A model predictive controller of the blowing mode during basic oxygen furnance process

Today in Ukraine and the world, the problem of energy saving and reducing the cost of smelted steel is state of art. Metallurgical enterprises are developing in conditions of fierce competition, the main reason is that Ukrainian products are extremely energy-intensive due to the depreciation of fixed assets and outdated technological processes. The basic oxygen furnace process is a process of producing steel from liquid cast iron with the addition of steel scrap to the converter and blowing oxygen from above through a water-cooling lance. Nowadays, the production of steel by BOF process is the most popular in the world and is becoming increasingly common. The main disadvantage of the basic oxygen furnace is the need to provide the initial amount of heat (in the form of liquid cast iron) and as a consequence - restrictions on the processing of scrap metal. Reducing the cost of basic oxygen furnace steel is achieved by increasing the share of scrap metal by increasing the degree of afterburning of CO to CO2 in the cavity of the converter, by optimal control of the parameters of the blast mode using model-predictive control. The principle of model-predictive control is based on a mathematical model of the plant. This approach minimizes the functional that characterizes the quality of the process. The linear-quadratic functional was chosen. A forecasting model is proposed taking into account the constraint on changing the position of the lance and the pneumatic oxygen supply valve. It was found that the change in the rate of decarburization of the metal depends on the distance of the lance to the level of the quiet bath and affects the degree of afterburning of CO to CO2. The decarburization process is non-stationary, described by a first-order inertial model, the transfer coefficient and time constant of which depends on the melting period and the duration of the purge. The mathematical model of the blast mode of oxygen-converter melting has been improved, taking into account the influence of the blast intensity on the decarburization process of the bath, which allowed to increase the accuracy and quality of blast control in terms of changing oxygen flow during purging. The simulation results of the automatic control system show that the model-predictive regulator provides the required level of carbon dioxide in the converter gases when the flow rate of oxygen for purge changes.

Evaluation of the Volume Stability and Resource Benefit of Basic Oxygen Furnace Slag and Its Asphalt Mixture Based on Field Application

Applying basic oxygen furnace (BOF) slag as aggregate in asphalt mixture is continuously investigated due to the increasing shortage of natural aggregate in recent years. However, the negative effect of BOF’s expansion in water greatly limits its further application in pavement construction. To address this problem, this paper studied the volume stability of BOF, and its asphalt mixture relied on actual engineering. The asphalt mixtures contained BOF aggregate was designed by the Marshall method with three different gradation types (AC-16, AC-20, and ATB-25). Besides, both laboratory samples and the core samples from field drilling were investigated in volume expansion rate after curing in a water bath. The economic and resource benefits of BOF replacement of natural aggregates were also analyzed. The results showed that the free calcium oxide content of BOF slag is positively related to the particle sizes. Nevertheless, the expansion rates of both the BOF aggregate and its asphalt mixture were less than 1%, which meant the BOF aggregate applied to the asphalt mixture meets the practical engineering requirements. The maximum allowable free calcium oxide content for large-grain size of steel slag is the smallest; it is also recommended that the expansibility of large-grain steel slag should be the first concern in the application. The resource assessment indicated that the use of steel slag for the construction of a trial section of one kilometer of single lane can save 967 tons of natural aggregates. The economic evaluation showed that the use of steel slag instead of natural aggregates for surface course construction could reduce the investment by 16.87%. The experimental methods and conclusions mentioned in this article provide stable references to enhance the development of sustainable pavement by recycling metallurgical slag in highway construction.

Estimation of phosphorus distribution ratio at the end of blowing in BOF

In integrated steel plants, the removal of phosphorous normally takes place during the primary basic oxygen furnace (BOF) steelmaking process. Phosphorous is usually introduced to the integrated steelmaking process through blast furnace additions, such as iron ore, coke, sinter, and fluxes. Among the others parameters such as optimizing the charging system, oxygen supply system, oxygen lance parameters of the converter, the flux quality in combination with temperature process control can improve the BOF efficiency of Dephosphorization. Phosphorus partition ratio (LP) is usually used to evaluate the thermodynamic efficiency of the dephosphorization of slags with different compositions in steelmaking processes. However, this parameter is only useful in equilibrium conditions, and it is not accurate when used to evaluate slag efficiency in industrial processes. Because of this, the aim of this work was to study the phosphorus partition ratio estimated from the experimental results in real plant conditions of two different BOF steel plants and compare them with well-known published models. In the present study, data from two steel plants (further Plant A and Plant B) were evaluated applying Healy’s, Suito and Inoui’s, Zhang’s as well as Assis’s equations. The calculated values were compared against measured values.

Experimental Investigation on the Effect of Converter Slag Aggregate for Blended Mortar Based on CT Scanning

This study investigated the air aging converter (Basic Oxygen Furnace, BOF) slag aggregate mortar with pulverized fly ash (PFA) and ferronickel slag (FNS). The chemical composition and mineralogical constituents of BOF incorporated mortar were analyzed. Setting time, flowability, compressive strength, and length change were measured to evaluate the fundamental properties of BOF mortar. The X-ray CT analysis was employed to observe the effect of converter slag in the cement matrix visually. The results showed that the hydration of BOF generated a pore at the vicinity of the aggregate, which decreased the compressive strength and increased the length change of mortar. However, the PFA or FNS incorporation of PFA or FNS can decrease the alkalinity of pore solution and subsequently reduce the reactivity of BOF aggregate. Thus, the incorporation of PFA and FNS can be a way to eliminate the disadvantage of BOF, such as volume expansion.

Effect of Silicon Nutrition on Yield, Uptake and Agronomic Efficiency of Paddy in Acid Lateritic Soils of Odisha

A field experiment was conducted in the central farm, Regional Research and Technology Transfer Station, Coastal Zone OUAT, Bhubaneswar during kharif 2020 using cv-Lalat variety of Rice. The experiment was laid out in randomized block design (RBD) with ten treatments and three replications. In this experiment BOF (Basic Oxygen Furnace) slag was used as a source of silica for application to rice crop. 200, 300 and 400 kg SiO2/ha was applied in combination with 50% STD and 75% STD in order to assess the efficacy of Silica with reduction in fertilizer dose by 50% and 25%. It was shown in case of grain yield, straw yield, and harvest index, 100% STD (T4) registered maximum (36.9q/ha) grain yield which was 29.4% more than that of control. Of course, grain yield in case of T9i.e., 75% STD+300kg SiO2/ha was at par 36.2q/ha indicated efficacy of silica application by reducing fertilizer dose. Harvest index was not significantly affected by Si treatments. However, maximum HI (0.478) was observed in T9. Available N, P, K and S status in post-harvest soil was increased significantly due to application of silica along with fertilizer over control indicated better availability of nutrients which plays a vital role in increasing production and productivity of rice. The content and uptake of N, P, K and Si was significantly increased over control due to application of silica with fertilizer. Though 100% STD (T4) was found to be very effective as compared to other treatments but 75% STD+300kgSiO2/ha was also equally effective so far as yield, yield attributing characters, available nutrient status, N, P, K and Si content and uptake along with Relative Agronomic Efficiency (RAE), Agronomic Efficiency (AE), Apparent Recovery (%) AR and Production Efficiency (PE) are concerned.

Evaluation of Silicon Nutrition on Yield, Growth Attributes and Available Nutrient Status of Paddy in Coastal Zone of Odisha

A field experiment was conducted in the central farm, Regional Research and Technology Transfer Station, Coastal Zone OUAT, Bhubaneswar, Odisha, India during kharif 2020 using cv-Lalat variety of Rice. The experiment was laid out in randomized block design (RBD) with ten treatments and three replications. In this experiment BOF (Basic Oxygen Furnace) slag was used as a source of silica for application to rice crop. 200, 300 and 400 kg SiO2/ha was applied in combination with 50% STD (Soil Test Dose) and 75% STD to assess the efficacy of Silica with reduction in fertilizer dose by 50% and 25%. It was shown that increase in number of effective tillers (7.8) per plant and length of the panicle (25.8 cm), but no significant increase was marked in case of 1000 grain weight (gm.) over control. In case of grain yield, straw yield and harvest index, 100% STD (T4) registered maximum (36.9q/ha) grain yield which was 29.4% more than that of control. Of course, grain yield in case of T9 i.e., 75% STD+300 kg SiO2/ha was at par 36.2q/ha indicated efficacy of silica application by reducing fertilizer dose. Harvest index was not affected by Si treatments. However, maximum HI (0.478) was observed in T9. Available N, P, K and S status in post-harvest soil was increased due to application of silica along with fertilizer over control indicated better availability of nutrients which plays a vital role in increasing production and productivity of rice. The study revealed that the DTPA extractable Fe and Mn content decreased, and Cu and Zn content increased with increased application of silica. Though 100% STD (T4) was found to be very effective as compared to other treatments but 75% STD + 300kgSiO2/ha was also equally effective so far as yield, growth attributing characters, available nutrient status of paddy.

Optimal control of the blowing mode parameters during basic oxygen furnace steelmaking process

The oxygen converter is intended for production of steel from liquid cast iron and steel scrap at blowing by oxygen. Nowadays, Basic Oxygen Furnace process is the main method for steelmaking. The main disadvantage of the basic oxygen furnace is the limited ability to increase the part of scrap metal. The task of the proposed approach is to control of the blowing mode parameters to establish the optimal level of CO2 that will ensure a minimum specific cost of steel in the presence of restrictions and boundary conditions of basic oxygen furnace steelmaking process. A model predictive control taking into account the constraints on the input signals and the quadratic functional is proposed. The design of Model Predictive Control is based on mathematical model of an object. This approach minimizes the cost function that characterizes the quality of the process. The result of the automatic control system modeling shows that the Model Predictive Control approach provides retention of carbon dioxide level when oxygen consumption is changing. The obtained quadratic functional is optimized to find the optimal control of blowing parameters.

Investigation on Vanadium Chemistry in Basic-Oxygen-Furnace (BOF) Slags—A First Approach

Basic oxygen furnace (BOF) slag accounts for the majority of all residual materials produced during steelmaking and may typically contain certain transition metals. Vanadium, in particular, came into focus in recent years because of its potential environmental toxicity as well as its economic value. This study addresses the vanadium chemistry in BOF slags to better understand its recovery and save handling of the waste stream. The experimental results from the electron probe microanalysis (EPMA) study show that vanadium is preferably incorporated in calcium orthosilicate-like compounds (COS), with two variations occurring, a low vanadium COS (COS-Si) (approx. 1 wt.%), and a high vanadium COS (COS-V) (up to 18 wt.%). Additionally, vanadium is incorporated in dicalcium ferrite-like compounds (DFS) with an average amount of 3 wt.%. Using powder x-ray diffraction analysis (PXRD), EPMA, and virtual component models, stoichiometric formulas of the main vanadium-bearing phases were postulated. The stoichiometries give an estimate of the oxidation states of vanadium in the respective hosts. According to these results, trivalent vanadium is incorporated on the Fe-position in dicalcium ferrite solid solution (DFS), and V4+ and V5+ are incorporated on the Si-position of the COS.

An Economic Model to Assess Profitable Scenarios of EAF-Based Steelmaking Plants under Uncertain Conditions

The steelmaking processes are considered extremely energy-intensive and carbon-dependent processes. In 2018, it was estimated that the emissions from global steel production represented 7–9% of direct emissions generated by fossil fuels. It was estimated that a specific emissions value of 1.8 tCO2 per ton of steel was produced due to the carbon-dependent nature of the traditional blast furnace and basic oxygen furnace (BF-BOF) route. Therefore, it is necessary to find an alternative solution to the BF-BOF route for steel production to counteract this negative trend, resulting in being sustainable from an environmental and economic point of view. To this concern, the objective of this work consists of developing a total cost function to assess the economic convenience of steelmaking processes considering the variability of specific market conditions (i.e., iron ore price, scraps price, energy cost, etc.). To this purpose, a direct reduction (DR) process fueled with natural gas (NG) to feed an electric arc furnace (EAF) using recycled steel scrap was considered. The approach introduced is totally new; it enables practitioners, managers, and experts to conduct a preliminary economic assessment of innovative steelmaking solutions under market uncertainty. A numerical simulation has been conducted to evaluate the profitability of the investment considering the economic and environmental costs. It emerged that the investment is profitable in any case from an economic perspective. On the contrary, considering the environmental costs, the profitability of the investment is not guaranteed under certain circumstances.