Influence of synthesis conditions on the morphologies of ReBO3 microstructures and white light emission of YBO3:Eu3+ phosphors prepared by an oleic acid-assisted hydrothermal method

RSC Advances ◽  
2016 ◽  
Vol 6 (73) ◽  
pp. 69442-69453 ◽  
Author(s):  
Baobao Liu ◽  
Xiuzhen Xiao ◽  
Jun Yu ◽  
Dongsen Mao ◽  
Guanzhong Lu

YBO3:5%Eu3+ phosphor prepared by the OA-assisted hydrothermal method displays the white color under excitation at 394 nm, and the light color of YBO3:Eu3+ can be varied with the Eu3+ dopant concentration or the excitation wavelength.

2018 ◽  
Vol 22 (09n10) ◽  
pp. 821-830 ◽  
Author(s):  
Zheng Wang ◽  
Jian-Hua Zhang ◽  
Cheng-Yi Zhu ◽  
Shao-Yun Yin ◽  
Mei Pan

Bipodal ligand 5,15-bis(4-carboxyphenyl) porphyrin (H[Formula: see text]DCPP) was designed and synthesized. By adjusting the molar ratio of H[Formula: see text]DCPP, ancillary ligand 4,4-bipyridine (bpy) and zinc acetate salts, three novel coordination assemblies, namely, zero-dimensional dimeric [Zn[Formula: see text](H[Formula: see text]DCPP)[Formula: see text] ·bpy] ·4H[Formula: see text]O ·4DMF (Zn-D), two-dimensional polymeric {[Zn[Formula: see text](DCPP) ·bpy[Formula: see text] ·H[Formula: see text]O ·DMF[Formula: see text]] ·solvent}[Formula: see text] (Zn-2D), and three-dimensional polymeric [Zn[Formula: see text](DCPP) ·bpy[Formula: see text]][Formula: see text] (Zn-3D) were assembled. Due to the delicate integration of multiple chromophores in the coordination space combining bpy, DCPP and MLCT emissions together, photoluminescence (PL) of the three porphyrin-zinc coordination assemblies differ from each other and color tone is tunable from blue to orange with changes of the excitation wavelength. In particular, white light emission (WLE) can be observed by the excitation of 270 to 290 nm, representing the first examples of single component WLE compounds based on porphyrin ligands. Furthermore, temperature-dependent luminescence results in a linear [Formula: see text]–[Formula: see text] relationship in Zn-2D and Zn-3D assemblies, applicable for long wavelength red-emitting thermometers.


2016 ◽  
Vol 45 (41) ◽  
pp. 16231-16239 ◽  
Author(s):  
Anna M. Kaczmarek ◽  
Dorine Ndagsi ◽  
Rik Van Deun

The emission color of Dy:YVO4 and Dy,Eu:YVO4 microstructures could be tuned towards white light and white light with a yellow undertone through varying the Ln3+ doping percentages as well as the excitation wavelengths.


2022 ◽  
Author(s):  
Jianyu Zhang ◽  
Parvej Alam ◽  
Siwei Zhang ◽  
Hanchen Shen ◽  
Lianrui Hu ◽  
...  

Clusteroluminogens (CLgens) refer to some non-conjugated molecules that show visible light due to the formation of aggregates and unique electronic properties with through-space interactions (TSI). Although mature and systematic theories of molecular photophysics have been developed to study conventional conjugated chromophores, it is still challenging to endow CLgens with designed photophysical properties by manipulating TSI. Herein, three CLgens with non-conjugated donor-acceptor structures and different halide substituents with secondary TSI are designed and synthesized. These molecules show multiple emissions and even white-light emission in the crystalline state and the intensity ratio of these multiple emission peaks is easily manipulated by changing the halide atom and excitation wavelength. Experimental and theoretical results successfully disclose the electronic nature of these multiple emissions: through-space conjugation for short-wavelength fluorescence, through-space charge transfer based on secondary TSI for long-wavelength fluorescence, and room-temperature phosphorescence. The introduction of secondary TSI to CLgens not only enriches their varieties of photophysical properties but also inspires the establishment of novel aggregate photophysics for clusteroluminescence.


2019 ◽  
Vol 55 (64) ◽  
pp. 9551-9554 ◽  
Author(s):  
Baihao Shao ◽  
Nell Stankewitz ◽  
Jacob A. Morris ◽  
Matthew D. Liptak ◽  
Ivan Aprahamian

Two hydrazones featuring a unique excitation wavelength-dependent dual fluorescence emission have been developed.


2016 ◽  
Vol 40 (12) ◽  
pp. 10440-10446 ◽  
Author(s):  
Liming Fan ◽  
Weiliu Fan ◽  
Bin Li ◽  
Xian Zhao ◽  
Xiutang Zhang

A series of trinuclear LnCPs with unprecedented (3,8)-connected 3D (4.52)2(42.512.66.75.83) architectures were synthesized. White light emission was realized by the Eu(iii)-doped Dy(iii) complexes.


2015 ◽  
Vol 44 (10) ◽  
pp. 4640-4647 ◽  
Author(s):  
Chang Feng ◽  
Jing-Wen Sun ◽  
Peng-Fei Yan ◽  
Yu-Xin Li ◽  
Tian-Qi Liu ◽  
...  

l-Di-2-thenoyltartaric acid mix-lanthanide coordination polymers with one-dimensional ladder-like chain structures present color-tunable and white-light emission upon varying the excitation wavelength.


2016 ◽  
Vol 4 (16) ◽  
pp. 3364-3374 ◽  
Author(s):  
Jiawei Wu ◽  
Huabin Zhang ◽  
Shaowu Du

This review highlights the luminescence tuning and white light emission of aromatic polycarboxylate-based mixed Ln-MOFs by changing the relative concentration of the constituent Ln3+ ions or the excitation wavelength.


2018 ◽  
Vol 20 (28) ◽  
pp. 19087-19097 ◽  
Author(s):  
S. Sekar ◽  
J. George Muller ◽  
J. Karthikeyan ◽  
P. Murugan ◽  
N. Lakshminarasimhan

Multifunctional roles of oleic acid as capping ligand, blue emitter and sensitizer are revealed in obtaining white light emission from Eu3+-based red phosphors.


Nanoscale ◽  
2018 ◽  
Vol 10 (9) ◽  
pp. 4189-4193 ◽  
Author(s):  
Yamei Ding ◽  
Qing Chang ◽  
Fei Xiu ◽  
Yingying Chen ◽  
Zhengdong Liu ◽  
...  

Zero- and two-dimensional hybrid carbon phosphors have been preparedviaa facile single-step hydrothermal method to realize high colorimetric purity white light-emission.


2013 ◽  
Vol 39 (8) ◽  
pp. 9809-9813 ◽  
Author(s):  
Jian Li ◽  
Zhi-yong Mao ◽  
Da-jian Wang ◽  
Ying-chun Zhu ◽  
Lin Gan ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document