Honeycomb porous films of pentablock copolymer on liquid substrates via breath figure method and their hydrophobic properties with static and dynamic behaviour

RSC Advances ◽  
2015 ◽  
Vol 5 (27) ◽  
pp. 21084-21089 ◽  
Author(s):  
Zhiguang Li ◽  
Xiaoyan Ma ◽  
Duyang Zang ◽  
Qing Hong ◽  
Xinghua Guan

The peeled film obtained on the isopropanol substrate through breath figure method exhibits the best hydrophobic properties, and the water droplet impact behavior shows an obvious rebound tendency and a weak maximum spreading diameter.

2017 ◽  
Vol 134 (47) ◽  
pp. 45476 ◽  
Author(s):  
Zhiguang Li ◽  
Zuoliang Zhang ◽  
Que Kong ◽  
Xuehong Ren

Author(s):  
Morteza Mohammadi ◽  
Mohammadreza Attarzadeh ◽  
Moussa Tembely ◽  
Ali Dolatabadi

Droplet impact on solid surfaces has been extensively reported in the literature, however the effect of accompanying air flow on the outcome of impacting droplet has yet to be addressed and analyzed which is similar to real scenario of impacting water droplet on aircraft’s leading edge at in-flight icing conditions. This study addresses the net effect of airflow (i.e. stagnation and the resultant shear flow) on the impacting water droplet with the same droplet impact velocity which is exposed to different airspeeds. In order to provide stagnation flow, a droplet accelerator was built which can generate different airspeeds up to 20 m/s. Droplet impact behavior accompanied with stagnation flow on a polished aluminum surface with a contact angle of 70° was investigated by high speed photography. 2.5 mm water droplet size with impact velocities of 2, 2.5 and 3 m/s which correspond to non-splashing regime of impacts are exposed to three different regimes of air speeds namely 0 (i.e. still air case), 10, and 20 m/s. It was observed that when droplet reaches to its maximum spreading diameter, some fingered shape at the end of spreading lamella (i.e. Rayleigh-Taylor instability) is appeared. When stagnation flow is present these fingered shape droplets are exposed to the generated shear flow close to the substrate (i.e. Homann flow approach) causes a droplet break up while complete non-splashing regime is observed in still air case. In spite of the fact that maximum spreading diameter is not largely affected by air flow compare to still air case, droplet height variation is significantly reduced by about 70 percent for strong stagnation flow (i.e. 20 m/s) which generates non-recoiling condition resulting in the thin film formation.


Materials ◽  
2018 ◽  
Vol 11 (4) ◽  
pp. 481 ◽  
Author(s):  
Hua Yuan ◽  
Bing Yu ◽  
Hailin Cong ◽  
Ming Chi ◽  
Yuanzhe Cheng ◽  
...  

2021 ◽  
Author(s):  
Pengcheng Cui ◽  
Silong Wu ◽  
Jun Xie ◽  
Jiaying Ma ◽  
Lingyun Ding ◽  
...  

Asymmetric multi-layered porous film was prepared by casting inverse emulsion following the breath figure method. The porous morphologies both on the surface and in the bulk of the fabricated film...


2014 ◽  
Vol 5 (11) ◽  
pp. 3666-3672 ◽  
Author(s):  
Liang-Wei Zhu ◽  
Wu Yang ◽  
Yang Ou ◽  
Ling-Shu Wan ◽  
Zhi-Kang Xu

Polymers with functional end groups are synthesized using a cyclic lactone ATRP initiator for honeycomb-patterned porous films by the breath figure method.


2018 ◽  
Vol 2018 ◽  
pp. 1-6 ◽  
Author(s):  
Yongjian Zhang ◽  
Zhiguang Li

The porous structure films of PS containing silica nanoparticles of different hydrophobicity were obtained from breath figure method. For the porous films, the pores at the peripheral region and the center region were compared. It was found that the pores at the peripheral region appeared more uniform in size and showed higher degree of ordering. In addition, the patterns of the porous film became more disordered with the enhancing concentration of nanoparticles, and the pore size of the pore was increased. With the increase of the content of SiOH, that is, decrease in particle hydrophobicity, the Si elements were aggregated at the surface of the film and the interior of the pores. A hierarchical porous structure had been obtained at appropriate humidity and particle concentration. Finally, a possible mechanism of the hierarchical structure was proposed.


2012 ◽  
Vol 012 (3) ◽  
pp. 291-298 ◽  
Author(s):  
Rui-lai Liu ◽  
Jing Han ◽  
Xiu-juan Chen ◽  
Sheng-hong Lei ◽  
Hai-qing Liu

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