 0.028 μm. The outer surface contact angle of the PEI-Zonly membrane increased from 81.3° to 100.4° due to the formation of an ultra-thin coated layer. The pure water flux of the PEI-Zonyl membrane was slightly reduced compared to the pristine PEI membrane. The permeate flux of 6.5 kg/m2 h and MB rejection of 98% was found for the PEI-Zonyl membrane during 76 h of the AGMD operation. Adsorption of MB on the membrane surface was confirmed based on the Langmuir isotherm evaluation, AFM and FESM analysis. The modified PEI-Zonyl membrane can be a favorable alternative for AGMD of dyeing wastewaters.