Lead-free BNT-based composite materials: enhanced depolarization temperature and electromechanical behavior

2017 ◽  
Vol 46 (44) ◽  
pp. 15340-15353 ◽  
Author(s):  
Wangfeng Bai ◽  
Peng Zheng ◽  
Fei Wen ◽  
Jingji Zhang ◽  
Daqin Chen ◽  
...  

The development of (Bi0.5Na0.5)TiO3-based solid solutions with both high depolarization temperature Td and excellent piezoelectric and electromechanical properties for practical application is intractable because improved thermal stability is usually accompanied by a deterioration in piezoelectric and electromechanical performance.

2012 ◽  
Vol 18 (S5) ◽  
pp. 113-114
Author(s):  
Muhammad Asif Rafiq ◽  
Maria Elisabete Costa ◽  
Paula Maria Vilarinho ◽  
Ian M Reaney

Piezoelectric materials find important applications in micro- and nano-electromechanical systems (MEMS/NEMS). Pb(Zrx,Ti1-x)O3 (PZT) is currently the most widely used composition for such applications but due to environmental concerns over the toxicity of lead, lead free alternative materials are required. K0.5Na0.5NbO3 (KNN) is considered as a potential lead free piezoelectric but the current generation of monolithic ceramics has inferior electromechanical properties as compared to PZT. Consequently, there is great interest in improving the piezoelectric properties of KNN ceramics and various methods such as doping, hot-pressing and texturing are currently being studied. KNN single crystals like lead based single crystals have shown better electromechanical properties as compared to their ceramic counterparts. In addition, the behavior of a ferroelectric is largely dependent on its local domain response to an applied electrical or mechanical loading. Therefore, to understand better the material’s macroscopic properties, it is essential to access local ferroelectric domains behavior which collectively determines the electromechanical performance.


Author(s):  
Lu Wang ◽  
Shengdong Sun ◽  
Huajie Luo ◽  
Yang Ren ◽  
Hui Liu ◽  
...  

The realization of high piezoelectric performance and excellent temperature stability simultaneously in lead-free ceramics is the key for replacing Pb-containing perovskites in industry. In this study, large piezoelectric performance (d33...


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Tianhao Wu ◽  
Zhenzhen Qin ◽  
Yanbo Wang ◽  
Yongzhen Wu ◽  
Wei Chen ◽  
...  

AbstractPerovskite solar cells (PSCs) emerging as a promising photovoltaic technology with high efficiency and low manufacturing cost have attracted the attention from all over the world. Both the efficiency and stability of PSCs have increased steadily in recent years, and the research on reducing lead leakage and developing eco-friendly lead-free perovskites pushes forward the commercialization of PSCs step by step. This review summarizes the main progress of PSCs in 2020 and 2021 from the aspects of efficiency, stability, perovskite-based tandem devices, and lead-free PSCs. Moreover, a brief discussion on the development of PSC modules and its challenges toward practical application is provided.


RSC Advances ◽  
2021 ◽  
Vol 11 (42) ◽  
pp. 26432-26443
Author(s):  
Chol-Hyok Ri ◽  
Yun-Sim Kim ◽  
Un-Gi Jong ◽  
Yun-Hyok Kye ◽  
Se-Hun Ryang ◽  
...  

We propose lead-free potassium iodide perovskite solid solutions KBI3 with B-site mixing between Ge/Sn and Mg as potential candidates for photocatalysts based on systematic first-principles calculations.


2021 ◽  
Author(s):  
Johannes Essmeister ◽  
M. Josef Taublaender ◽  
Thomas Koch ◽  
D. Alonso Cerrón-Infantes ◽  
Miriam M. Unterlass ◽  
...  

A novel class of fully organic composite materials with well-balanced mechanical properties and improved thermal stability was developed by incorporating highly crystalline, hydrothermally synthesized polyimide microparticles into an epoxy matrix.


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