Manganese oxides supported on hydrogenated TiO2 nanowire array catalysts for the electrochemical oxygen evolution reaction in water electrolysis

2015 ◽  
Vol 3 (42) ◽  
pp. 21308-21313 ◽  
Author(s):  
Nan Li ◽  
Wei-Yan Xia ◽  
Jing Wang ◽  
Zi-Li Liu ◽  
Qing-Yu Li ◽  
...  

Manganese oxide/hydrogenated TiO2 core–shell nanowires exhibited enhanced electrocatalytic activity toward the oxygen evolution reaction in water electrolysis.

2014 ◽  
Vol 146 ◽  
pp. 119-124 ◽  
Author(s):  
Zhuo-ying Li ◽  
Shu-ting Shi ◽  
Qi-sui Zhong ◽  
Chan-juan Zhang ◽  
Chang-wei Xu

Nanoscale ◽  
2018 ◽  
Vol 10 (35) ◽  
pp. 16911-16918 ◽  
Author(s):  
Zong Liu ◽  
Huaguang Yu ◽  
Baoxia Dong ◽  
Xu Yu ◽  
Ligang Feng

Thermal-driving core–shell structure formation in Fe–Ni alloy incorporated by S, N-doped carbon can greatly boost the catalytic performance for electrochemical oxygen evolution reaction.


2019 ◽  
Vol 55 (63) ◽  
pp. 9347-9350 ◽  
Author(s):  
Lei Zhong ◽  
Yufei Bao ◽  
Xu Yu ◽  
Ligang Feng

An Fe doped NiTe bulk crystal was demonstrated to exhibit an extremely active and stable performance for the electrochemical oxygen evolution reaction.


Author(s):  
Min Jiang ◽  
Wei Fan ◽  
Anquan Zhu ◽  
Pengfei Tan ◽  
Jianping Xie ◽  
...  

This work employs bacteria as precursors and induces a cost-effective biosorption strategy to obtain Fe2P@carbon nanoparticles decorated on N and P co-doped carbon (Fe2P@CNPs/NPC) materials.


Author(s):  
Tingting Li ◽  
Tianyun Jing ◽  
Dewei Rao ◽  
Xiaotian Jia ◽  
Yunpeng Zuo ◽  
...  

Multimetallic pyrite-type sulfides have been a promising electrocatalytic materials for electrochemical oxygen evolution reaction (OER), but still requires further improve due to the easily oxidization of surface atoms and the...


2020 ◽  
Author(s):  
Ioannis Spanos ◽  
Justus Masa ◽  
Aleksandar Zeradjanin ◽  
Robert Schlögl

AbstractThere is an ongoing debate on elucidating the actual role of Fe impurities in alkaline water electrolysis, acting either as reactivity mediators or as co-catalysts through synergistic interaction with the main catalyst material. This perspective summarizes the most prominent oxygen evolution reaction (OER) mechanisms mostly for Ni-based oxides as model transition metal catalysts and highlights the effect of Fe incorporation on the catalyst surface in the form of impurities originating from the electrolyte or co-precipitated in the catalyst lattice, in modulating the OER reaction kinetics, mechanism and stability. Graphic Abstract


2021 ◽  
Author(s):  
Xiaoping Ma ◽  
Lili Deng ◽  
Manting Lu ◽  
Yi He ◽  
Shuai Zou ◽  
...  

Abstract Although researches on non-noble metal electrocatalysts have been made some progress recently, their performance in proton exchange membrane water electrolyzer (PEMWE) is still incomparable to that of noble-metal-based catalysts. Therefore, it is a more practical way to improve the utilization of precious metals in electrocatalysts for oxygen evolution reaction (OER) in the acidic medium. Herein, nanostructured IrCo@IrCoOx core-shell electrocatalysts composed of IrCo alloy core and IrCoOx shell were synthesized through a simple colloidally synthesis and calcination method. As expected, the hybrid IrCo-200 NPs with petal-like morphology show the best OER activities in acidic electrolytes. They deliver lower overpotential and better electrocatalytic kinetics than pristine IrCo alloy and commercial Ir/C, reaching a low overpotential (j = 10 mA/cm2) of 259 mV (vs. RHE) and a Tafel slope of 59 mV dec−1. The IrCo-200 NPs displayed robust durability with life time of about 55 h in acidic solution under a large current density of 50 mA/cm2. The enhanced electrocatalytic activity may be associated with the unique metal/amorphous metal oxide core-shell heterostructure, allowing the improved charge transferability. Moreover, the *OH-rich amorphous shell functions as the active site for OER and prevents the further dissolution of the metallic core and thus ensures high stability.


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