The efficient adsorption removal of Cr(vi) by using Fe3O4 nanoparticles hybridized with carbonaceous materials

RSC Advances ◽  
2015 ◽  
Vol 5 (74) ◽  
pp. 60033-60040 ◽  
Author(s):  
Hongtao Gao ◽  
Shuang Lv ◽  
Jinbiao Dou ◽  
Miaomiao Kong ◽  
Dongmei Dai ◽  
...  

Carbonaceous materials, such as pinecone and graphene, have been hybridized with Fe3O4 to modify its surface properties and enhance its adsorption efficiency for Cr(vi) removal in aqueous solution.


2012 ◽  
Vol 518-523 ◽  
pp. 352-355
Author(s):  
Hui Liu ◽  
Hong Liang Li ◽  
Meng Xue Wang ◽  
Jing Jing Sang ◽  
Xiu Song Zhao

Methylene blue (MB) was used as model molecule to investigate the effects of surface properties and solvent pH values on the adsorption and desorption (or release) behaviors of mesoporous SBA-15 materials. It was found that the treatment of SBA-15 with a pH 7.8 aqueous solution can enhance the adsorption rate and capacity in comparison with the pristine SBA-15. The effect of pH values on MB releasing from the weak base treated SBA-15 and the pristine one have been studied and been compared in pH values range from 0.5 to 7.0. Both of them showed a maximum releasing rate at about pH 2 and all of the treated SBA-15 samples showed a higher releasing quantity than the pristine ones. The influence mechanisms of base treatment on the adsorption ability and that of pH values on the releasing properties of SBA-15 samples have been analyzed and been discussed based on the composition, the morphology, the surface area and pore size distribution and adsorption/desorption measurements.



2015 ◽  
Vol 3 (10) ◽  
pp. 5674-5682 ◽  
Author(s):  
Yan Liu ◽  
Chao Luo ◽  
Jian Sun ◽  
Haizhen Li ◽  
Zebin Sun ◽  
...  

Two nanostructured proton-containing δ-MnO2 (H-δ-MnO2) materials were synthesized through proton exchange for K-containing δ-MnO2 (K-δ-MnO2) nanosheets and nanoparticles prepared by the hydrothermal homogeneous precipitation method and solid-state reaction.





2013 ◽  
Vol 20 (8) ◽  
Author(s):  
Shan Yang ◽  
Zhiqing Zhang ◽  
Fang Wang ◽  
Lijuan Feng ◽  
Tao Wang


Author(s):  
Huifen Yang ◽  
Peng Fu ◽  
Ge Zhang ◽  
Qingping Zhang ◽  
Xuan Li


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Fanhua Wu ◽  
Yuyu Zhang ◽  
Tao Li ◽  
Yongfeng Liu ◽  
Yi Liu ◽  
...  

Purpose The purpose of this study was to prepare carboxylated attapulgite (APT-COOH) and then be used as one of the ligands to prepare metal organic framework (MOF) hybrid materials to reduce the cost of MOF materials and improve the dispersed condition of APT. And then the materials were used to enrich anionic dye Congo red from aqueous solution. Design/methodology/approach The MOF hybrid materials were designed by means of facile reflux method rather than hydrothermal method, characterized by Thermogravimetric Analysis (TGA), Fourier Transform Infrared (FTIR) Spectrometer and pore structure. The dispersed degree of APT-COOH in the MOF materials was validated according to adsorption efficiency for Congo red. Findings Due to introduction of APT-COOH, the microenvironment of the MOF materials changed, leading to different adsorption behaviors. Compared to the MOF material without APT-COOH, the adsorption capacities of the hybridized MOF materials with different amounts of APT-COOH introduced increased by 4.58% and 15.55%, respectively, as the initial concentration of Congo red solution of 300 mg/L. Meantime, hybridized MOF materials were suitable to remove Congo red with low concentration, while the MOF material without APT-COOH was appropriate to enrich Congo red with high concentration. Research limitations/implications The microstructure of MOF hybrid materials in detail is the further and future investigation. Practical implications This study will provide a method to reduce the cost of MOF materials and a theoretical support to treat anionic dyes from aqueous solution. Originality/value APT-COOH was prepared and used as one of the ligands to synthesize MOF material to improve the dispersed degree of APT-COOH and reduce the cost of the MOF materials. The adsorption efficiency was greatly enhanced with low concentration of Congo red solution, and the results indicated that hydrogen bonding, electrostatic interaction, and p-p conjugation were involved in the adsorption process. The prepared MOFs materials exhibited excellent adsorption efficiency, which made the present materials highly promising and potentially useful in practical application as adsorbents to enrich anionic dyes such as Congo red from aqueous solution.



2015 ◽  
Vol 43 (3) ◽  
pp. 277-281 ◽  
Author(s):  
M Rahman ◽  
S Gul ◽  
M Ajmal ◽  
A Iqbal ◽  
Akk Achakzai

Removal of cadmium from aqueous solution was studied by using Quetta pine (Pinus halepensis Mill.) leaves. Batch adsorption experiments were performed as a function of appropriate equilibrium time, pH, concentration of adsorbate and amount of adsorbent. The optimum pH required for maximum adsorption was found to be 7.0 and the maximum contact time for the equilibrium was 30 minutes at adsorbent dose of 10 g. The maximum adsorption efficiency of cadmium removal was 98.50%. The results were better fitted by Langmuir than Freundlich isotherm. The separation factor of equilibrium 0.12 and 0.67 showed that Quetta pine leaves are good adsorbent of cadmium from aqueous solution DOI: http://dx.doi.org/10.3329/bjb.v43i3.21598 Bangladesh J. Bot. 43(3): 277-281, 2014 (December)



1993 ◽  
Vol 41 (1) ◽  
pp. 6-11 ◽  
Author(s):  
Shoko YOKOYAMA ◽  
Junko OBATA ◽  
Tadao JUJIE ◽  
Masayuki NAKAGAKI




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