Divergent syntheses of iodinated isobenzofuranones and isochromenones by iodolactonization of 2-alkynylbenzoic acids in ionic liquids

2017 ◽  
Vol 15 (22) ◽  
pp. 4831-4841 ◽  
Author(s):  
Raffaella Mancuso ◽  
Christian C. Pomelli ◽  
Francesco Malafronte ◽  
Asif Maner ◽  
Nadia Marino ◽  
...  

2-Alkynylbenzoic acids can be divergently iodocyclized to either isobenzofuranones or isochromenones by changing the nature of the ionic liquid medium.

2019 ◽  
Vol 6 (11) ◽  
pp. 1895-1899 ◽  
Author(s):  
Sangepu Bhavanarushi ◽  
Yin Xu ◽  
Imran Khan ◽  
Zhibin Luo ◽  
Bin Liu ◽  
...  

Transition-metal-free borylation of unactivated propargylic alcohols in basic ionic liquids allowed the construction of various highly functionalized vinylboronates.


2013 ◽  
Vol 58 (4) ◽  
pp. 435-439
Author(s):  
V. I. Chistov ◽  
E. V. Esipova ◽  
I. S. Filimonov ◽  
E. A. Chendakova ◽  
A. G. Vendilo

2012 ◽  
Vol 610-613 ◽  
pp. 215-219
Author(s):  
Yun Xiao He ◽  
Xiao Ming Chen

The stability factors for Cr6+ and Cr3+ in microbiological media, including temperature, preservation conditions and medium components were studied in this research project, through potassium permanganate oxidation and DPC (Diphenylcarbazide) spectrophotometry. It shows that the protein component mainly influences Cr6+ content changes at pre- and post- heat sterilization to the chromium ionic liquid medium, other than being impacted basically by inorganic salt ions. It also indicates that the method can be introduced into experiment researches for microbe dechromisation i.e. Chromium ion aqueous solution and fluid medium are sterilized separately, and then are made into the chrome ions liquid as per a certain concentration. The concentration of hexavalent chromium ions is affected by preservation time and temperature also. For this reason, chromium ionic liquid medium is kept at low temperature, and as quickly as possible for the test.


2017 ◽  
Vol 46 (34) ◽  
pp. 11355-11362 ◽  
Author(s):  
Seraj Ahmad Ansari ◽  
Prasanta Kumar Mohapatra ◽  
Andrea Leoncini ◽  
Jurriaan Huskens ◽  
Willem Verboom

Three benzene-centred tripodal diglycolamide (Bz-T-DGA) ligands were evaluated for actinide ion extraction/complexation in an ionic liquid medium.


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