Donor–acceptor interaction-driven folding of linear naphthalene–glycol oligomers templated by a rigid bipyridinium rod

2015 ◽  
Vol 2 (12) ◽  
pp. 1578-1583 ◽  
Author(s):  
Tian-Guang Zhan ◽  
Ben-Ye Lu ◽  
Feng Lin ◽  
Tian-You Zhou ◽  
Xin Zhao ◽  
...  

The construction of folded and helical supramolecular structures through the self-assembly of a series of flexible linear oligomers induced by a rigid rod-like template has been demonstrated.

2016 ◽  
Vol 18 (35) ◽  
pp. 24219-24227 ◽  
Author(s):  
Doan Chau Yen Nguyen ◽  
Lars Smykalla ◽  
Thi Ngoc Ha Nguyen ◽  
Michael Mehring ◽  
Michael Hietschold

Hydrogen-bonded supramolecular structures of BTP at the undecanol–graphite interface were studied by STM in dependence on the deposition temperature.


RSC Advances ◽  
2016 ◽  
Vol 6 (75) ◽  
pp. 71638-71651 ◽  
Author(s):  
Ankita Saini ◽  
K. R. Justin Thomas

The self-assembly of small organic molecules into molecular stacks plays a vital role in the construction of stable supramolecular structures.


2018 ◽  
Vol 74 (8) ◽  
pp. 1151-1154
Author(s):  
Pushpendra Singh ◽  
Harkesh B. Singh ◽  
Ray J. Butcher

In the title compound, [HgCl2(C16H28N2Se)], the primary geometry around the Se and Hg atoms is distorted trigonal–pyramidal and distorted square-pyramidal, respectively. The distortion of the molecular geometry in the complex is caused by the steric demands of the ligands attached to the Se atom. The Hg atom is coordinated through two chloride anions, an N atom and an Se atom, making up an unusual HgNSeCl2 coordination sphere with an additional long Hg...N interaction. Intermolecular C—H...Cl interactions are the only identified intermolecular hydrogen-bonding interactions that seem to be responsible for the self assembly. These relatively weak C—H...Cl hydrogen bonds possess the required linearity and donor–acceptor distances. They act as molecular associative forces that result in a supramolecular assembly along the b-axis direction in the solid state of the title compound.


2016 ◽  
Vol 52 (73) ◽  
pp. 10938-10947 ◽  
Author(s):  
Tomasz Marszalek ◽  
Mengmeng Li ◽  
Wojciech Pisula

This review discusses the role of chemical design on the self-assembly of donor–acceptor polymers on surfaces. Three major structural factors are highlighted including molecular weight, side chain engineering and backbone curvature of the polymers.


2017 ◽  
Vol 53 (15) ◽  
pp. 2371-2374 ◽  
Author(s):  
Sougata Datta ◽  
Nilanjan Dey ◽  
Santanu Bhattacharya

We report the electrochemical analysis of a donor–acceptor type two-component hydrogelation by an electroactive co-assembly of pyranine and n-dodecyl methyl viologen.


Nanoscale ◽  
2017 ◽  
Vol 9 (45) ◽  
pp. 17975-17982 ◽  
Author(s):  
Shengsheng Yu ◽  
Yuntian Yang ◽  
Tie Chen ◽  
Jingzhe Xu ◽  
Long Yi Jin

Pyrene-based amphiphiles self-assemble into nanofibers, spherical micelles and multilayer nanotubes. The addition of TNF allowed polymerization of these objects through charge-transfer interactions to form various supramolecular nanoassemblies.


2019 ◽  
Vol 55 (43) ◽  
pp. 6070-6073
Author(s):  
Yeray Dorca ◽  
Cristina Naranjo ◽  
Patricia Delgado-Martínez ◽  
Rafael Gómez ◽  
Luis Sánchez

The geometry-dependent self-assembling features of two PAHs, 1 and 2, is reported. The more planar 1 forms H-type supramolecular polymers, in a highly cooperative fashion by combination of H-bonding and π-stacking, with rod-like morphology. However, the highly distorted 2 interacts only by means of H-bonding yielding lamellar supramolecular structures.


2006 ◽  
Vol 24 (9) ◽  
pp. 1200-1208 ◽  
Author(s):  
Dai-Jun Feng ◽  
Peng Wang ◽  
Xiao-Qiang Li ◽  
Zhan-Ting Li

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