Low-surface-area nitrogen doped carbon nanomaterials for advanced sodium ion batteries

2018 ◽  
Vol 54 (17) ◽  
pp. 2142-2145 ◽  
Author(s):  
Chaokun Liu ◽  
Jiangtao Hu ◽  
Luyi Yang ◽  
Wenguang Zhao ◽  
Hejie Li ◽  
...  

A low-surface-area nitrogen-doped carbon nanomaterial was prepared via a facile annealing method, which shows good Na-ion storage ability (334 mA g−1) and coulombic efficiency due to its mixed charge–discharge mechanism and unique structural features.

ChemSusChem ◽  
2018 ◽  
Vol 11 (8) ◽  
pp. 1334-1343 ◽  
Author(s):  
Yuxiang Chen ◽  
Jie Li ◽  
Yanqing Lai ◽  
Ming Xu ◽  
Junming Li ◽  
...  

Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2163 ◽  
Author(s):  
Yuliya V. Fedoseeva ◽  
Egor V. Lobiak ◽  
Elena V. Shlyakhova ◽  
Konstantin A. Kovalenko ◽  
Viktoriia R. Kuznetsova ◽  
...  

Highly porous nitrogen-doped carbon nanomaterials have distinct advantages in energy storage and conversion technologies. In the present work, hydrothermal treatments in water or ammonia solution were used for modification of mesoporous nitrogen-doped graphitic carbon, synthesized by deposition of acetonitrile vapors on the pyrolysis products of calcium tartrate. Morphology, composition, and textural characteristics of the original and activated materials were studied by transmission electron microscopy, X-ray photoelectron spectroscopy, near-edge X-ray absorption fine structure spectroscopy, infrared spectroscopy, and nitrogen gas adsorption method. Both treatments resulted in a slight increase in specific surface area and volume of micropores and small mesopores due to the etching of carbon surface. Compared to the solely aqueous medium, activation with ammonia led to stronger destruction of the graphitic shells, the formation of larger micropores (1.4 nm vs. 0.6 nm), a higher concentration of carbonyl groups, and the addition of nitrogen-containing groups. The tests of nitrogen-doped carbon materials as electrodes in 1M H2SO4 electrolyte and sodium-ion batteries showed improvement of electrochemical performance after hydrothermal treatments especially when ammonia was used. The activation method developed in this work is hopeful to open up a new route of designing porous nitrogen-doped carbon materials for electrochemical applications.


2018 ◽  
Vol 6 (19) ◽  
pp. 8868-8873 ◽  
Author(s):  
Zhan Xin Mao ◽  
Changyao Wang ◽  
Qianyuan Shan ◽  
Min Jie Wang ◽  
Yuxin Zhang ◽  
...  

An unusual low-surface-area N-doped carbon with nice performances of 400 F g−1 and 507 F cm−3, for gravimetric and volumetric capacitances respectively, has been extensively investigated to reveal the structural features.


2020 ◽  
Vol 46 (16) ◽  
pp. 25775-25782
Author(s):  
Zhipeng Xu ◽  
Ying Huang ◽  
Zheng Zhang ◽  
Ling Ding ◽  
Heng Gao ◽  
...  

2018 ◽  
Vol 6 (4) ◽  
pp. 1582-1589 ◽  
Author(s):  
Mingxiang Hu ◽  
Hongjiang Zhou ◽  
Xin Gan ◽  
Le Yang ◽  
Zheng-Hong Huang ◽  
...  

Nitrogen-doped graphite oxide can serve as anode material for Na-ion battery with high initial coulombic efficiency and excellent rate properties.


Nanomaterials ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 887 ◽  
Author(s):  
Amber S. Griffith ◽  
Thomas D. Zhang ◽  
Seth C. Burkert ◽  
Zelal Adiguzel ◽  
Ceyda Acilan ◽  
...  

Carbon nanomaterials, specifically, carbon nanotubes (CNTs) have many potential applications in biology and medicine. Currently, this material has not reached its full potential for application due to the potential toxicity to mammalian cells, and the incomplete understanding of how CNTs interface with cells. The chemical composition and structural features of CNTs have been shown to directly affect their biological compatibility. The incorporation of nitrogen dopants to the graphitic lattice of CNTs results in a unique cup shaped morphology and minimal cytotoxicity in comparison to its undoped counterpart. In this study, we investigate how uniquely shaped nitrogen-doped carbon nanocups (NCNCs) interface with HeLa cells, a cervical cancer epithelial cultured cell line, and RPE-1 cells, an immortalized cultured epithelial cell line. We determined that NCNCs do not elicit a cytotoxic response in cells, and that they are uptaken via endocytosis. We have conjugated fluorescently tagged antibodies to NCNCs and shown that the protein-conjugated material is also capable of entering cells. This primes NCNCs to be a good candidate for subsequent protein modifications and applications in biological systems.


2019 ◽  
Vol 7 (46) ◽  
pp. 26342-26350 ◽  
Author(s):  
Zhonghui Chen ◽  
Shuo Li ◽  
Yong Zhao ◽  
Mohamed F. Aly Aboud ◽  
Imran Shakir ◽  
...  

Exploring advanced electrode materials with simultaneous efficient lithium and sodium ion storage is highly desired but remains a considerable challenge mainly due to the significant difference of lithium and sodium ion sizes.


Sign in / Sign up

Export Citation Format

Share Document