scholarly journals Pyridinium 5-aminothiazoles: specific photophysical properties and vapochromism in halogenated solvents

RSC Advances ◽  
2017 ◽  
Vol 7 (29) ◽  
pp. 18132-18135 ◽  
Author(s):  
Kirara Yamaguchi ◽  
Toshiaki Murai ◽  
Yuki Tsuchiya ◽  
Yohei Miwa ◽  
Shoichi Kutsumizu ◽  
...  
Keyword(s):  
Fluorescence Spectra ◽  
Photophysical Properties ◽  
Absorption And Fluorescence Spectra ◽  
Halogenated Solvents

Pyridinium-5-aminothiazoles exhibited bathochromically shifted absorption and fluorescence spectra, solvatochromism, and a reversible vapochromism specific to halogenated solvents.

Synthesis, Characterization and Photophysical Properties of Rhenium(I) Complexes Containing 4,5-Diazafluorene Ligan

2011 ◽  
Vol 239-242 ◽  
pp. 2612-2615
Author(s):  
Jie Xiu Wang ◽  
Feng Zhao
Keyword(s):  
Charge Transfer ◽  
Fluorescence Spectra ◽  
Photophysical Properties ◽  
Absorption And Fluorescence Spectra ◽  
Rhenium Complexes ◽  
H Nmr ◽  
Ligand Charge Transfer

Two related tricarbonyl rhenium complexes with the formula of [Re(CO)3(L)Cl], where L=4,5-diazafluoren-9-one (Dafo-Re) and 9-(phenylamino)-4,5-diazafluoren (PADF-Re) were successfully synthesized with the aim to explore the effect of the geometry of Dafo on Rhenium(I) coordination, and characterized by1H NMR. Photophysical behaviors are investigated by UV–vis absorption and Fluorescence spectra. The two complexes Dafo-Re and PADF-Re show metal-to-ligand charge transfer absorptions at ca.391nm, ca.394 nm and emissions at ca.492nm, ca.470nm, respectively.

Photophysical properties and photodynamic anti-tumor activity of corrole-coumarin dyads

2018 ◽  
Vol 22 (09n10) ◽  
pp. 886-898 ◽  
Author(s):  
Fan Cheng ◽  
Hua-Hua Wang ◽  
Atif Ali ◽  
Jaipal Kandhadi ◽  
Hui Wang ◽  
...  
Keyword(s):  
Fluorescence Spectra ◽  
Photophysical Properties ◽  
Fluorescence Emission ◽  
S Phase ◽  
Absorption And Fluorescence Spectra ◽  
Siha Cells ◽  
Phase Arrest ◽  
Intracellular Ros ◽  
Anti Tumor Activity ◽  
Gallium Complex

A new non-conjugated corrole-coumarin dyad and its gallium complex has been synthesized. Photophysical properties of the dyads were tested in two solvents, exhibiting strong solvent effect on the absorption and fluorescence spectra. Absorption spectra of the dyads are a linear combination of the spectra of their corresponding monomers, demonstrating a negligible electronic communication between coumarin and corrole moiety. However, fluorescence emission of coumarin entity in all dyads were quenched significantly as compared to pristine coumarin; this was attributed to intramolecular energy transfer from coumarin to the corrole. Photodynamic anti-tumor tests revealed that gallium corrole-coumarin dyads (2-Ga) exhibited good PDT activity towards SiHa cells. After PDT treatment, 2-Ga could induce apoptosis in SiHa cells, which was associated to cell S phase arrest, collapse of the mitochondrial membrane potential and increase of the intracellular ROS level.

A phthalocyanine-based fluorescent sensor for Zn2+ ion

2013 ◽  
Vol 17 (01n02) ◽  
pp. 99-103 ◽  
Author(s):  
Hui He ◽  
Jian-Yong Liu ◽  
Dennis K.P. Ng
Keyword(s):  
Metal Ions ◽  
Spectral Properties ◽  
Fluorescence Spectra ◽  
Near Infrared ◽  
Fluorescent Sensor ◽  
High Sensitivity ◽  
Absorption And Fluorescence Spectra

This paper describes the preparation and spectral properties of a near-infrared fluorophore in which two bis(2-picolyl)amino moieties are axially linked to a silicon(IV) phthalocyanine core. The effects of various metal ions on its absorption and fluorescence spectra have been examined. The results indicate that this compound shows a high sensitivity and moderate selectivity toward Zn2+ ion.

Influence of Si-Al-Ge-Sb Matricies on Tm3+ Excitation Levels

2008 ◽  
Vol 587-588 ◽  
pp. 293-297
Author(s):  
M. Pospíšilová ◽  
P. Adámek ◽  
P. Peterka ◽  
V. Kubeček ◽  
I. Kašík ◽  
...  
Keyword(s):  
Genetic Algorithm ◽  
Chemical Vapor Deposition ◽  
Vapor Deposition ◽  
Fluorescence Spectra ◽  
Chemical Vapor ◽  
Oscillator Strengths ◽  
Absorption And Fluorescence Spectra ◽  
Measured Absorption ◽  
Optical Fiber Drawing ◽  
Solution Doping

Absorption and fluorescence spectra in the range from 350 to 1750 nm of several Tm3+- doped optical performs (rods) for optical fiber drawing were measured. Silica-based matrices of Al2O3-GeO2-P2O5-Sb2O3-SiO2 composition doped with several thousands ppm of Tm3+ were characterized. The preforms were fabricated by the Modified Chemical Vapor Deposition and by the solution doping methods. A new method, Genetic Algorithm SPEctra Decomposition was adopted for processing of the measured absorption spectra. This decomposition made it possible to calculate the oscillator strengths of Tm3+ absorption levels. Fluorescence bands of Tm3+ at 800 nm or 1640 nm were found in fluorescence spectra measured on the preform samples when excited at 1064 nm only.

scholarly journals Indenopyrans – synthesis and photoluminescence properties

2016 ◽  
Vol 12 ◽  
pp. 825-834 ◽  
Author(s):  
Andreea Petronela Diac ◽  
Ana-Maria Ţepeş ◽  
Albert Soran ◽  
Ion Grosu ◽  
Anamaria Terec ◽  
...  
Keyword(s):  
Solid State ◽  
Emission Band ◽  
Fluorescence Spectra ◽  
Photophysical Properties ◽  
Quantum Yields ◽  
Band Broadening ◽  
Photoluminescence Properties ◽  
Fluorescence Quantum Yields ◽  
Blue Emitters ◽  
Solid State Fluorescence

New indeno[1,2-c]pyran-3-ones bearing different substituents at the pyran moiety were synthesized and their photophysical properties were investigated. In solution all compounds were found to be blue emitters and the trans isomers exhibited significantly higher fluorescence quantum yields (relative to 9,10-diphenylanthracene) as compared to the corresponding cis isomers. The solid-state fluorescence spectra revealed an important red shift of λmax due to intermolecular interactions in the lattice, along with an emission-band broadening, as compared to the solution fluorescence spectra.

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