scholarly journals Copper doped ceria porous nanostructures towards a highly efficient bifunctional catalyst for carbon monoxide and nitric oxide elimination

2015 ◽  
Vol 6 (4) ◽  
pp. 2495-2500 ◽  
Author(s):  
Shanlong Li ◽  
Nengli Wang ◽  
Yonghai Yue ◽  
Guangsheng Wang ◽  
Zhao Zu ◽  
...  

Cu2+ doped CeO2 porous nanomaterials were synthesized by calcining CeCu–MOF nanocrystals. They exhibited a superior bifunctional catalytic performance for CO oxidation and selective catalytic reduction of NO.

Clay Minerals ◽  
1997 ◽  
Vol 32 (4) ◽  
pp. 665-672 ◽  
Author(s):  
K. Bahranowski ◽  
J. Janas ◽  
T. Machej ◽  
E. M. Serwicka ◽  
L. A. Vartikian

AbstractA series of V-doped titania-pillared clay catalysts, characterized by ICP-AES chemical analysis, X-ray diffraction, BET surface area measurement, and ESR spectroscopy, have been tested in the selective catalytic reduction of NO by NH3. An ESR analysis shows that V dopant is anchored to the titania pillars. Vanadyl species with differing degrees of in-plane V-O π-covalent bonding are produced depending on the method of sample preparation. Polymeric V species appear as the V content is increased. Catalytic performance of these systems depends on the method of preparation and on the V content. The best catalyst, converting 90-100% NO in the temperature range 523-623 K, is obtained by exchange of pillared montmorillonite with vanadyl ions, at an extent of exchange below the level where significant amounts of polymeric V species appear. The co-pillared catalyst, containing vanadyl centres characterized by a higher degree of in-plane ncovalent bonding (according to ESR), is less selective than the exchanged samples.


2010 ◽  
Vol 96 (3-4) ◽  
pp. 408-420 ◽  
Author(s):  
Fudong Liu ◽  
Hong He ◽  
Changbin Zhang ◽  
Zhaochi Feng ◽  
Lirong Zheng ◽  
...  

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