Versatile preparation of surface-skinless particles of epoxy resin-based monoliths using a well-defined diblock copolymer surfactant

2018 ◽  
Vol 9 (4) ◽  
pp. 414-419 ◽  
Author(s):  
Keita Sakakibara ◽  
Kyoko Konishi ◽  
Norio Ishizuka ◽  
Atsushi Goto ◽  
Yoshinobu Tsujii

This is the first report on a versatile and facile preparation method for well-defined and surface-skinless epoxy resin-based monolithic particles by polymerization-induced phase separation in an oil-in-oil emulsion system in the presence of a designed block copolymer.

Polymer ◽  
2004 ◽  
Vol 45 (4) ◽  
pp. 1253-1259 ◽  
Author(s):  
Minghai Wang ◽  
Yingfeng Yu ◽  
Xianguo Wu ◽  
Shanjun Li

2013 ◽  
Vol 705 ◽  
pp. 115-119
Author(s):  
Bao Yong Tian ◽  
Er Jun Tang ◽  
Miao Yuan ◽  
Rui Xia Hao ◽  
Cun Man Li ◽  
...  

The well-defined block copolymer PMMA-b-PS was prepared by two-step ATRP in emulsion system. GPC results indicate that Mn increased linearly with conversion and polydispersity remained relatively narrow. It presents the characteristics of living polymerization in emulsion system. FT-IR demonstrated that block copolymer PMMA-b-PS could be successfully synthesized by ATRP with macroinitiator PMMA-Cl in emulsion system. The morphological characteristic of the self-assembly depends on the block copolymer concentration and transforms between spheres and rodlike micelles. The property indicates a perfect potential application in drug delivery materials.


2010 ◽  
Vol 31 (18) ◽  
pp. 1635-1640 ◽  
Author(s):  
Stanislav Dubinsky ◽  
Alla Petukhova ◽  
Ilya Gourevich ◽  
Eugenia Kumacheva

1997 ◽  
Vol 22 (2) ◽  
pp. 145-156 ◽  
Author(s):  
C. SERBUTOVIEZ ◽  
J. G. KLOOSTERBOER ◽  
H. M. J. BOOTS ◽  
F. A. M. A. PAULISSEN ◽  
F. J. TOUWSLAGER

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