A π-electronic covalent organic framework catalyst: π-walls as catalytic beds for Diels–Alder reactions under ambient conditions

2015 ◽  
Vol 51 (50) ◽  
pp. 10096-10098 ◽  
Author(s):  
Yang Wu ◽  
Hong Xu ◽  
Xiong Chen ◽  
Jia Gao ◽  
Donglin Jiang

Covalent organic frameworks were developed as heterogeneous catalysts to explore their π-walls as catalytic beds that enabled Diels–Alder reactions under ambient conditions.

2021 ◽  
Author(s):  
Farah Benyettou ◽  
Nawel Kaddour ◽  
Thirumurugan Prakasam ◽  
Gobinda Das ◽  
Sudhir Kumar Sharma ◽  
...  

We report the successful use of a gastro-resistant covalent organic framework for in vivo oral delivery of insulin.


2019 ◽  
Vol 7 (45) ◽  
pp. 25802-25807 ◽  
Author(s):  
Priyanka Manchanda ◽  
Stefan Chisca ◽  
Lakshmeesha Upadhyaya ◽  
Valentina-Elena Musteata ◽  
Mark Carrington ◽  
...  

Thin layers of a covalent organic framework (COF) have been synthesized on a flexible polymeric support using a new diffusion-induction method under ambient conditions in reaction times as short as 3 hours.


2018 ◽  
Vol 6 (34) ◽  
pp. 16655-16663 ◽  
Author(s):  
Bidhan Chandra Patra ◽  
Sabuj Kanti Das ◽  
Arnab Ghosh ◽  
Anish Raj K ◽  
Parikshit Moitra ◽  
...  

Covalent organic frameworks (COFs) promise several benefits as materials in terms of gas adsorption, for use in optoelectronic devices, etc.


2020 ◽  
Vol 56 (5) ◽  
pp. 766-769 ◽  
Author(s):  
Ziqian Liu ◽  
Qing Su ◽  
Pengyao Ju ◽  
Xiaodong Li ◽  
Guanghua Li ◽  
...  

The highly hydrophilic COF exhibits superior photocatalytic activity and recyclability together with environmental benignity in photocatalytic oxidation of benzylamine in water under ambient conditions.


Nanoscale ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 1128-1137 ◽  
Author(s):  
Alicia Moya ◽  
Mercedes Hernando-Pérez ◽  
Marta Pérez-Illana ◽  
Carmen San Martín ◽  
Julio Gómez-Herrero ◽  
...  

Hybridization of imine-based covalent organic framework (COF-300) on oxidized MWCNT surface have been designed and succesfully developed for the first time in one-pot chemical synthesis.


2019 ◽  
Vol 7 (47) ◽  
pp. 27148-27155 ◽  
Author(s):  
Muhammad Faheem ◽  
Saba Aziz ◽  
Xiaofei Jing ◽  
Tingting Ma ◽  
Junyi Du ◽  
...  

The assembly of two electron-rich fluorescent monomers produces a new dual luminescent covalent organic framework (DL-COF), which exhibits nitro explosives detecting ability with high sensitivity (Ksv ∼ 106 M−1, Kq ∼ 1015 M−1 s−1) and high selectivity (at ppb level).


CrystEngComm ◽  
2017 ◽  
Vol 19 (33) ◽  
pp. 4927-4932 ◽  
Author(s):  
D. Cui ◽  
J. M. MacLeod ◽  
M. Ebrahimi ◽  
F. Rosei

Monolayer covalent organic frameworks selectively bind fullerenes and trichlorobenzene at different sites via different types of interactions.


RSC Advances ◽  
2015 ◽  
Vol 5 (35) ◽  
pp. 27290-27294 ◽  
Author(s):  
Peiyuan Wang ◽  
Qiong Wu ◽  
Lifeng Han ◽  
Shen Wang ◽  
Shaoming Fang ◽  
...  

A novel imine-linked covalent organic framework on graphene composite with excellent electrochemical properties was conveniently synthesized in one step.


2017 ◽  
Vol 5 (44) ◽  
pp. 22933-22938 ◽  
Author(s):  
Yongfeng Zhi ◽  
Ziping Li ◽  
Xiao Feng ◽  
Hong Xia ◽  
Yumin Zhang ◽  
...  

A robust two-dimensional covalent organic framework (COF-JLU5), which exhibits excellent heterogeneous photocatalytic performances for oxidative C–H functionalizations under visible-light irradiation using O2as a green oxygen source, is reported.


2020 ◽  
Vol 49 (8) ◽  
pp. 2291-2302 ◽  
Author(s):  
D. Rodríguez-San-Miguel ◽  
C. Montoro ◽  
F. Zamora

Covalent organic frameworks are crystalline porous materials with 2- or 3-dimensional structures designed modularly from their molecular precursors. Using bottom-up or top-down strategies, single- or few-layer materials can be obtained from them.


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