A novel zinc based binary catalytic system for CO2utilization under mild conditions

2016 ◽  
Vol 3 (2) ◽  
pp. 156-164 ◽  
Author(s):  
Willi Desens ◽  
Christina Kohrt ◽  
Anke Spannenberg ◽  
Thomas Werner
Keyword(s):  
Catalytic System ◽  
Building Block ◽  
Solvent Free ◽  
Cyclic Carbonates ◽  
Mild Conditions ◽  
Solvent Free Conditions

A novel zinc based binary catalytic system for the synthesis of cyclic carbonates under mild and solvent-free conditions utilizing CO2as a C1 building block is reported.

DBU/benzyl bromide: an efficient catalytic system for the chemical fixation of CO2 into cyclic carbonates under metal- and solvent-free conditions

2016 ◽  
Vol 6 (11) ◽  
pp. 3872-3877 ◽  
Author(s):  
Lin Wang ◽  
Koichi Kodama ◽  
Takuji Hirose
Keyword(s):  
Catalytic System ◽  
Benzyl Bromide ◽  
Solvent Free ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Metal Free ◽  
Solvent Free Conditions ◽  
Wide Range

A simple, mild and inexpensive catalytic system, DBU and benzyl bromide, was developed for the cycloaddition of epoxides to ambient CO2 under metal-free and solvent-free conditions and a wide range of epoxides was converted to the corresponding cyclic carbonates with good to excellent yields (81–95%).

Rhodium-catalyzed synthesis of quinolines and imines under mild conditions

RSC Advances ◽  
2015 ◽  
Vol 5 (64) ◽  
pp. 51570-51575 ◽  
Author(s):  
Dilip Kumar T. Yadav ◽  
Bhalchandra M. Bhanage
Keyword(s):  
Aqueous Medium ◽  
Catalytic System ◽  
Solvent Free ◽  
Mild Conditions ◽  
Solvent Free Conditions

An efficient protocol for the synthesis of quinolines in aqueous medium using a Rh(ii)acetate/TPPTS recyclable catalytic system has been developed. Furthermore, imines were also synthesized from benzylamines in moderate to good yields under solvent free conditions.

scholarly journals Efficient Conversion of Epoxides into Carbonates with CO2 and a Single Organocatalyst: Laboratory and Kilogram-Scale Experiments

Synlett ◽  
2019 ◽  
Vol 31 (02) ◽  
pp. 183-188 ◽  
Author(s):  
Rabah Azzouz ◽  
Viviana Contreras Moreno ◽  
Clara Herasme-Grullon ◽  
Vincent Levacher ◽  
Lionel Estel ◽  
...  
Keyword(s):  
Solvent Free ◽  
Cyclic Carbonates ◽  
Mild Conditions ◽  
Efficient Conversion ◽  
Solvent Free Conditions ◽  
Related Compounds

Cheap and readily available 2-aminopyridine and related compounds can be used as organocatalysts for the conversion of epoxides into cyclic carbonates. This reaction gives high conversions under solvent-free conditions and is amenable to a kilogram-scale conversion under mild conditions.

scholarly journals Homocoupling of terminal alkynes catalyzed by CuCl under solvent-free conditions

2021 ◽  
pp. 174751982110325
Author(s):  
Yan Xiao ◽  
Jiyu Gao ◽  
Peng Chen ◽  
Guangliang Chen ◽  
Zicheng Li ◽  
...  
Keyword(s):  
Functional Group ◽  
Reaction Times ◽  
Environmentally Friendly ◽  
Solvent Free ◽  
Copper Salt ◽  
Terminal Alkynes ◽  
Mild Conditions ◽  
Solvent Free Conditions ◽  
Environmentally Friendly Process

A series of symmetrical 1,4-disubstituted buta-1,3-diynes is prepared with excellent yields (up to 95%) through homocoupling of terminal alkynes catalyzed by a copper salt under solvent-free conditions. This method provides an environmentally friendly process to prepare 1,3-diynes in short reaction times under mild conditions. Furthermore, the method is suitable for a wide substrate scope and has excellent functional group compatibility. The reaction can also be scaled up to gram level.

Efficient CO2 fixation into cyclic carbonates catalyzed by NNO-scorpionate zinc complexes

2019 ◽  
Vol 48 (28) ◽  
pp. 10733-10742 ◽  
Author(s):  
Sonia Sobrino ◽  
Marta Navarro ◽  
Juan Fernández-Baeza ◽  
Luis F. Sánchez-Barba ◽  
Andrés Garcés ◽  
...  
Keyword(s):  
Co2 Fixation ◽  
Functional Group ◽  
Zinc Complexes ◽  
Solvent Free ◽  
Cyclic Carbonates ◽  
Solvent Free Conditions

Chiral bifunctional and bicomponent NNO-scorpionate zinc-based catalysts have been developed for the fixation of CO2 into cyclic carbonates with broad substrate scope and functional group tolerance under mild and solvent-free conditions.

A multicomponent reaction on a ‘free’ KCC-1 catalyst at room temperature under solvent free conditions by visible light

RSC Advances ◽  
2016 ◽  
Vol 6 (59) ◽  
pp. 54236-54240 ◽  
Author(s):  
Seyed Mohsen Sadeghzadeh
Keyword(s):  
Visible Light ◽  
Multicomponent Reaction ◽  
Efficient Method ◽  
Room Temperature ◽  
Solvent Free ◽  
Green Protocol ◽  
Mild Conditions ◽  
Solvent Free Conditions

A green and efficient method for the synthesis of various triazolo[1,2-a]indazoletrione under mild conditions is reported, that making it a genuinely green protocol.

Sign in / Sign up

Export Citation Format

Share Document