Microstructure, growth process and enhanced photocatalytic activity of flower-like ZnO particles

RSC Advances ◽  
2016 ◽  
Vol 6 (9) ◽  
pp. 7403-7408 ◽  
Author(s):  
Yumin Su ◽  
Jibiao Li ◽  
Zhanzhou Luo ◽  
Bin Lu ◽  
Ping Li

A simple hydrothermal process was developed to synthesize flower-like ZnO microstructures that exhibited excellent photocatalytic activity.

2019 ◽  
Vol 7 (10) ◽  
pp. 5493-5503 ◽  
Author(s):  
Junli Chen ◽  
Hai Wang ◽  
Zhiqiang Zhang ◽  
Lifeng Han ◽  
Yonghui Zhang ◽  
...  

Ultrathin HNb3O8 nanosheets with oxygen vacancies were successfully synthesized by a simple hydrothermal process. HNb3O8 NSs showed excellent photocatalytic activity.


2018 ◽  
Vol 2018 ◽  
pp. 1-10 ◽  
Author(s):  
Xue-Yu Tao ◽  
Jie Ma ◽  
Rui-Lin Hou ◽  
Xiang-Zhu Song ◽  
Lin Guo ◽  
...  

Star-like nano-ZrO2 has been synthesized using Zr(NO3)4·5H2O as zirconium source by a hydrothermal process without any template and surfactant. The structure of the as-prepared ZrO2 powder was investigated by multiple advanced analytical methods. The results showed that CH3COO− and NO3− had great effects on the formation of star-like ZrO2 nanostructures. The as-prepared ZrO2 had a superior catalytic activity, and the reason for it was analyzed by UV-Vis diffuse reflectance spectroscopy. The effect of raw material ratios on the photocatalytic property of ZrO2 was studied. The synthesized ZrO2 showed a narrow bandgap (3.50–3.85 eV) and an excellent photocatalytic activity, and the degradation of RhB was up to nearly 100% in 30 min with this photocatalyst.


2020 ◽  
Vol 11 ◽  
pp. 407-416 ◽  
Author(s):  
Changqiang Yu ◽  
Min Wen ◽  
Zhen Tong ◽  
Shuhua Li ◽  
Yanhong Yin ◽  
...  

Photocatalysis is considered to be a green and promising technology for transforming organic contaminants into nontoxic products. In this work, a CuO/tourmaline composite with zero-dimensional/two-dimensional (0D/2D) CuO architecture was successfully obtained via a facile hydrothermal process, and its photocatalytic activity was evaluated by the degradation of methylene blue (MB). Surface element valence state and molecular vibration characterization revealed that CuO chemically interacted with tourmaline via Si–O–Cu bonds. The specific surface area of the CuO/tourmaline composite (23.60 m2 g−1) was larger than that of the pristine CuO sample (3.41 m2 g−1). The CuO/tourmaline composite exhibited excellent photocatalytic activity for the degradation of MB, which was ascribed to the increase in the quantity of the adsorption-photoreactive sites and the efficient utilization of the photoinduced charge carriers. This study provides a facile strategy for the construction of 0D/2D CuO structures and the design of tourmaline-based functional composite photocatalysts for the treatment of organic contaminants in water.


2010 ◽  
Vol 97-101 ◽  
pp. 19-22 ◽  
Author(s):  
Yu Shiang Wu ◽  
Wen Ku Chang ◽  
Min Jou

Zinc stannate Zn2SnO4 (ZTO) nanoparticles were synthesized via a hydrothermal process utilizing sodium carbonate (Na2CO3) as a weak basic mineralizer. The samples were hydrothermally treated at 150, 200, and 250oC for 48 h. The X-ray diffraction (XRD) patterns show that the highly-crystalline ZTO nanostructure could be formed in a well-dispersed manner for the 250°C sample at a particle size of less than 50 nm. As determined from transmission electron microscopy (TEM) results, ZTO nanoparticles are face-centered cubic single crystals agglomerated together. The Raman spectra results showed that the ZTO nanocrystals have a spinel structure. Furthermore, photocatalytic activity was tested with methylene blue (MB) by UV irradiation. The ZTO synthesized by the 2 M Na2CO3 mineralizer at 250oC demonstrated excellent photocatalytic activity. The ZTO treated three different ways had three distinct UV-Visible absorption curves, which directly influences their corresponding photocatalytic activity.


2017 ◽  
Vol 41 (8) ◽  
pp. 3134-3142 ◽  
Author(s):  
Zheng Qiao ◽  
Tingjiang Yan ◽  
Wenjuan Li ◽  
Baibiao Huang

In2S3/In(OH)3 heterostructures which were synthesized via an in situ anion exchange reaction and the hydrothermal process displayed excellent photocatalytic activity compared to pure components and the reported In2S3/In2O3.


RSC Advances ◽  
2014 ◽  
Vol 4 (53) ◽  
pp. 27642-27653 ◽  
Author(s):  
Subramanian Balachandran ◽  
Kuppulingam Thirumalai ◽  
Meenakshisundaram Swaminathan

Heterostructrued Pr6O11–ZnO prepared by a simple hydrothermal process, shows enhanced solar photocatalytic activity for azo dye degradation, hydrophobicity and photoconductivity.


2018 ◽  
Vol 42 (15) ◽  
pp. 12779-12786 ◽  
Author(s):  
Hui Fang ◽  
Yanxia Guo ◽  
Tong Wu ◽  
Yuping Liu

Highly photocatalytic urchin-like CuO/ZnO nanocomposites were synthesized using glutamine as a growth regulator by a hydrothermal process with subsequent calcination.


2013 ◽  
Vol 48 (9) ◽  
pp. 3032-3036 ◽  
Author(s):  
Siyao Guo ◽  
Song Han ◽  
Mao Haifeng ◽  
Chenghui Zeng ◽  
Yong Sun ◽  
...  

2017 ◽  
Vol 46 (44) ◽  
pp. 15582-15588 ◽  
Author(s):  
Amar Al-Keisy ◽  
Long Ren ◽  
Tian Zheng ◽  
Xun Xu ◽  
Michael Higgins ◽  
...  

Excellent photocatalytic activity is given rise to enhanced charge separation in ferroelectric heterogeneous Bi4(SiO4)3/Bi2SiO5 photocatalyst.


2013 ◽  
Vol 448-453 ◽  
pp. 169-173
Author(s):  
Chun Yan Yan ◽  
Wen Tao Yi

Pure and F, Fe-codoped TiO2 were prepared by sol-hydrothermal process, in which titanium (IV) n-butoxide, Fe (NO3)2·6H2O and NH4F were used as precursors. And the samples were characterized by X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy (DRS), scanning electron microscopy (SEM), and N2 adsorption-desorption method. The results showed that the F, Fe-codoped samples were principally single-phase anatase structures, and the particles possessed higher BET area than that of pure TiO2. The photocatalytic activity and reusability of the catalysts under UV light (365nm) was investigated with neutral red as the model compound. The results showed that F (2.0%), Fe (4.0%) codoped TiO2 had the highest photocatalytic activity among all as-prepared samples. The kinetic study showed that this photocatalytic process coincided with the Langmuir-Hinshelwood (L-H) pseudo first order reaction model.


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