Highly dispersed Pt nanoparticles supported on carbon nanotubes produced by atomic layer deposition for hydrogen generation from hydrolysis of ammonia borane

2017 ◽  
Vol 7 (2) ◽  
pp. 322-329 ◽  
Author(s):  
Jiankang Zhang ◽  
Chaoqiu Chen ◽  
Shuai Chen ◽  
Qingmin Hu ◽  
Zhe Gao ◽  
...  

Highly active Pt nanoparticles deposited on CNTs were synthesized by atomic layer deposition used for hydrogen generation from AB hydrolysis.

2016 ◽  
Vol 6 (7) ◽  
pp. 2112-2119 ◽  
Author(s):  
Jiankang Zhang ◽  
Chaoqiu Chen ◽  
Wenjun Yan ◽  
Feifei Duan ◽  
Bin Zhang ◽  
...  

Highly efficient Ni nanoparticles deposited on CNTs were synthesized by atomic layer deposition used for hydrogen generation from AB hydrolysis.


2019 ◽  
Vol 16 (2) ◽  
pp. 855-862 ◽  
Author(s):  
Yang-Chih Hsueh ◽  
Chia-Te Hu ◽  
Chih-Chieh Wang ◽  
Chueh Liu ◽  
Tsong-Pyng Perng

2022 ◽  
Vol 13 (1) ◽  
Author(s):  
Zhe Gao ◽  
Guofu Wang ◽  
Tingyu Lei ◽  
Zhengxing Lv ◽  
Mi Xiong ◽  
...  

AbstractThe contribution of the reverse spillover effect to hydrogen generation reactions is still controversial. Herein, the promotion functions for reverse spillover in the ammonia borane hydrolysis reaction are proven by constructing a spatially separated NiO/Al2O3/Pt bicomponent catalyst via atomic layer deposition and performing in situ quick X-ray absorption near-edge structure (XANES) characterization. For the NiO/Al2O3/Pt catalyst, NiO and Pt nanoparticles are attached to the outer and inner surfaces of Al2O3 nanotubes, respectively. In situ XANES results reveal that for ammonia borane hydrolysis, the H species generated at NiO sites spill across the support to the Pt sites reversely. The reverse spillover effects account for enhanced H2 generation rates for NiO/Al2O3/Pt. For the CoOx/Al2O3/Pt and NiO/TiO2/Pt catalysts, reverse spillover effects are also confirmed. We believe that an in-depth understanding of the reverse effects will be helpful to clarify the catalytic mechanisms and provide a guide for designing highly efficient catalysts for hydrogen generation reactions.


2019 ◽  
Vol 9 (10) ◽  
pp. 2664-2672 ◽  
Author(s):  
Quan Hu ◽  
Kun Cao ◽  
Yun Lang ◽  
Rong Chen ◽  
Shengqi Chu ◽  
...  

Highly dispersed platinum (Pt) nanoparticles are deposited on CeO2 nanorods via atomic layer deposition (ALD) to improve the catalytic activity towards the NO–CO reaction.


2015 ◽  
Vol 5 (8) ◽  
pp. 4218-4223 ◽  
Author(s):  
Jianwei Li ◽  
Bin Zhang ◽  
Yao Chen ◽  
Jiankang Zhang ◽  
Huimin Yang ◽  
...  

Pt sub-nanoparticles supported on carbon nanotubes prepared by atomic layer deposition exhibit unusual catalytic performance for styrene hydrogenation.


2021 ◽  
Author(s):  
Marwa Atwa ◽  
Xiaoan Li ◽  
Zhaoxuan Wang ◽  
Samuel Dull ◽  
Shicheng Xu ◽  
...  

A self-supported, binder-free and scalable nanoporous carbon scaffold serves as an excellent host for the efficient and uniform atomic layer deposition of Pt nanoparticles, showing exemplary performance as a cathode catalyst layer in a PEM fuel cell.


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