Evaluation of parameters of intramolecular interaction from absorption and fluorescence spectra of substituted arylpolyene with poor resolved vibrational structure

2005 ◽  
Vol 111 (1-2) ◽  
pp. 37-45 ◽  
Author(s):  
N.L. Naumova ◽  
I.A. Vasil’eva ◽  
A.V. Naumov ◽  
I.S. Osad’ko
Keyword(s):  
Fluorescence Spectra ◽  
Intramolecular Interaction ◽  
Vibrational Structure ◽  
Absorption And Fluorescence Spectra ◽  
Evaluation Of Parameters

A Highly Resolved Yibronic Spectra of Dioxido-p-terphenyl and Trioxido-p-quaterphenyl in n-Hexanc at 77 K

1982 ◽  
Vol 37 (1) ◽  
pp. 91-94
Author(s):  
A. Kawski ◽  
M. Ligȩza
Keyword(s):  
Raman Spectra ◽  
Ground State ◽  
Fluorescence Spectra ◽  
Vibrational Structure ◽  
Ir And Raman Spectra ◽  
Absorption And Fluorescence Spectra ◽  
Excited Singlet ◽  
Ir And Raman ◽  
Good Agreement

Abstract Highly resolved vibronic absorption and fluorescence spectra of dioxido-p-terphenyl and the fluorescence spec-trum of trioxido-p-quaterphenyl in n-hexane at 77 K were obtained. The analysis of the vibrational structure in the excited singlet Si and in the ground So state gives funda-mental frequencies in the ground state in good agreement with those from infrared (IR) and Raman spectra.

Absorption and Fluorescence Spectra of some 1,3,4-Oxadiazole Derivatives in n-Paraffins at 77 K

1978 ◽  
Vol 33 (6) ◽  
pp. 731-735 ◽  
Author(s):  
P. Bałuk ◽  
A. Kawski
Keyword(s):  
Infrared Spectra ◽  
Ground State ◽  
Fluorescence Spectra ◽  
Singlet State ◽  
Vibrational Structure ◽  
Excited Singlet State ◽  
Absorption And Fluorescence Spectra ◽  
Excited Singlet ◽  
Oxadiazole Derivatives

Abstract The quasilinear absorption and fluorescence spectra of 2- (1-naphthyl) -5-phenyl 1,3,4 oxadiazole, 2-(2-naphthyl)-5- phenyl 1,3,4 oxadiazole, 2-(1-naphthyl) -5-(4-biphenylyl) - 1,3,4 oxadiazole and 2-(2-naphthyl)-5-(4-biphenylyl)-1,3,4 oxadiazole have been studied in n-hexane, decane and nonane at 77 K. An analysis of the vibrational structure in the first electronic excited singlet state (S1) and in the ground state (S0) is given. Internal oscillations in the investigated molecules found from the quasilinear spectra are in agreement with those found in the infrared spectra.

A phthalocyanine-based fluorescent sensor for Zn2+ ion

2013 ◽  
Vol 17 (01n02) ◽  
pp. 99-103 ◽  
Author(s):  
Hui He ◽  
Jian-Yong Liu ◽  
Dennis K.P. Ng
Keyword(s):  
Metal Ions ◽  
Spectral Properties ◽  
Fluorescence Spectra ◽  
Near Infrared ◽  
Fluorescent Sensor ◽  
High Sensitivity ◽  
Absorption And Fluorescence Spectra

This paper describes the preparation and spectral properties of a near-infrared fluorophore in which two bis(2-picolyl)amino moieties are axially linked to a silicon(IV) phthalocyanine core. The effects of various metal ions on its absorption and fluorescence spectra have been examined. The results indicate that this compound shows a high sensitivity and moderate selectivity toward Zn2+ ion.

Influence of Si-Al-Ge-Sb Matricies on Tm3+ Excitation Levels

2008 ◽  
Vol 587-588 ◽  
pp. 293-297
Author(s):  
M. Pospíšilová ◽  
P. Adámek ◽  
P. Peterka ◽  
V. Kubeček ◽  
I. Kašík ◽  
...  
Keyword(s):  
Genetic Algorithm ◽  
Chemical Vapor Deposition ◽  
Vapor Deposition ◽  
Fluorescence Spectra ◽  
Chemical Vapor ◽  
Oscillator Strengths ◽  
Absorption And Fluorescence Spectra ◽  
Measured Absorption ◽  
Optical Fiber Drawing ◽  
Solution Doping

Absorption and fluorescence spectra in the range from 350 to 1750 nm of several Tm3+- doped optical performs (rods) for optical fiber drawing were measured. Silica-based matrices of Al2O3-GeO2-P2O5-Sb2O3-SiO2 composition doped with several thousands ppm of Tm3+ were characterized. The preforms were fabricated by the Modified Chemical Vapor Deposition and by the solution doping methods. A new method, Genetic Algorithm SPEctra Decomposition was adopted for processing of the measured absorption spectra. This decomposition made it possible to calculate the oscillator strengths of Tm3+ absorption levels. Fluorescence bands of Tm3+ at 800 nm or 1640 nm were found in fluorescence spectra measured on the preform samples when excited at 1064 nm only.

Development of temporal spectroscopic properties for Xerogel matrices doped with Rhodamine 6G dye

Open Physics ◽  
2006 ◽  
Vol 4 (3) ◽  
Author(s):  
Abbas Al-Wattar ◽  
Baha Chiad ◽  
Wesam Twej ◽  
Sarmed Al-Awadi
Keyword(s):  
Fluorescence Spectra ◽  
Rhodamine 6G ◽  
Sol Gel ◽  
Blue Shift ◽  
Spectroscopic Properties ◽  
Dye Molecules ◽  
Absorption And Fluorescence Spectra ◽  
Silica Network ◽  
Sol Gel Process ◽  
Two Parameters

AbstractThe solid host of a laser dye modifies its spectroscopic properties with respect to its liquid host. During the Sol-Gel process the dye molecules suffer from changing their environment. Two parameters affect this matter, the change in the concentration due to the evaporation of the solvent (drying) and the caging of dye molecules inside the pores or attachment to the silica network. Rhodamine 6G absorption and fluorescence spectra with different concentrations, during Sol-Gel time processing, have been studied. Both, absorption and fluorescence spectra of the dye in the solid host, for different concentrations, show a blue-shift relative to its liquid phase.

Sign in / Sign up

Export Citation Format

Share Document